Geochemistry of S-type granitic rocks from the reversely zoned Castelo Branco pluton (central Portugal)     

I.M.H.R. Antunes  A.M.R. Neiva  M.M.V.G. Silva  F. Corfu 《Lithos》2008,103(3-4):445-465

The zoned pluton from Castelo Branco consists of Variscan peraluminous S-type granitic rocks. A muscovite>biotite granite in the pluton's core is surrounded successively by biotite>muscovite granodiorite, porphyritic biotite>muscovite granodiorite grading to biotite=muscovite granite, and finally by muscovite>biotite granite. ID-TIMS U–Pb ages for zircon and monazite indicate that all phases of the pluton formed at 310 ± 1 Ma. Whole-rock analyses show slight variation in ⁸⁷Sr/⁸⁶Sr_310 Ma between 0.708 and 0.712, Nd_310 Ma values between − 1 and − 4 and δ¹⁸O values between 12.2 and 13.6. These geological, mineralogical, geochemical and isotopic data indicate a crustal origin of the suite, probably from partial melting of heterogeneous Early Paleozoic pelitic country rock. In detail there is evidence for derivation from different sources, but also fractional crystallization linking some of internal plutonic phases. Least-squares analysis of major elements and modelling of trace elements indicate that the porphyritic granodiorite and biotite=muscovite granite were derived from the granodiorite magma by fractional crystallization of plagioclase, quartz, biotite and ilmenite. By contrast variation diagrams of major and trace elements in biotite and muscovite, the behaviours of Ba in microcline and whole-rock δ¹⁸O, the REE patterns of rocks and isotopic data indicate that both muscovite-dominant granites were probably originated by two distinct pulses of granite magma.  相似文献   

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon     

Lutz Nasdala  Wolfgang Hofmeister  Nicholas Norberg  James M. Martinson  Fernando Corfu  Wolfgang Dörr  Sandra L. Kamo  Allen K. Kennedy  Andreas Kronz  Peter W. Reiners  Dirk Frei  Jan Kosler  Yusheng Wan  Jens Götze  Tobias Häger  Alfred Kröner  John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   

The age and source of late Hercynian magmatism in the central Alps: evidence from precise U−Pb ages and initial Hf isotopes   总被引：1，自引：0，他引：1  

Urs Schaltegger  Fernando Corfu 《Contributions to Mineralogy and Petrology》1992,111(3):329-344

This study presents U–Pb ages for zircon, titanite, allanite and epidote, and initial Hf isotopic compositions for zircon of Upper Carboniferous granites, diorites and syenites from the Aar massif, central Alps. The rocks were emplaced during three magmatic pulses after Hercynian collisional tectonics: (A) a shoshonitic-ultrapotassic series at 334±2.5 Ma; (B) scattered diorites and granites at 308–310 Ma; and (C) a high-K cale-alkaline granite batholith at 298±2 Ma. Inheritance of old zircons is negligible among all three groups. The Southern Aar granite, in contrast, is a syn-tectonic, probably ca. 350 Ma old granite that contains large amounts of inherited Precambrian zircons. Alpine metamorphism caused weak lead loss in many analyzed zircon fractions, but left the titanite U–Pb system undisturbed: thorites were almost completely reset by Alpine and recent lead loss. Mineral isochrons defined by titanite, allanite, epidote and apatite yield initial Pb isotopic compositions that are in agreement with the model values of Stacey and Kramers. Initial Hf isotopic compositions range from _Hf=–8 to +3.5. The data follow a trend of increasing _Hf with decreasing age. The _Hf versus element concentration relationships suggest mixing between a mantle and a crustal component. These relationships can be explained in terms of generation of the melts from a subcontinental mantle that had been enriched during subduction events at about 1 Ga and by 300 Ma had developed an isotopic signature distinct from that of MORB-type mantle. Further contamination of the melts occurred during ascent and differentiation in the crust. This late Hercynian magmatism can be related to post-collisional strike-slip tectonics.  相似文献   

U–Pb ages of the Dalsfjord Complex, SW Norway, and their bearing on the correlation of allochthonous crystalline segments of the Scandinavian Caledonides   总被引：1，自引：0，他引：1  

Fernando Corfu  Torgeir B. Andersen 《International Journal of Earth Sciences》2002,91(6):955-963

