The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)     

Matteo Lelli  Roberto Cioni  Luigi Marini 《Environmental Geology》2008,56(1):139-158

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Luigi Marini (Corresponding author)Email:

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A model for the viscosity of rhyolite as a function of H₂O-content and pressure: A calibration based on centrifuge piston cylinder experiments     

Paola Ardia  Daniele Giordano 《Geochimica et cosmochimica acta》2008,72(24):6103-6123

The Newtonian viscosity of synthetic rhyolitic liquids with 0.15-5.24 wt% dissolved water was determined in the interval between 580 and 1640 °C and pressures of 1 atm and 5-25 kbar. Measurements were performed by combining static and accelerated (up to 1000g) falling sphere experiments on water-bearing samples, with high temperature concentric cylinder experiments on 0.15 wt% H₂O melts. These methods allowed viscosity determinations between 10² and 10⁷ Pa s, and cover the complete range of naturally occurring magmatic temperatures, pressures, and H₂O-contents for rhyolites.Our viscosity data, combined with those from previous studies, were modeled by an expression based on the empirical Vogel-Fulcher-Tammann equation, which describes viscosities and derivative properties (glass transition temperature T_g, fragility m, and activation volume of viscous flow Va) of silicic liquids as a function of P-T-X_(H2O). The fitted expressions do not account for composition-dependent parameters other than X_(H2O) and reproduce the entire viscosity database for silicic liquids to within 3.0% average relative error on log η (i.e. std. error of estimate of 0.26 log units).The results yield the expected strong decrease of viscosity with temperature and water content, but show variable pressure dependencies. Viscosity results to be strongly affected by pressure at low pressures; an effect amplified at low temperatures and water contents. Fragility, as a measure for the deviation from Arrhenian behavior, decreases with H₂O-content but is insensitive to pressure. Activation volumes are always largely negative (e.g., less than −10 cm³/mol) and increase strongly with H₂O-content. Variations in melt structure that may account for the observed property variations are discussed.  相似文献   

Total content and chemical speciation of arsenic in the polychaete Sabella spallanzanii     

Fattorini D  Bocchetti R  Bompadre S  Regoli F 《Marine environmental research》2004,58(2-5):839-843

An unusual feature has been observed in polychaetes regarding their capacity to accumulate high levels of relatively toxic forms of arsenic in specific tissues. Basal levels of arsenic and distribution of its compounds were investigated in tissues of the Mediterranean polychaete Sabella spallanzanii. Particularly high concentrations were measured in the branchial crown (1036+/-136 microg/g d.w.) and chemical speciation revealed that the predominant form was the relatively toxic dimethylarsinate (DMA). These data suggest a potential role of As as anti-predatory strategy in polychaetes.  相似文献   

Measurement of alkaline and earthy ions in fish otolith and sea water using a high performance ion chromatography     

M. Marini  A. Campanelli  F. Abballe 《Marine Chemistry》2006,99(1-4):24

Fish growth and the relation between growth and environmental conditions offer a good opportunity for measuring alkaline and earthy ions in fish otoliths.The analytical method must involve high sensitivity when attempting to discriminate between fish growth and environmental conditions.The aim of this paper is to propose a chromatographic method, with low detection limits, as a new approach in determining some important micronutrients present in sea water and fish otoliths.The work samples are: coastal, off-shore and sediment waters and fish otoliths (Engraulis encrasicholus, Mullus barbatus, Umbrina cirrhosa, Sciaena umbra, Pagellus erythrinus) in the Adriatic Sea and the Canal of Sicily.The analytical method includes an IONPAC CS12A chromatographic column and a 18 mM methanesulfonic acid eluent.The detection limit readings obtained with this method, for one E. encrasicholus fish otolith, weighing 2.6 mg are equal or inferior to 0.1 μg/L for lithium (Li), 59 μg/L for sodium (Na), 46 μg/L for ammonium (NH₄), 23 μg/L for potassium (K), 13 μg/L for magnesium (Mg), 88 μg/L for manganese (Mn), 2.567 μg/L for calcium (Ca) and 13 μg/L for strontium (Sr).The HPIC method minimizes overlaps such as Na on Li, and NH₄ in seawater and Ca on Mg and Sr in fish otolith. These elements are an essential constituent present in otoliths when describing the relation between growth and environmental conditions.Good separation among analytes is achieved within 16 min.  相似文献   

Estimation of daily stream water temperatures with a Bayesian regression approach          下载免费PDF全文

Mohammad M. Sohrabi  Rohan Benjankar  Daniele Tonina  Seth J. Wenger  Daniel J. Isaak 《水文研究》2017,31(9):1719-1733

Stream water temperature plays a significant role in aquatic ecosystems where it controls many important biological and physical processes. Reliable estimates of water temperature at the daily time step are critical in managing water resources. We developed a parsimonious piecewise Bayesian model for estimating daily stream water temperatures that account for temporal autocorrelation and both linear and nonlinear relationships with air temperature and discharge. The model was tested at 8 climatically different basins of the USA and at 34 sites within the mountainous Boise River Basin (Idaho, USA). The results show that the proposed model is robust with an average root mean square error of 1.25 °C and Nash–Sutcliffe coefficient of 0.92 over a 2‐year period. Our approach can be used to predict historic daily stream water temperatures in any location using observed daily stream temperature and regional air temperature data.  相似文献   

