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The present study aims to apply the AMS method (Anisotropy of Magnetic Susceptibility) at a regional scale to track the fluid circulation direction that has produced an iron metasomatism within pre-existing dolomite host rock. The Urgonian formations hosting the Zn–Pb mineralizations in La Florida (Cantabria, northern Spain) have been taken as target for this purpose. Sampling was carried out, in addition to ferroan dolomite host rock enclosing the Zn–Pb mineralizations, in dolomite host rock and limestone to make the comparison possible between magnetic signals from mineralized rocks, where fluid circulation occurred, and their surrounding formations. AMS study was coupled with petrofabric analysis carried out by texture goniometry, Scanning Electron Microscopy (SEM) observations and also Shape Preferred Orientation (SPO) statistics. SEM observations of ferroan dolomite host rock illustrate both bright and dark grey ribbons corresponding respectively to Fe enriched and pure dolomites. SPO statistics applied on four images from ferroan dolomite host rock give a well-defined orientation of ribbons related to the intermediate axis of magnetic susceptibility K2. For AMS data, two magnetic fabrics are observed. The first one is observed in ferroan dolomite host rock and characterized by a prolate ellipsoid of magnetic susceptibility with a vertical magnetic lineation. The magnetic susceptibility carrier is Fe-rich dolomite. These features are probably acquired during metasomatic fluid circulations. In Fe-rich dolomite host rock, ?c? axes are vertical. As a rule, (0001) planes (i.e. planes perpendicular to ?c? axes) are isotropic with respect to crystallographic properties. So, the magnetic anisotropy measured in this plane should reflect crystallographic modification due to fluid circulation. This is confirmed by the texture observed using the SEM. Consequently, AMS results show a dominant NE–SW elongation interpreted as the global circulation direction and a NW–SE secondary elongation that we have considered as sinuosities of the fluid trajectory. The second type of magnetic fabric is essentially observed in the limestone and characterized by an oblate form of the ellipsoid of magnetic susceptibility, a horizontal magnetic foliation and mixed magnetic susceptibility carriers. It is interpreted as a sedimentary fabric.  相似文献   
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Oxygen isotopic composition of emerald from 62 occurrences and deposits in the world reveals a wide range in δ18O (SMOW) between +6.2 and +24.7‰. The δ18O-values for each deposit are restricted and can be used to determine the origin of emerald from the world's most important producers. The δ18O-value of emerald appears to be a fingerprint of its origin, especially for gems of exceptional quality from Colombia (eastern emerald zone, δ18O = +16.8 ± 0.1‰; western emerald zone, δ18O = +21.2 ± 0.5‰), Afghanistan (δ18O = +13.5 ± 0.1‰), Pakistan (Swat-Mingora districts, δ18O = +15.7 ± 0.1‰), Brazil (Santa Terezinha de Goiás, δ18O = +12.2 ± 0.1‰; Quadrilatero Ferrifero, δ18O = +6.9 ± 0.4‰) and Zimbabwe (Sandawana, δ18O = +7.5 ± 0.5‰). Furthermore, the 18O-composition of emerald appears to be a good marker of its geological environment because the data suggest that host-rock-buffering of fluid δ18O is considerable during fluid-rock interaction. Received: 29 January 1998 / Accepted: 25 March 1998  相似文献   
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The Variscan Armorican belt was the World leading producer of antimony at the beginning of the twentieth century. However, geological controls on the deposits remain unconstrained. Here, we illustrate the field setting of mineralisations and perform a statistical analysis using Geographical Information System software, geophysical and geological data. The analysis shows that Sb deposits are spatially correlated with high‐density and magnetic zones. This may reflect the presence of mafic/ultramafic bodies at depth – a suggestion that is further supported by numerous occurrences of doleritic dykes throughout the region. Future antimony prospecting should focus on the high‐density and high‐magnetic zones which comprise about 18% of the Armorican massif. Links between Sb deposits and mafic intrusions are recognised elsewhere in the West European Variscan belt, emphasising that these may be key for antimony prospecting in deformation belts.  相似文献   
4.
Mid‐Ocean Ridges host various types of hydrothermal systems including high‐T black‐smokers found in ultramafic rocks exhumed along slow spreading ridges. These systems are mostly described in two dimensions as their exposure on the present‐day seafloor lacks the vertical dimension. One way to understand these systems at depth is to study their fossilized equivalents preserved on‐land. Such observation can be done in the Platta nappe, Switzerland, where a Jurassic‐aged mineralized system is exposed in 3D. Serpentinites host a Cu‐Fe‐Ni‐Co‐Zn‐rich mineralization made of sulphides, magnetite and Fe‐Ca‐silicates either replacing serpentinites or within stockwork. Fe‐Ca‐silicates, abundant at the deepest levels, vanish in the mineralization close to the palaeo‐detachment. Fluids were channelized along mafic dykes and sills acting as preferential drains. Warm carbonation (~130°C) is the latest hydrothermal record. We propose that this system is an analog to the root zone of present‐day serpentinite‐hosted hydrothermal systems such as those found along the Mid‐Atlantic Ridge.  相似文献   
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In the Saint-Aubin-des-Chateaux quarry (Armorican Hercynian belt, western France), an epigenetic hydrothermal alteration affects an oolitic ironstone layer intercalated within the Lower Ordovician Grès armoricain Formation. The hydrothermal overprint produced pervasive and massive sulphidation with stratoid pyritised lenticular bodies within the oolitic ironstone layer. These sulphide lenses are spatially associated with strike-slip faults and extend laterally from them. After the massive sulphidation stage (Fe–As, stage 1), subsequent fracturing allowed the deposition of base metals (stage 2) and Pb–Sb–Au (stage 3) parageneses in veins. The dominant brittle structures are vertical extension veins, conjugate shear veins and strike-slip faults of various orders. All these structures are filled with the same paragenetic sequence. Deformation analysis allows the identification of structures that developed incrementally via right-lateral simple shear compatible with bulk strain affecting the Central Armorican Domain. Each increment corresponds to a fracture set filled with specific parageneses. Successive hydrothermal pulses reflect clockwise rotation of the horizontal shortening direction. Geothermometry on chlorite and arsenopyrite shows an input of hot hydrothermal fluids (maximum of 390–350°C) during the main sulphide stage 1. The subsequent stages present a marked temperature drop (300–275°C). Lead isotopes suggest that the lead source is similar for all hydrothermal stages and corresponds to the underlying Neo-Proterozoic basement. Lead isotope data, relative ages of deformation and comparison with neighbouring deposits suggest that large-scale fluid pulses occurred during the whole Hercynian orogeny rather than pulses restricted to the late Hercynian period. The vicinity of the Hercynian internal domain appears as a key control for deformation and fluid flow in the oolitic ironstones, which acted as a chemical and structural trap for the hydrothermal fluids. The epigenetic mineralisation of Saint-Aubin-des-Chateaux appears to be very similar to epigenetic sulphidation described in banded iron formation-hosted gold deposits.  相似文献   
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