The Dalsfjord Complex is an allochthonous crystalline unit in the hanging wall of a major extensional detachment of the Caledonian orogen on the western coast of Norway. U-Pb geochronology has been carried out to test a previously proposed correlation between this unit and the Jotun Nappe Complex, a member of the Middle Allochthon now occupying a foreland position to the east. A monzonite sample of the Dalsfjord suite yields a zircon age of 1,634Dž Ma, whereas a crosscutting gabbro was formed at 1,464Lj Ma. Both rocks were strongly overprinted during the Sveconorwegian orogeny, especially the monzonite whose zircons U-Pb data were strongly pulled towards a lower intercept age of 882ᆱ Ma, and whose titanite indicates a two-stage growth history at >960 Ma and <920 Ma. These relationships support the correlation of these units with the Jotun Complex, and to some degree also with the Lindås Nappe in the Bergen Arcs.  相似文献   

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif     

Javier Fernández-Suárez  Fernando Corfu  Ricardo Arenas  Alberto Marcos  José R. Martínez Catalán  Florentino García  Jacobo Abati  Francisco J. Fernández 《Contributions to Mineralogy and Petrology》2002,143(2):236-253

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.  相似文献   

Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis          下载免费PDF全文

Lutz Nasdala  Fernando Corfu  John W. Valley  Michael J. Spicuzza  Fu‐Yuan Wu  Qiu‐Li Li  Yue‐Heng Yang  Chris Fisher  Carsten Münker  Allen K. Kennedy  Peter W. Reiners  Andreas Kronz  Michael Wiedenbeck  Richard Wirth  Chutimun Chanmuang  Manuela Zeug  Tamás Váczi  Nicholas Norberg  Tobias Häger  Alfred Kröner  Wolfgang Hofmeister 《Geostandards and Geoanalytical Research》2016,40(4):457-475

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.  相似文献   

Rutile R632 – A New Natural Reference Material for U‐Pb and Zr Determination          下载免费PDF全文

Emelie Axelsson  Jonas Pape  Jasper Berndt  Fernando Corfu  Klaus Mezger  Michael M. Raith 《Geostandards and Geoanalytical Research》2018,42(3):319-338

A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g^?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g^?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.  相似文献   

Unscrambling the stratigraphy of an Archean greenstone belt; a U---Pb geochronological study of the Favourable Lake belt, northwestern Ontario, Canada     

F Corfu  L.D Ayres 《Precambrian Research》1991,50(3-4)

New zircon and baddeleyite U---Pb ages show that the major units of the Archean Favourable Lake greenstone belt in the northern Superior Province were formed by episodic magmatism spanning more than 250 Ma and demonstrate that the original stratigraphy is disrupted by thrusts that juxtaposed older supracrustal rocks on top of younger ones. The oldest rocks of the area are a 2950 Ma gneissic tonalite and a 3000-2960 Ma granodiorite clast from a ca. 2725 Ma conglomerate. Five distinct volcanic (and sedimentary) groups formed during presumably short-lived episodes at 2925 Ma (I), 2870 Ma (II), 2858 Ma (III), 2734 Ma (IV), and 2725 Ma (V). The youngest group contains the thickest sedimentary unit, a turbiditic and alluvial-fluvial sequence. Compression caused thrusting that placed Groups I and V on top of IV, III on V, and II on III. The thrust complex was subsequently isoclinally folded. Compression was accompanied by major plutonism that emplaced the bulk of the bounding batholiths between 2732 and 2711 Ma ago. The late tectonic, Mo-mineralized Setting Net Lake Stock in the centre of the belt has an age of about 2708 Ma and was overprinted by younger hydrothermal events that produced monazite (2706 Ma), titanite (ca. 2695-2690 Ma) and rutile (the youngest rutile at 2657 Ma). Similar late hydrothermal pulses are recorded by secondary titanite elsewhere in the belt and within the batholiths. The protracted magmatic evolution of the belt is typical of that observed in a number of greenstone belts of the northern Superior Province but is uncommon farther to the south. In contrast, the structural complications and put-of-sequence stratigraphy appear to be a quite common tectonic characteristic of greenstone belts of the whole Superior Province.  相似文献   

U-Pb age and genetic significance of heterogeneous zircon populations in rocks from the Favourable Lake area,Northwestern Ontario     

