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We present a solid solution model, able to take into account short-range interactions up to the third nearest neighbor. This
model has been applied to illite/smectite mixed-layer clay minerals and tests the relative thermodynamic stability of each
illite/smectite stacking sequence. The non-ideal energy terms have been calculated, showing a strong decrease of the interaction
energy as the distance between elements grows. From ΔG
m calculations the model predicts the following succession in I/S stacking sequences as X
i
tends to 1:R1, R2 and then R3. This succession agrees well with some mineralogical observations in natural series.
Received: July 12, 1996 / Revised, accepted: March 21, 1997 相似文献
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Nejib Abidi Joëlle Duplay Amane Jada Raymonde Baltenweck Emna Errais Khadija Semhi Malika Trabelsi-Ayadi 《Arabian Journal of Geosciences》2017,10(16):373
Clays, particularly kaolinite, are promising adsorbents for the treatment of textile effluents, but there is a need of better understanding the mechanisms of adsorption, especially in the case of anionic dyes. Thus, the removal of RR120 anionic dye was investigated using Tunisian raw clay (TBK) composed of kaolinite and illite, and a standard kaolinite (KGa-2), and conducting batch experiments by varying different parameters (contact time, ionic strength, concentration, temperature). We investigated the clays’ surface charges by electrophoretic mobility measures and the dye-clay interactions during adsorption, by the streaming-induced potentials (SIP). The results showed that KGa-2 has higher adsorption capacity for RR120 dye than TBK clay, moreover enhanced by increasing the ionic strength and/or lowering the pH of the aqueous. The SIP results showed an increase of negative charges for both clays, reflecting the adsorption of the anionic dye on the positive charges of the amphoteric surfaces of the clays. The SIP magnitudes indicated a higher adsorption rate for KGa-2 in accordance with the kinetic study. The Sips model that described the best adsorption isotherms indicates lateral interactions of the dye molecules, stronger in the case of KGa-2 than TBK. Also, the dye molecules form a thinner layer on KGa-2 surfaces. In addition, the dye molecule’s structure was not altered, as verified by mass spectrometry. The adsorption process was feasible and spontaneous and favored at ambient temperature. Thus, kaolinite-rich clays are effective in the removal of anionic dyes in aqueous solution and potential good adsorbents in wastewater treatment. 相似文献
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Slim Khedhiri Khadija Semhi Joëlle Duplay Fadila Darragi 《Environmental Earth Sciences》2011,62(5):1013-1025
A sequential extraction procedure applied to surface sediments from El Kelbia Lagoon determined the partitioning of Ba, Co,
Cr, Cu, Ni, Sr, V and Zn among evaporites, carbonates, Fe–Mn oxides, organic matter and silicates. To validate the procedure,
the sequential extraction results (SER) were compared to principal components analysis (PCA) using major and trace element
concentrations and mineralogical quantitative data of surface sediments. SER showed that a part of Sr was highly mobile; Cu,
Sr, and Zn and a part of Co and Ni were mobile depending on pH conditions; Cr and V were strongly bound to silicate phases;
Co and Ni were partitioned between carbonates, oxides and silicates, and a great part of Ba and Sr were bound to organic matter
or sulfides. An agreement was found with PCA in terms of partitioning among minerals for most trace elements. Moreover, the
absence of correlation between Ca concentrations and the abundances of calcite, gypsum or dolomite could be explained by an
important fraction of Ca bound to organic matter. Also, unexpected negative correlations between abundances of smectite and
illite could be explained by a transformation of illite into smectite. Thus, SER and PCA were mostly convergent, which enabled:
(1) validation of the extraction procedure used, and (2) refinement of interpretations of the origin and relations between
minerals. 相似文献
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Heavy metal contamination of coastal lagoon sediments by anthropogenic activities: the case of Nador (East Morocco) 总被引：1，自引：0，他引：1
Nador lagoon sediments (East Morocco) are contaminated by industrial iron mine tailings, urban dumps and untreated wastewaters
from surrounding cities. The lagoon is an ecosystem of biological, scientific and socio-economic interests but its balance
is threatened by pollution already marked by biodiversity changes and a modification of foraminifera and ostracods shell structures.
