Carbon-isotope records of the Early Jurassic (Toarcian) oceanic anoxic event from the Valdorbia (Umbria–Marche Apennines) and Monte Mangart (Julian Alps) sections: palaeoceanographic and stratigraphic implications     

NADIA SABATINO  RODOLFO NERI  ADRIANA BELLANCA  HUGH C. JENKYNS†  FRANÇOIS BAUDIN‡  GUIDO PARISI§  DANIELE MASETTI¶ 《Sedimentology》2009,56(5):1307-1328

The Toarcian oceanic anoxic event ( ca 183 Ma) coincides with a global perturbation marked by enhanced organic carbon burial and a general decrease in calcium carbonate production, probably triggered by changes in the composition of marine plankton and elevated carbon dioxide levels in the atmosphere. This study is based on high-resolution sampling of two stratigraphic successions, located in Valdorbia (Umbria–Marche Apennines) and Monte Mangart (Julian Alps), Italy, which represent expressions of the Toarcian oceanic anoxic event in deep-water pelagic sediments. These successions are characterized by the occurrence of black shales showing relatively low total organic carbon concentrations (compared with coeval strata in Northern Europe), generally < 2%, and low hydrogen indices. On this basis, they are similar to other Toarcian black shales described from the Tethyan region. The positive and negative carbon-isotope records from the two localities permit a high-resolution correlation such that ammonite biostratigraphy information from Valdorbia can be transferred to those parts of the Monte Mangart section that lack these fossils. Spectral analyses of δ¹³C_org values and of CaCO₃ percentages from the sedimentary records of both the Valdorbia and Monte Mangart sections reveal a strong cyclic pattern, best interpreted as an eccentricity signal which hence implies a duration of ca 500 kyr for the negative carbon-isotope excursion. Based on the carbon-isotope curves obtained, the high-resolution correlation between the Italian successions and a section in Yorkshire (Northern Europe) confirms the supposition that the apparent mismatch between the dating of the Toarcian oceanic anoxic event in the Boreal and Tethyan realms is an artefact of biostratigraphy.  相似文献   

Cyclic sedimentation in the Southern Alpine Rhaetic: the importance of climate and eustasy in controlling platform-basin interactions     

MARK T. BURCHELL  MARCO STEFANI†  DANIELE MASETTI† 《Sedimentology》1990,37(5):795-815

Uppermost Triassic (Rhaetic) facies, as developed in the Southern Alpine region of Northern Italy, were deposited in a rapidly subsiding, fault-dissected trough (the Lombardy Basin) bounded by carbonate platforms. The main part of the Rhaetic succession consists of 10-m-scale asymmetric cycles, each divided into three parts: a lower shale portion; a central rhythmic portion consisting of repeated marl-limestone couplets, the limestone parts of which thicken upward; and an upper, wholly carbonate unit. A study of the diagenetic history of the series demonstrates that both the major asymmetric cyclicity and the limestone-marl couplets of the central rhythmic member (together constituting a ‘compound’ cyclic form) are fundamentally depositional in nature. It is suggested that this compound cyclicity resulted from the superposition of a low-frequency (approximately 100 000-year periodicity) asymmetric carbonate mud signal with a higher-frequency terrigenous mud signal. Field, petrographic, and geochemical investigations suggest that the basinal carbonate is predominantly allochthonous in origin, having been derived as relatively pure aragonitic mud from adjacent carbonate platforms. It is postulated that the asymmetric carbonate signal was linked to the ecological effects of eustatic fluctuation on platform carbonate systems. Repeated subaerial exposure of subtidal muds in shallow areas indicates that such sea-level variations occurred. A model is presented in which the basinward export of carbonate was negligible in the deepening phase, increased to a maximum during shallowing and was finally halted by the emergence of large platform flats. In contrast, the higher frequency terrigenous mud signal of the basin is thought to have been climatically modulated; fluctuations of a shorter period than those predicted by the Milankovitch theory affected hinterland precipitation and runoff. Particularly rapid subsidence and high depositional rates may have allowed the preservation of this signal.  相似文献   

Properties of dust aerosol particles transported to Portugal from the Sahara desert   总被引：1，自引：0，他引：1  

FRANK WAGNER  DANIELE BORTOLI  SÉRGIO PEREIRA  MARIA JOÃO COSTA  ANA MARIA SILVA  BERNADETT WEINZIERL  MICHAEL ESSELBORN  REAS PETZOLD  KATHI RASP  BERND HEINOLD  INA TEGEN 《Tellus. Series B, Chemical and physical meteorology》2009,61(1):297-306