Ressi experimental catchment: Ecohydrological research in the Italian pre-Alps     

Giulia Zuecco  Chiara Marchina  Ylenia Gelmini  Anam Amin  H. J. van Meerveld  Daniele Penna  Marco Borga 《水文研究》2021,35(3):e14095

Ressi is a small (2.4 ha) forested catchment located in the Italian pre-Alps. The site became an experimental catchment to investigate the water fluxes in the soil–plant–atmosphere continuum and the impact of vegetation on runoff generation in 2012. The elevation of the catchment ranges from 598 to 721 m a.s.l. and the climate is humid temperate. The bedrock consists of rhyolites and dacites; the soil is a Cambisol. The catchment is covered by a dense forest, dominated by beech, chestnut, maple, and hazel trees. The field set up includes measurements of the rainfall in an open area, streamflow at the outlet, soil moisture at various depths and locations, and depth to water table in six piezometers at a 5- or 10-min interval. Samples of precipitation, stream water, shallow groundwater and soil water are collected monthly for tracer analysis (stable isotopes (²H and ¹⁸O), electrical conductivity and major ions), and during selected rainfall–runoff events to determine the contribution of the various sources to runoff. Since 2017, soil and plant water samples have been collected to determine the sources of tree transpiration. Data collected in the period 2012–2016 are publicly available. Data collection is ongoing, and the data set is expected to be updated on an annual basis to include the most recent measurements.  相似文献   

In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O     

Gennaro Ventruti  Giancarlo Della Ventura  Nicola Corriero  Daniele Malferrari  Alessandro F. Gualtieri  Umberto Susta  Maria Lacalamita  Emanuela Schingaro 《Physics and Chemistry of Minerals》2016,43(8):587-595

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   

Using a regional numerical weather prediction model for GNSS positioning over Brazil     

Daniele Barroca Marra Alves  Luiz Fernando Sapucci  Haroldo Antonio Marques  Eniuce Menezes de Souza  Tayná Aparecida Ferreira Gouveia  Jackes Akira Magário 《GPS Solutions》2016,20(4):677-685

The global navigation satellite system (GNSS) can provide centimeter positioning accuracy at low costs. However, in order to obtain the desired high accuracy, it is necessary to use high-quality atmospheric models. We focus on the troposphere, which is an important topic of research in Brazil where the tropospheric characteristics are unique, both spatially and temporally. There are dry regions, which lie mainly in the central part of the country. However, the most interesting area for the investigation of tropospheric models is the wet region which is located in the Amazon forest. This region substantially affects the variability of humidity over other regions of Brazil. It provides a large quantity of water vapor through the humidity convergence zone, especially for the southeast region. The interconnection and large fluxes of water vapor can generate serious deficiencies in tropospheric modeling. The CPTEC/INPE (Center for Weather Forecasting and Climate Studies/Brazilian Institute for Space Research) has been providing since July 2012 a numerical weather prediction (NWP) model for South America, known as Eta. It has yield excellent results in weather prediction but has not been used in GNSS positioning. This NWP model was evaluated in precise point positioning (PPP) and network-based positioning. Concerning PPP, the best positioning results were obtained for the station SAGA, located in Amazon region. Using the NWP model, the 3D RMS are less than 10 cm for all 24 h of data, whereas the values reach approximately 60 cm for the Hopfield model. For network-based positioning, the best results were obtained mainly when the tropospheric characteristics are critical, in which case an improvement of up to 7.2 % was obtained in 3D RMS using NWP models.  相似文献   

The gas/steam ratio as indicator of heat transfer at the Solfatara fumaroles,Phlegraean Fields (Italy)     

R. Cioni  E. Corazza  L. Marini 《Bulletin of Volcanology》1984,47(2):295-302

A simple geochemical model of Solfatara, Phlegraean Fields (Italy), is proposed on the basis of gas composition and temperature at the surface.Data on the Solfatara fumaroles have been collected since 1979 within the framework of a geochemical monitoring for the surveillance of the Phlegraean volcanic system.Surface manifestations of Solfatara are likely to be fed through isoenthalpic expansion of dry steam, which separates from a geothermal liquid in an intensively fractured zone at about 236°C. This value is consistent both with gas composition and surface temperature.The gas/steam ratio appears to be the most effective parameter to detect changes of heat flow at depth.Actually a remarkable decrease in the gas/steam ratio has been observed since 1981, while the gas composition and the temperature did not change significantly. These facts suggest increased heat flow at depth.  相似文献   

Some remarks on the deep seismicity in the southern Tyrrhenian and its geodynamic interpretation     

Enzo Mantovani  Daniele Babbucci  Ferruccio Farsi 《Ocean Dynamics》1984,37(2):45-56

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