Pyrite formation driven by MSW landfill leachate in the Madrid Basin, Spain     

Ricardo Castelló  Clemente Recio  Pilar Morillas  Carmen Vizcayno 《Environmental Geology》2008,54(4):679-688

The role of municipal solid waste (MSW) landfill leachate on the genesis of minor amounts of pyrite associated with gypsum in an otherwise predominantly evaporitic sequence was studied in geological and geochemical terms. The potential association between landfill leachate and the conditions required for bacterial reduction of sulfate and fixation of H₂S as pyrite were examined. The lithological column was generally found to contain little or no Fe. The δ³⁴S values for sulfates were consistent with previously reported data; however, the measured δ¹⁸O values were slightly higher. Sulfides disseminated in the marl/lutite exhibited higher δ³⁴S values (≈−8‰) than gypsum-coating pyrite crystals (δ³⁴S < −30‰). Dissolution of gypsum to sulfate and the supply of metabolizable organic matter and Fe required for H₂S fixation as sulfides may have originated from landfill leachate. Intermittent availability of leachate, a result of the precipitation regime, can facilitate sulfur disproportionation and lead to fractionations as high as   相似文献   

Space–time distribution of ancient and active alluvial karst subsidence: examples from the central Ebro Basin,Spain     

J. L. Simón  M. A. Soriano  L. E. Arlegui  J. Gracia  C. L. Liesa  A. Pocoví 《Environmental Geology》2008,53(5):1057-1065

Space and time variations of alluvial karst subsidence in the central Ebro Basin are analysed in trenches (paleodolines), aerial photographs (historical dolines) and field surveys (present-day active dolines). The measured subsidence rates, as well as a comparison between densities of paleodolines computed in randomly selected scan-lines and density of active dolines computed in maps, suggest that present-day subsidence in favourable areas is more intense than that of Pleistocene times. According to diachronic maps drawn from (a) different aerial photographs taken after 1946 and (b) field surveys on deformations in urbanized areas, subsidence behaved as a nearly steady process while the whole area was used for agriculture. In contrast, rapid changes (through periods of several tens of years) have occurred in urbanized areas, in which dolines expand their boundaries through small marginal collapses, shifting sharply their sinking centres to neighbouring sites. These rapid changes do not have an equivalent in observed paleodolines.  相似文献   

Boundary manifolds for energy surfaces in celestial mechanics     

Ernesto A. Lacomba  Carles Simó 《Celestial Mechanics and Dynamical Astronomy》1982,28(1-2):37-48

We complete Mc Gehee's picture of introducing a boundary (total collision) manifold to each energy surface. This is done by constructing the missing components of its boundary as other submanifolds. representing now the asymptotic behavior at infinity.It is necessary to treat each caseh=0,h>0 orh<0 separately. In the first case, we repeat the known result that the behavior at total escape is the same as in total collision. In particular, we explain why the situation is radically different in theh>0 case compared with the zero energy case. In the caseh<0 we have many infinity manifold components. and the general situation is not quite well understood.Finally, our results forh0 are shown to be valid for general homogeneous potentials.Paper presented at the 1981 Oberwolfach Conference on Mathematical Methods in Celestial Mechanics.The research conducted in this paper has been partially supported by CONACYT (México), under grant PCCBNAL 790178.Partially supported by an Ajut a l'Investigacio of the University of Barcelona.  相似文献   

Variscan tectonics in the Iberian Pyrite Belt, South Portuguese Zone     

C. Soriano  J. Casas 《International Journal of Earth Sciences》2002,91(3):557-558

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On the oceanic impact of a data-assimilation method in a coupled ocean-land-atmosphere model     

Clemente A. S. Tanajura  Konstantin P. Belyaev 《Ocean Dynamics》2002,52(3):123-132