F. Corfu  L. D. Ayres 《Contributions to Mineralogy and Petrology》1984,88(1-2):86-101

The study evaluates the relationships between measured U-Pb ages and zircon characteristics of five morphologically, texturally, and isotopically complex zircon populations and compares the zircon development stages to the orogenic evolution of the Favourable Lake area. Two distinct zircon types from a hornblendite xenolith in a granitoid batholith of the Sachigo subprovince of the Superior Province yield U-Pb ages of 2729.0±6.8 Ma and 2714.8 _–6.4 ^+7.4 Ma, which date specific metamorphic phases coinciding with major plutonic pulses in the batholith. Zircons from a metamorphosed felsic dike, crosscutting the hornblendite, consist of an old zircon component with a minimum age of 2788 Ma possibly reflecting igneous crystallization 2950 Ma ago, and a younger component with an inferred age of 2725±15 Ma, probably reflecting metamorphism during batholith emplacement.In the Berens River subprovince to the south, granodiorite forms both a late tectonic phase in a large batholith and a post-tectonic pluton intruded into the batholith, yet zircons from these granodiorites have identical ages of 2697.3±1.7 Ma and 2696.2±1.2 Ma, respectively. The late tectonic granodiorite also contains inherited zircons with a minimum age of 2767 Ma which are indirect evidence for the presence of old sialic crust in this subprovince. Zircons from a sheared monzonite near the boundary fault between the two subprovinces yield an upper intercept age of 2769 _–26 ⁺⁶³ Ma, which we interpret as the intrusion age of the monzonite. This rock is older than most dated units in the surrounding batholiths and suggests that the boundary is a long-lived Archean structure.A lower intercept age of about 1750 Ma for zircons of the hornblendite is the result of chemical alteration of the zircons. This, and a similar lower intercept age shown by the sheared monzonite zircons, are thought to reflect increased fluid activity and possibly shearing during the Early Proterozoic Hudsonian orogeny which occurred in the Churchill Province to the northwest. A later Pb-loss mainly from near-surface domains of the zircons is indicated by lower intercept ages of about 500–100 Ma.Publication approved by the Director, Ontario Geological Survey  相似文献   

Geochronology of zircon megacrysts from nepheline-bearing gneisses as constraints on tectonic setting: implications for resetting of the U-Pb and Lu-Hf isotopic systems     

L. D. Ashwal  R. A. Armstrong  R. J. Roberts  M. D. Schmitz  F. Corfu  C. J. Hetherington  K. Burke  M. Gerber 《Contributions to Mineralogy and Petrology》2007,153(4):389-403

Nepheline-bearing gneisses from the 75 km² Tambani body in the Mozambique Belt of southern Malawi, are miaskitic biotite-nepheline monzodiorites, reflecting an absence of K-feldspar, alkali amphiboles or pyroxenes, and contain euhedral zircon megacrysts up to 5 cm across. The zircons contain U = 1–1,860 ppm, Th = 0–2,170 ppm and Y = 400–1,100 ppm, and very low concentrations of all other measured trace elements except Hf (HfO₂ = 0.53–0.92 wt. %). Cathodoluminescence images reveal oscillatory sector growth zoning and no evidence for xenocrystic cores, indicating that the zircons represent primary magmatic crystallization products that have survived amphibolite grade metamorphism. U-Pb isotopic analyses (by TIMS) yield an upper intercept age of 730 ± 4 Ma (MSWD = 1.7), which we interpret as the time of magmatic crystallization of the zircons. This is coincident with 11 SHRIMP spot analyses, which yield a mean age of 729 ± 7 Ma (MSWD = 0.37). Metamorphism, at 522 ± 17 Ma as suggested by monazite, caused partial Pb-loss during local recrystallization of zircon. Lu-Hf isotopic data for three whole-rock samples of nepheline-bearing gneiss are collinear with those for zircon megacrysts, and correspond to an age of 584 ± 17 Ma (MSWD = 0.37. We interpret the Lu-Hf array to represent a mixing line defined by the Hf isotopic signature of primary zircon and that of the rock-forming minerals reset during metamorphic (re-)crystallization; hence the 584 Ma age is likely geologically meaningless. Given the well-defined association of nepheline syenites (and phonolitic volcanic equivalents) with continental rifting, we suggest that the Tambani body represents a magmatic product formed at 730 Ma during the break-up of the Rodinia supercontinent. The 522 Ma age is akin to other Pan-African metamorphic ages that record collisional suturing events during the final assembly of Gondwana. Zircon-bearing nepheline gneisses thus preserve a record of intra-continental rifting and of continental collision in southern Malawi.  相似文献