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Paul R. Craddock Olivier J. Rouxel Lary A. Ball Wolfgang Bach 《Chemical Geology》2008,253(3-4):102-113
We have developed a technique for the accurate and precise determination of 34S/32S isotope ratios (δ34S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O2+. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical. 相似文献
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CL de Moor SJ Johnston A Brandão RA Rademeyer JP Glazer LB Furman 《African Journal of Marine Science》2015,37(3):285-311
The waters off South Africa's coastline boast a rich mix of commercially fished species. Quantitative assessments of these marine resources have developed from simple methods first applied in the 1970s, to models that encompass a wide range of methodologies. The more valuable resources have undergone regular assessments in recent decades, with frequencies closely related to the management approach employed for each fishery. Many of these assessments form the operating models used to simulation-test candidate management procedures. This paper provides a comprehensive review of the assessments of 11 of the most important fisheries resources in South Africa. Some assessments use simple biomass dynamics models, whereas others are a hybrid of age- and length-based models, each designed to model the specific characteristics of the resource and fishery concerned. Many of the assessments have been disaggregated by species/stock and/or area as related multispecies/stock/ distribution hypotheses have arisen. This paper explores the similarities and differences in the data available and the methods applied. The review indicates that, whereas the status of three of these resources cannot be estimated reliably at present, the status of six resources is considered to be reasonable to good, whereas that of abalone Haliotis midae and West Coast rock lobster Jasus lalandii remains poor. 相似文献
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Stuart J. Robbins Wesley A. Watters John E. Chappelow Veronica J. Bray Ingrid J. Daubar Robert A. Craddock Ross A. Beyer Margaret Landis Lillian R. Ostrach Livio Tornabene Jamie D. Riggs Brian P. Weaver 《Meteoritics & planetary science》2018,53(4):583-637
One important, almost ubiquitous, tool for understanding the surfaces of solid bodies throughout the solar system is the study of impact craters. While measuring a distribution of crater diameters and locations is an important tool for a wide variety of studies, so too is measuring a crater's “depth.” Depth can inform numerous studies including the strength of a surface and modification rates in the local environment. There is, however, no standard data set, definition, or technique to perform this data-gathering task, and the abundance of different definitions of “depth” and methods for estimating that quantity can lead to misunderstandings in and of the literature. In this review, we describe a wide variety of data sets and methods to analyze those data sets that have been, are currently, or could be used to derive different types of crater depth measurements. We also recommend certain nomenclature in doing so to help standardize practice in the field. We present a review section of all crater depths that have been published on different solar system bodies which shows how the field has evolved through time and how some common assumptions might not be wholly accurate. We conclude with several recommendations for researchers which could help different data sets to be more easily understood and compared. 相似文献
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Recently reported detrital zircon (DZ) data help to associate the Paleogene strata of the Gulf of Mexico region to various provenance areas. By far, recent work has emphasised upper Paleocene‐lower Eocene and upper Oligocene strata that were deposited during the two episodes of the highest sediment supply in the Paleogene. The data reveal a dynamic drainage history, including (1) initial routing of western Cordilleran drainages towards the Gulf of Mexico in the Paleocene, (2) an eastward shift of the western continental divide, from the Jura‐Cretaceous cordilleran arc to the eastern edge of the Laramide province after the Paleocene and (3) a southward shift, along the eastern Laramide province, of the headwaters of river systems draining to the Mississippi and Houston embayments at some time between the early Eocene and Oligocene. However, DZ characterisation of most (~20 Myr) of the middle Eocene‐lower Oligocene section remains limited. We present 60 DZ age spectra, most of which are from the middle or upper Eocene outcrop belts, with 50–200‐km spacing. We define six to eight distinct groups of DZ age spectra for middle and upper Eocene strata. Data from this and other studies resolve at least six substantial temporal changes in age spectra at various positions along the continental margin. The evolving age spectra constrain the middle and upper Eocene drainage patterns of large parts of interior North America. The most well‐resolved aspects of these drainage patterns include (1) persistent rivers that flowed from erosional landscapes across the Paleozoic Appalachian orogen either into the low‐lying Mississippi embayment or directly into the eastern Gulf; (2) at least during marine regressions, a trunk channel that likely flowed southward along the axial part of Mississippi Embayment and integrated tributaries from the east and west; and (3) rivers that flowed to the Houston embayment in the middle Eocene that likely originated in the Laramide province in central Colorado and southern Wyoming, as Precambrian basement highs in those source areas were being unroofed. 相似文献
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E Correia JP Granadeiro A Regalla E Dias A Almeida P Catry 《African Journal of Marine Science》2017,39(4):389-396