 Based on the Kalman filter theory, a new data-assimilation method has been used to improve the 3-D oceanic temperature field of the Center for Ocean-Land-Atmosphere Studies (COLA) coupled general circulation model. This method is applied to assimilate surface and subsurface temperature of in situ measurements from the Pilot Research Moored Array in the Tropical Atlantic project (PIRATA). The assimilation of the PIRATA data produces an improved representation of the thermal state of the ocean and allows a better estimation of other oceanographic quantities, like meridional heat fluxes and zonal currents. The present paper focuses on the tropical Atlantic and, in particular, it contains new reconstructed temperature profiles. One-month forecast experiments during 1999 were performed and the impact of the assimilation is discussed. Received: 24 April 2001 / Accepted: 8 March 2002  相似文献   

Spatio‐temporal variability of the isotopic input signal in a partly forested catchment: Implications for hydrograph separation     

Carles Cayuela  Jrme Latron  Josie Geris  Pilar Llorens 《水文研究》2019,33(1):36-46

The isotopic composition of precipitation (D and ¹⁸O) has been widely used as an input signal in water tracer studies. Whereas much recent effort has been put into developing methodologies to improve our understanding and modelling of hydrological processes (e.g., transit‐time distributions or young water fractions), less attention has been paid to the spatio‐temporal variability of the isotopic composition of precipitation, used as input signal in these studies. Here, we investigated the uncertainty in isotope‐based hydrograph separation due to the spatio‐temporal variability of the isotopic composition of precipitation. The study was carried out in a Mediterranean headwater catchment (0.56 km²). Rainfall and throughfall samples were collected at three locations across this relatively small catchment, and stream water samples were collected at the outlet. Results showed that throughout an event, the spatial variability of the input signal had a higher impact on hydrograph separation results than its temporal variability. However, differences in isotope‐based hydrograph separation determined preevent water due to the spatio‐temporal variability were different between events and ranged between 1 and 14%. Based on catchment‐scale isoscapes, the most representative sampling location could also be identified. This study confirms that even in small headwater catchments, spatio‐temporal variability can be significant. Therefore, it is important to characterize this variability and identify the best sampling strategy to reduce the uncertainty in our understanding of catchment hydrological processes.  相似文献   

Biogeochemical characterization of a Mediterranean shallow lake using stable isotopes: Laguna del Cristo (NW Iberian Peninsula)     

Margarita Jambrina-Enríquez  Clemente Recio  Ildefonso Armenteros 《Environmental Earth Sciences》2018,77(2):49

The present multi-isotopic study (δ¹⁸O–δD_water, δ³⁴S–δ¹⁸O_{dissolved-sulphate}, δ¹³C_{dissolved-inorganic-carbon}, δ¹³C–δ¹⁸O_{shells-modern-gastropods}, δ¹³C_plants, and δ¹³C_{sedimentary-organic-matter}) is aimed at assessing the hydrogeochemical changes and biogeochemical dynamics in a Mediterranean shallow lake fed by a Quaternary–Tertiary aquifer, the “Laguna del Cristo” (NW Iberian Peninsula), a system sensitive to climate fluctuations, between 2010 and 2011. Lake water is of the bicarbonate type, and there are no major pollutants. δ¹⁸O-δD_water values plot on a local evaporation line (δD=5.29δ¹⁸O–12.29) indicating that evaporative enrichment had a significant impact on lake water isotopic features. Periods of high water levels are characterized by lower δ³⁴S–δ¹⁸O_{dissolved-sulphate} and δ¹³C_{dissolved-inorganic-carbon} values and suggest sulphate derived from weathering of sulphides in the catchment area, delivered to the lake by surface run-off or via groundwater, and in situ decay of organic matter. During lower water levels, sulphate reduction and enhanced primary productivity lead to higher δ³⁴S_{dissolved-sulphate} and δ¹³C_{dissolved-inorganic-carbon} values. Evaporation induced enrichment in ¹⁸O_sulphate, ¹³C_{dissolved-inorganic-carbon} and ¹³C–¹⁸O_{shells-Galba-Gyraulus}. δ¹³C_plant confirms the C3 photosynthetic pathway. Enrichment in ¹³C submerged aquatic plants indicates that HCO₃^? is the main carbon source, except for ¹³C-depleted Potamogeton. The TOC, δ¹³C_org values, and TC/TN ratios in sediments all confirm the autochthonous character of organic matter contribution. This study provides a baseline for isotopic research into shallow, flow-through lakes fed by siliciclastic aquifers, and stresses the importance of evaporation and refilling (direct precipitation and groundwater discharge) in controlling the solute chemistry and stable isotopic composition in temperate regions with contrasting seasonal climates. The results also provide a snapshot of modern lake isotope variability that can be applied to paleoenvironmental reconstructions.  相似文献   