The aim of the study is to assess the heavy metal contamination level and mobility by identifying the trapping phases. The
study includes analyses by ICP-AES and ICP-MS, of, respectively, major (Si, Al, Mg, Ca, Fe, Mn, Ti, Na, K, P) and trace elements
(Sr, Ba, V, Ni, Co, Cr, Zn, Cu, As, Pb, Cd) in sediments and suspended matter, heavy metals enrichment factors calculations
and sequential extractions. Results show that sediments contain Zn, Cu, Pb, V, Cr, Co, As, Ni with minimum and maximum concentrations,
respectively, of 4–1190 μg/g, 4–466 μg/g, 11–297 μg/g, 11–194 μg/g, 9–139 μg/g, 1–120 μg/g, 4–76 μg/g, 2–62 μg/g. High concentrations
in Zn are also present in suspended matter. The enrichment factors show contamination in Zn, Pb and As firstly induced by
the mining industry and secondly by unauthorized dumps and untreated wastewaters. Cr and Ni are bound to clays, whereas V,
Co, Cu and Zn are related to oxides. Thus, the risk in metal mobility is for the latter elements and lies in the oxidation–reduction-changing
conditions of sediments. 相似文献
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Luis Martinez Joëlle Duplay Isabel Suarez-Ruiz Jean Robert Disnar Geneviève Farjanel Philippe Larqué Nicole Liewig 《Comptes Rendus Geoscience》2002,334(14):1021-1028
Two wells, Balazuc (BA1) and Morte-Mérie (MM1), located in a confined area (1200 m apart) and separated by the Uzer fault (a Liassic structure with a dip fault of 1300 m) were analysed using conventional methodologies and techniques (PRV, TAI, XRD, STEM) in order to compare the diagenetic evolution of clays and organic matter. The thermal convective process allows the circulation of hot fluids and the oxidation of organic matter. The conductive process allows the maturation of the organic matter, the expulsion of hydrocarbons and the deposit of pyrobitumes in the migration channels. To cite this article: L. Martinez et al., C. R. Geoscience 334 (2002) 1021–1028. 相似文献
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Mazouz El Hadi Hamimed Messaoud Yahiaoui Abdelouahab Benzagouta Mohamed Said Khodja Mohamed Achi Nada Duplay Joëlle 《Arabian Journal of Geosciences》2020,13(9):1-11
The creep property of rock under cyclic loading is very important in civil engineering. In order to establish a novel constitutive equation for rock under cyclic loading, a fractional-order viscoplastic body under cyclic loading was constructed based on fractional-order viscous element. A fractional-order visco-elastoplastic model (FVEPM) for rock was established by connecting constructed fractional-order viscoplastic body with Burgers model. The model was a Burgers model when the maximum value of cyclic loading was less than the critical strength of rock; otherwise, it was a FVEPM which can be used to reflect the transient, steady-state, and tertiary creep phases of rock. The cyclic loading was decomposed into a static load and a cyclic loading with a zero average stress. According to rheological mechanics theory, the rheology constitutive equation of rock under the static load can be derived. According to viscoelastic mechanics theory, the constitutive equation under cyclic loading with a zero average stress was established by introducing the variation parameters of energy storage and energy dissipation compliance caused by rock damage and fracture. Finally, a new dynamic constitutive equation of rock cyclic loading can be obtained by superimposing the constitutive equation under static load and cyclic loading with a zero average stress. Compared with existing test results of rock under cyclic loading, the proposed constitutive model can be used to describe the creep characteristics of rock under cyclic loading and reflect the presented fluctuation of strain curve of rock under cyclic loading. 相似文献
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Khadija Semhi Joëlle Duplay Gwenaël Imfeld René Boutin 《Arabian Journal of Geosciences》2018,11(19):590
The main objective of this study is to investigate the distribution of rare earth elements (REEs) in Lolium perenne L. plant species which has been grown on vineyard soils treated with pesticide commonly used in the study area. These plants have been grown on two types of soils: (1) brown calcareous soils developed on loess and (2) brown to calcic brown soils developed on conglomerates. The significant correlation observed between the concentrations of phosphorus and the total amount of REEs, in addition to the enrichment in middle REEs (MREEs), suggests the complexation of REEs with phosphates and organic matter. The soils were enriched in REEs due to pesticide application but the plants were depleted. The ratio of REEs in plant over REEs in soil before application of pesticides is higher than that after application of pesticides. Application of pesticides to crops did not affect the fractionation of REEs neither in leaves nor in roots. No selectivity in uptake of REEs occurred because of pesticides except for Ce and Eu which show a negative anomaly relative to the other REEs. 相似文献
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The Nador lagoon ecosystem (North-East of Morocco) displays a major socioeconomic interest. In fact, it is essential to evaluate consequences of anthropogenic activities in the lagoon especially by organic matter studies (nature and distribution) in the sedimentary compartment. Surface sediments show variable rates in total organic carbon and in sulfur, high in some cases (7.5 and 1.8% respectively). These high contents are recorded in the center of the lagoon. Their distributions are controlled by the hydrodynamism and the anthropogenic degree. The molecular biomarkers analyses and especially n-alkanes distribution reveal: a zone of marine influence; and a zone of continental influence. The occurrence of pentacyclic triterpanes with a typical distribution of a thermally mature organic matter reveals a contamination due to petroleum products in the entire lagoon except for the center. Coprostanol occurrence near cities indicates wastewater effluents inputs and reducing conditions underlined by high values of stanols/sterol ratios. Thus, the organic contamination (petroleum by-products and wastewater effluents) occurs in the vicinity of the cities whereas the littoral edge and center remain weakly affected by these contaminations. 相似文献
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