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An exploratory investigation was conducted to assess the present conditions and evaluate the potential impacts of mining activities on soil and water environments at the Shivee-Ovoo coalmine area in Mongolia. Water quality analysis was conducted on samples from mine dewatering boreholes, a tailings dam, and drinking water sources around the mine area. In drinking water supplies of the area, concentrations of Mg, Fe, and F exceeded the levels set in Mongolian and World Health Organization guidelines. Water type and the principal components analysis indicated that water from the mine area and from public water-supply wells originated from the same aquifer. However, the water quality differed in shallow wells and deep wells because of bedrock differences and geochemical weathering processes, rather than climate effects such as from evaporation. The discharged water poses medium to high salinity hazard for use in irrigation, suggesting the need to manage its use in sustainable agriculture or projects to prevent desertification. The particle size distribution and fractal dimension values of soils revealed the dominance of fine to medium sands, which have strong potential for desertification. X-ray photoelectron spectroscopy analysis showed that the soils currently pose no apparent threat for acid rock drainage. Consequently, the open-pit mining of the study area shows no obvious environmental impact at present in its vicinity. However, for sustainable development and expansion of the mine, environmental changes should be continuously monitored, with consideration of possible measures for waste recycling. 相似文献
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Yongliang Xiong Haoran Deng Martin Nemer Shelly Johnsen 《Geochimica et cosmochimica acta》2010,74(16):4605-4611
In this study, the solubility constant of magnesium chloride hydroxide hydrate, Mg3Cl(OH)5·4H2O, termed as phase 5, is determined from a series of solubility experiments in MgCl2-NaCl solutions. The solubility constant in logarithmic units at 25 °C for the following reaction,
Mg3Cl(OH)5·4H2O+5H+=3Mg2++9H2O(l)+Cl- 相似文献
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Pure-iron end-member hibbingite, Fe2(OH)3Cl(s), may be important to geological repositories in salt formations, as it may be a dominant corrosion product of steel waste canisters in an anoxic environment in Na–Cl- and Na–Mg–Cl-dominated brines. In this study, the solubility of Fe2(OH)3Cl(s), the pure-iron end-member of hibbingite (FeII, Mg)2(OH)3Cl(s), and Fe(OH)2(s) in 0.04 m to 6 m NaCl brines has been determined. For the reactionFe2(OH)3Cl(s) + 3H+ ? 3 H2O + 2 Fe2+ + Cl?,the solubility constant of Fe2(OH)3Cl(s) at infinite dilution and 25 °C has been found to be log10 K = 17.12 ± 0.15 (95% confidence interval using F statistics for 36 data points and 3 parameters). For the reactionFe(OH)2(s) + 2H+ ? 2 H2O + Fe2+,the solubility constant of Fe(OH)2 at infinite dilution and 25 °C has been found to be log10 K = 12.95 ± 0.13 (95 % confidence interval using F statistics for 36 data points and 3 parameters). For the combined set of solubility data for Fe2(OH)3Cl(s) and Fe(OH)2(s), the Na+–Fe2+ pair Pitzer interaction parameter θNa+/Fe2+ has been found to be 0.08 ± 0.03 (95% confidence interval using F statistics for 36 data points and 3 parameters). In nearly saturated NaCl brine we observed evidence for the conversion of Fe(OH)2(s) to Fe2(OH)3Cl(s). Additionally, when Fe2(OH)3Cl(s) was added to sodium sulfate brines, the formation of green rust(II) sulfate was observed, along with the generation of hydrogen gas. The results presented here provide insight into understanding and modeling the geochemistry and performance assessment of nuclear waste repositories in salt formations. 相似文献
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