Anticipating the effects of groundwater withdrawal on seawater intrusion and soil settlement in urban coastal areas     

Josep Mas‐Pla  Agustí Rodríguez‐Florit  Manel Zamorano  Carles Roqué  Anna Menció  David Brusi 《水文研究》2013,27(16):2352-2366

Intensive pumping in urban coastal areas is a common threat to water resource quality due to seawater intrusion. In those areas where subsurface water resources are not usually used for human consumption or irrigation, intensive pumping is associated with other activities like the lowering of the water table necessary to support underground structures and building foundations. This activity also increases the likelihood of soil settlement that affects building stability and the corrosion of concrete structures due to groundwater salinity. Under these circumstances, the awareness of a certain municipality (Calonge, NE Spain) of the potential effects of groundwater withdrawal upon foundations has led to an integrated approach to anticipate seawater intrusion related to urban development. Geological mapping and correlation of borehole logs, electrical resistivity tomography, and hydrochemical data provide comprehensive knowledge of the geology and hydrogeology of the area and act as screening tools necessary to discern the influence of hydrological processes in coastal areas. Developing Strack's analytical solution, new comprehensive, dimensionless expressions are herein derived to determine the critical pumping rate necessary to prevent seawater intrusion, as well as to reproduce the evolution of the wedge toe and the water table stagnation point under different withdrawal rates. Furthermore, the Dupuit–Forchheimer well discharge formula allows the estimation of the effects of the water table lowering due to such critical pumping in the surrounding building foundations. Field data from the Calonge coastal plain illustrate this approach and provide assessment criteria for future urban development and planning. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Spatial assessment of groundwater use potential for irrigation in Teesta Barrage Project in Bangladesh     

Shahriar M. Wahid  Mukand S. Babel  Ashim Das Gupta  Roberto S. Clemente 《Hydrogeology Journal》2007,15(2):365-382

In Bangladesh, development of the groundwater resource for irrigation is a vital component of the government’s agricultural strategy to attain food self-sufficiency. Amidst reports of falling groundwater levels in many parts of Bangladesh, the potential of groundwater use has been investigated in the Teesta Barrage Project (TBP) in which large-scale groundwater development for dry-season irrigation has taken place in the recent past. Several techniques and tools have been applied such as the combination of analysis of groundwater hydrographs and mathematical modelling to derive key hydrogeological variables, calculation of net irrigation requirement and the use of geographical information systems. The results show that the economically attractive high-yielding variety (HYV) Boro (dry season) rice cultivation during the groundwater irrigation season may not be sustained in large parts of the project area if the current trends in abstraction are continued. However, due to spatial variation in abstraction, nine thanas (sub-districts)—out of a total of 21 in the project area—may still be able to expand groundwater-irrigated cropland and a groundwater-use potential of 40 mm/year may be created if deep-set shallow tubewells are used by the farmers to abstract groundwater. A structured approach, based on zoning of potential areas, is recommended for groundwater development and use.