Knowledge of trophic interactions between the key components of marine communities is required to understand food-web dynamics and develop ecosystem-based management approaches. In West Africa, where fisheries sustain the livelihoods of a significant part of the human population, this understanding is even more urgent, especially in the face of rapidly expanding fisheries and some stock collapses in the region. We studied the feeding ecology of the Crevalle jack Caranx hippos, West African Spanish mackerel Scomberomorus tritor and Guinean barracuda Sphyraena afra in the Bijagós Archipelago, Guinea-Bissau. These are the most abundant pelagic predatory teleost fishes in the area, but little is known about their ecology despite being species with commercial and recreational value, and they likely also play an important role in various African coastal ecosystems. Our findings show a high degree of dietary overlap among these three predator species, despite some degree of segregation by prey size and type. All three predators depend on Sardinella maderensis as the most important prey, which together with other members of the Clupeidae represented 47–96% of the ingested prey items. There was little difference in the diets of the predators between the dry and rainy seasons. These novel findings suggest a ‘wasp-waist’-structured ecosystem in the Bijagós Archipelago in which S. maderensis is the central small-sized pelagic fish species, and stress the need for an ecosystem-based approach to fisheries management in the region, with precautionary measures taken to avoid the overexploitation of clupeids. 相似文献
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Microchemical analyses of rare earth element (REE) concentrations and Sr and S isotope ratios of anhydrite are used to identify sub-seafloor processes governing the formation of hydrothermal fluids in the convergent margin Manus Basin, Papua New Guinea. Samples comprise drill-core vein anhydrite and seafloor massive anhydrite from the PACMANUS (Roman Ruins, Snowcap and Fenway) and SuSu Knolls (North Su) active hydrothermal fields. Chondrite-normalized REE patterns in anhydrite show remarkable heterogeneity on the scale of individual grains, different from the near uniform REEN patterns measured in anhydrite from mid-ocean ridge deposits. The REEN patterns in anhydrite are correlated with REE distributions measured in hydrothermal fluids venting at the seafloor at these vent fields and are interpreted to record episodes of hydrothermal fluid formation affected by magmatic volatile degassing. 87Sr/86Sr ratios vary dramatically within individual grains between that of contemporary seawater and that of endmember hydrothermal fluid. Anhydrite was precipitated from a highly variable mixture of the two. The intra-grain heterogeneity implies that anhydrite preserves periods of contrasting hydrothermal versus seawater dominant near-seafloor fluid circulation. Most sulfate δ34S values of anhydrite cluster around that of contemporary seawater, consistent with anhydrite precipitating from hydrothermal fluid mixed with locally entrained seawater. Sulfate δ34S isotope ratios in some anhydrites are, however, lighter than that of seawater, which are interpreted as recording a source of sulfate derived from magmatic SO2 degassed from underlying felsic magmas in the Manus Basin. The range of elemental and isotopic signatures observed in anhydrite records a range of sub-seafloor processes including high-temperature hydrothermal fluid circulation, varying extents of magmatic volatile degassing, seawater entrainment and fluid mixing. The chemical and isotopic heterogeneity recorded in anhydrite at the inter- and intra-grain scale captures the dynamics of hydrothermal fluid formation and sub-seafloor circulation that is highly variable both spatially and temporally on timescales over which hydrothermal deposits are formed. Microchemical analysis of hydrothermal minerals can provide information about the temporal history of submarine hydrothermal systems that are variable over time and cannot necessarily be inferred only from the study of vent fluids. 相似文献
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Characterization of fluvial activity in Parana Valles using different age-dating techniques 总被引：1，自引：0，他引：1
Martian valley networks provide the best evidence that the climate on Mars was different in the past. Although these features are located primarily in heavily cratered terrain of Noachian age (>3.7 Ga), the ages of the features and the time when they were active is not well understood. From superposed craters several recent global studies determined that most valley networks formed during the Late Noachian to Early Hesperian; however, there were some disparities between the techniques. In this study, our principal objective was to test the reliability of the different age-dating techniques to better understand their accuracy and limitations. We applied these techniques to Parana Valles using a variety of high-resolution images taken from different instruments that allow us to identify smaller craters (D > 125 m) while providing sufficient coverage to support a statistically reliable sampling of crater populations, which is necessary to reduce the uncertainties in age determination. Our results indicate that Parana Valles formed during the Early Hesperian Period but that the crater density (D > 353 m) is heterogeneous inside the Parana Valles basin. The crater population decreases from the headwaters downstream recording a resurfacing event that is most likely related to the erosion of downstream sub-basins. The terrain near the source area is Late Noachian to Early Hesperian in age while terrains closer to the outlet are Early to Late Hesperian in age. Crater densities (D > 125 m) inside the valley are also heterogeneous and record several resurfacing events on the valley floor. Where the width of the valley network narrows to <2 km we found evidence of an Amazonian age eolian deposit that is a relatively thin layer of only few meters that was probably deposited as a result of topographic influences. Our results validate the reliability of several proposed age-dating techniques, but we also determined the accuracy and applicability of these techniques. Our results also demonstrate that crater populations can be used to not only determine the relative ages of valley networks, but also to map the distribution of sedimentary materials and the extent of resurfacing events that occurred after valley network formation. 相似文献
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High‐precision iron isotopic compositions for Fe‐bearing geological reference materials and chondrites with a wide range of matrices (e.g., silicates, oxides, organic‐bearing materials) are reported. This comprehensive data set should serve as a reference for iron isotopic studies across a range of geological and biological disciplines for both quality assurance and inter‐laboratory calibration. Where comparison is available, the iron isotopic compositions of most geological reference materials measured in this study were in agreement with previously published data within quoted uncertainties. Recommendations for the reporting of future iron isotopic data and associated uncertainties are also presented. Long‐term repeat analyses of all samples indicate that highly reproducible iron isotopic measurements are now obtainable (± 0.03‰ and ± 0.05‰ for δ56Fe and δ57Fe, respectively). 相似文献