Aerosol properties of mineral particles in the far field of an African desert dust outbreak were investigated that brought Saharan dust over the Mediterranean in different layers to Portugal. The measurements were performed inside the project Desert Aerosols over Portugal (DARPO) which was linked to the Saharan Mineral Dust Experiment (SAMUM). The maximum particle mass concentration was about 150 μg m⁻³ and the corresponding scattering coefficient was 130 M m⁻¹ which results in a mass scattering efficiency of 0.87 m² g⁻¹. The aerosol optical depth reached values up to 0.53 and the lidar ratio was between 45 and 50 in the whole dust loaded column. A comparison between particle size distributions and refractive indices derived from different instruments and models showed a general good agreement but some minor differences could also be observed. Measurements as well as calculations with a particle transport model suggest that there is a relatively higher concentration of very large particles in the upper region of the dust layer than on the surface which is likely connected with meteorological conditions at the observational site (Évora, Portugal).  相似文献   

Discontinuous Melt Extraction and Weak Refertilization of Mantle Peridotites at the Vema Lithospheric Section (Mid-Atlantic Ridge)   总被引：1，自引：0，他引：1  

BRUNELLI  DANIELE; SEYLER  MONIQUE; CIPRIANI  ANNA; OTTOLINI  LUISA; BONATTI  ENRICO 《Journal of Petrology》2006,47(4):745-771

Melting processes beneath the Mid-Atlantic Ridge were studiedin residual mantle peridotites sampled from a lithospheric sectionexposed near the Vema Fracture Zone at 11°N along the Mid-AtlanticRidge. Fractional and dynamic melting models were tested basedon clinopyroxene rare earth element and high field strengthelement data. Pure fractional melting (non-modal) cannot accountfor the observed trends, whereas dynamic melting with criticalmass porosity <0·01 fits better the measured values.Observed microtextures suggest weak refertilization with 0·1–1%quasi-instantaneous or partially aggregated melts trapped duringpercolation. The composition of the melts is evaluated, togetherwith their provenance, with respect to the garnet–spineltransition. Partial melts appear to be aggregated over shortbut variable intervals of the melting column. Deep melts (generatedwithin the garnet stability field at the base of the meltingcolumn) escape detection, being separated from the residuesby transport inside conduits or fractures. The temporal evolutionof the melting process along the exposed section shows a steadyincrease of mantle temperature from 20 Ma to present. KEY WORDS: mantle partial melting; abyssal peridotite; trace element; refertilization; Vema Fracture Zone  相似文献   

Comparison of 40Ar-39Ar and Rb-Sr Data on Phengites from the UHP Brossasco-Isasca Unit (Dora Maira Massif, Italy): Implications for Dating White Mica     

DI VINCENZO  GIANFRANCO; TONARINI  SONIA; LOMBARDO  BRUNO; CASTELLI  DANIELE; OTTOLINI  LUISA 《Journal of Petrology》2006,47(7):1439-1465

Different lithologies (impure marble, eclogite and graniticorthogneiss) sampled from a restricted area of the coesite-bearingBrossasco–Isasca Unit (Dora Maira Massif) have been investigatedto examine the behaviour of ⁴⁰Ar–³⁹Ar and Rb–Srsystems in phengites developed under ultrahigh-pressure (UHP)metamorphism. Mineralogical and petrological data indicate thatzoned phengites record distinct segments of the P–T path:prograde, peak to early retrograde in the marble, peak to earlyretrograde in the eclogite, and late retrograde in the orthogneiss.Besides major element zoning, ion microprobe analysis of phengitein the marble also reveals a pronounced zoning of trace elements(including Rb and Sr). ⁴⁰Ar–³⁹Ar apparent ages (35–62Ma, marble; 89–170 Ma, eclogite; 35–52 Ma, orthogneiss),determined through Ar laserprobe data on phengites (step-heatingand in situ techniques), show wide intra-sample and inter-samplevariations closely linked to within-sample microchemical variations:apparent ages decrease with decreasing celadonite contents.These data confirm previous reports on excess Ar and, more significantly,highlight that phengite acted as a closed system in the differentlithologies and that chemical exchange, not volume diffusion,was the main factor controlling the rate of Ar transport. Conversely,a Rb–Sr internal isochron from the same eclogite yieldsan age of 36 Ma, overlapping with the time of the UHP metamorphicpeak determined through U–Pb data and thereby corroboratingthe previous conclusion that UHP metamorphism and early retrogressionoccurred in close succession. Different phengite fractions ofthe marble yield calcite–phengite isochron ages of 36to 60 Ma. Although this time interval matches Ar ages from thesame sample, Rb–Sr data from phengite are not entirelyconsistent with the whole dataset. According to trace elementvariations in phengite, only Rb–Sr data from two wet-groundphengite separates, yielding ages of 36 and 41 Ma, are internallyconsistent. The oldest age obtained from a millimetre-sizedgrain fraction enriched in prograde–peak phengites mayrepresent a minimum age estimate for the prograde phengite relics.Results highlight the potential of the in situ ⁴⁰Ar–³⁹Arlaser technique in resolving discrete P–T stages experiencedby eclogite-facies rocks (provided that excess Ar is demonstrablya negligible factor), and confirm the potential of Rb–Srinternal mineral isochrons in providing precise crystallizationages for eclogite-facies mineral assemblages. KEY WORDS: ⁴⁰Ar–³⁹Ar dating; Rb–Sr dating; phengite; SIMS; UHP metamorphism  相似文献