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Resumen En Bangladesh, el desarrollo de las aguas subterráneas para riego es un componente vital del la estrategia agrícola del Gobierno para obtener la auto-suficiencia alimentaria. Un informe intermedio evidencia un descenso de los niveles de aguas subterráneas en muchas partes de Bangladesh, el uso potencial de aguas subterránea ha sido investigado en el Proyecto Tessta Barrage (TBP) en el cual ha tenido lugar el desarrollo de las aguas subterráneas a gran escala para el riego en la estación seca en un pasado reciente. Se ha aplicado algunas técnicas y herramientas, como la combinación del análisis de datos gráficos de aguas subterráneas y modelización matemática para obtener variables hidrogeológicas clave, el cálculo de la necesidad neta de riego y el uso de Sistemas de Información Geográfica. El resultado muestra que el cultivo, económicamente atractivo, de arroz HYV Boro (estación seca) durante la estación de riego con aguas subterráneas puede no ser sostenible en gran parte del área del proyecto si continúan las tendencias actuales en las extracciones. Sin embargo, debido a la variación espacial en la extracción, nueve thanas (subdistritos)—de un total de 21 en el área del Proyecto—pueden todavía sufrir un aumento de la tierra cultivable regada con aguas subterráneas y que se puede asumir un uso potencial de agua subterránea de 40 mm/estación si los granjeros utilizan sondeos someros instalados en fosas para la extracción. Se recomienda una aproximación estructurada para el desarrollo y uso de las aguas subterráneas, basada en la zonificación de áreas potenciales.

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Résumé Au Bangladesh, l’exploitation des ressources en eau souterraines pour l’irrigation est une composante vitale de la stratégie agricole gouvernementale pour atteindre l’auto-suffisance alimentaire. Parmi les baisses de niveaux piézométriques rapportées sur de nombreuses régions du Bangladesh, le potentiel d’utilisation des eaux souterraines a été étudié sur le Projet de Barrage de Teesta (TBP), où, dans un passé récent, les eaux souterraines ont été massivement exploitées pour l’irrigation en saison sèche. De nombreux outils et techniques ont été utilisés, comme l’analyse combinée des chroniques piézométriques et des modèles mathématiques pour dégager les variables hydrogéologiques clés, le calcul des besoins nets pour l’irrigation, et l’utilisation des systèmes d’information géographique. Les résultats démontrent que la culture en saison d’irrigation de la variété de riz HYV Boro (saison sèche), économiquement attrayante, n’est potentiellement pas viable sur de nombreux secteurs de la zone étudiée si les prélèvements perdurent selon la tendance actuelle. Cependant, du fait de la variation spatiale des prélèvements, neuf thanas (sous-districts)—sur un total de 21 sur le secteur d’étude—pourraient encore augmenter les surfaces irriguées, et une disponibilité en eau de 40 mm/saison pourrait être générée si les agriculteurs utilisaient des puits peu profonds pour exploiter les ressources souterraines. Une approche structurée, basée sur le zonage des secteurs potentiels, est recommandée pour l’exploitation et l’utilisation des eaux souterraines.

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Interannual variability in the biochemical composition of newly hatched larvae of the spider crab Maja brachydactyla (Decapoda,Majidae)     

Guiomar Rotllant  Carles G. Simeó  Guillermo Guerao  Marta Sastre  Daniel F. R. Cleary  Ricardo Calado  Alicia Estévez 《Marine Ecology》2014,35(3):298-307

The spider crab Maja brachydactyla is an important commercial species in Europe and supports intensive fisheries in the NE Atlantic. A field survey was performed to assess long‐term and consecutive interannual (2005–2010) variation of the biochemical composition of newly hatched larvae of M. brachydactyla. Larval biochemical profiles differed significantly among years, with pronounced differences being recorded in 2010. Differences among batches of newly hatched larvae were mainly explained by the contribution of triacylglycerols and, to a lesser degree, by protein and lipid content. The use of different nutrition indices is discussed. The biochemical composition of newly hatched larvae from M. brachydactyla was highly variable, even though surveyed broodstock was obtained from the same local population and was always sampled during the same season. The unpredictable biochemical profiles of newly hatched larvae may condition their survival and recruitment. This largely overlooked aspect of larval variability should be considered in future fisheries management strategies and captive production of marine organisms that still rely on wild seeds.  相似文献