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The Labrieville anorthosite massif (LBV) is found in the Central Granulite Terrain of the Grenville Structural Province, but it displays no evidence of post-emplacement deformation or metamorphism, implying intrusion following peak Grenvillian metamorphic conditions. We report U---Pb zircon dates of 1008±3.4 Ma for border leucogabbro and 1010±5.6 Ma for a cogenetic jotunite dike intruding anorthosite. We interpret these dates as igneous crystallization ages, and regard 1010 Ma as a reasonable estimate of the emplacement age for LBV. LBV is thus the youngest massif anorthosite yet recognized in North America, and its age is consistent with late-tectonic emplacement relative to the 1.1-1.0 Ga Grenville Orogeny. We also report a U---Pb date of 1015±1.8 Ma for metamorphic zircon in a country rock amphibolite. This could reflect the age of Grenvillian regional metamorphism, or perhaps a later heating episode resulting from the intrusion of numerous “late” felsic plutons in this area.
Rb---Sr, Sm---Nd and U---Th---Pb isotopic compositions for four rock types (anorthosite, jotunite, leucogabbro and a plagioclase megacryst) span narrow ranges in each case, consistent with comagmatism among these units. ISr (T=1010 Ma) range from 0.7032–0.7034 and are among the lowest yet reported for anorthosite in the Grenville Province. Initial εNd-values are positive (+0.8 to +2.5), like other Grenville anorthosites. Pb-isotopic compositions lie near the model mantle evolution curve of Zartman and Doe (1981), implying no involvement of significantly older crust in the petrogenesis of these rocks. Collectively, these data suggest a source for LBV in the mantle or mafic lower crust. LBV is a compositionally extreme anorthosite characterized by alkalic plagioclase (An32Or12) and high levels of Sr (2000 ppm) and Ba (1000 ppm). These properties cannot be attributed to simple crustal contamination of mantle-derived basalt. We suggest, alternatively, that LBV's compositional features may be linked with its late-tectonic character, perhaps reflecting partial melting of mafic lower crust brought about by crustal thickening during the Grenville Orogeny. 相似文献
2.
The “North American shale composite”: Its compilation,major and trace element characteristics 总被引：6，自引：0，他引：6
L.Peter Gromet Larry A. Haskin Randy L. Korotev Robert F. Dymek 《Geochimica et cosmochimica acta》1984,48(12):2469-2482
The compilation and major element composition of the “North American shale composite” (NASC) are reported for the first time, along with redeterminations for the REE and selected other elements by modern, high precision analytical methods. The NASC is not strictly of North American origin; 5 of the constituent samples are from Africa and Antarctica, and 15 are from unspecified locations. The major element composition of the NASC compares quite closely with other average shale compositions. New analyses of the NASC document that significant portions of the REE and some other trace elements are contained in minor phases (zircon and possibly other minerals) and that their uneven distribution in the NASC powder appears to have resulted in heterogeneity among analyzed aliquants. The results of this study show that the REE distributions of detrital sediments can be dependent to some extent on their minor mineral assemblages and the sedimentological factors that control these assemblages. Consequently, caution should be exercised in the interpretation of the REE distributions of sediment samples as they may be variable and biased relative to average REE distribution of the crustal rocks supplying detritus. These effects appear to be largely averaged out in sediment composites, with the result that their REE distributions are more likely to be representative of their provenances. 相似文献
3.
We report whole-rock, major- and trace-element compositions (obtained by XRF and INA methods) for the amphibolite-facies Buksefjorden and granulite-facies Nordland anorthosites, SW Greenland. In a previous petrologic study on the same sample suite, we documented differences in texture, mineralogy, and mineral compositions between these two anorthosite bodies. Chemical analyses confirm differences in composition between the two bodies, but these differences cannot be explained by variations in metamorphic conditions, and point towards differences in the nature of their protoliths. Analyzed Nordland samples are anorthosites and leucogabbros with 88-98% normative plagioclase, whereas those from Buksefjorden include anorthosite, leucogabbro, and gabbro with ~55-95% normative plagioclase. Two or more compositional groupings can be recognized at each site, which correspond to differences in color and mineralogy of the hand samples. Samples from Buksefjorden are mainly quartz-normative, whereas those from Nordland are olivine (- nepheline) normative. Other differences include higher Ni/Co ratio and REE contents in the granulite-facies anorthosites from Nordland. REE pattern shapes are similar, however, being moderately fractionated at ~0.5-102 chondrites with positive Eu-anomalies. Calculated equilibrium melt patterns are similar for both anorthosites, being relatively flat at ~50-1502 chondrites, suggesting unfractionated (but evolved) parental magmas. Olivine must have been present in the protoliths of the Nordland rocks compared with Buksefjorden. Otherwise, the protoliths contained plagioclase with variable An-content (~An62-An92) and a mafic component with variable Fe/Mg (mg ~0.3-0.8). This mafic component was either hornblende or a combination of ortho- and clinopyroxene in fixed proportions, plus a small amount of magnetite. Mixing calculations demonstrate that some Buksefjorden anorthosites contain two varieties of plagioclase: a calcic type that may correspond to cumulus crystals, and a sodic-type that may correspond to a trapped-melt component. On plots of normative whole-rock An versus mg, compositions of the Buksefjorden and Nordland anorthosites form crude negative arrays that differ from the generally positive trends of mafic layered intrusions (Kiglapait, Skaergaard) and from the generally flats trends of plagioclase-rich cumulate rocks (St. Urbain and Stillwater anorthosites). This difference provides further evidence for the distinctive nature of Archean calcic-anorthosite complexes compared with other types of mafic intrusions. Moreover, this distribution of data points is consistent with the assembly of the protolith of the SW Greenland anorthosites mainly as mixtures of plagioclase and hornblende. Finally, the field for the Buksefjorden and Nordland anorthosites overlaps only slightly with that for the Fiskenaesset Complex, thus extending the known range of compositions for Archean anorthosites in West Greenland. 相似文献
4.
We report new data on the major, minor and trace element compositions of metasedimentary quartzcordierite gneisses (QCG), an important member of the Archaean Malene supracrustal suite found throughout the Godthåbsfjord region of West Greenland. The analyzed QCG contain assemblages of quartz+cordierite+biotite±garnet±anthophyllite/gedrite±staurolite±sillimanite±plagioclase (with abundant accessory zircon, and minor rutile, monazite and allanite), and broadly resemble cordierite-orthoamphibole rocks found in a great number of other metamorphic terrains. Chemically, the QCG are characterized by: (1) high but variable SiO2 (59–87 wt%), relative enrichments in MgO, FeO, and Al2O3 (mg～0.35–0.85), and depletions in Na2O, K2O and especially CaO; (2) low concentrations of Sc, Cr, Co, Ni, and Sr; (3) high concentrations of Y, Nb, Zr, Hf, Ta, Th, U, and REE (rare earth elements)-with prominent negative Eu-anomalies in each case; (5) high concentrations of Ga (18–55 ppm), with variable Ga/Al ratios that are significantly higher than average crustal material. Low Cr and Ni, together with enriched and fractionated REE (displaying negative Eu-anomalies), distinguish the Malene QCG from published accounts of most other Archaean sedimentary rocks. Furthermore, all of the above-mentioned trace element characteristics distinguish the QCG from “ordinary” Malene clastic metasediments (quartzites, psammites, and pelites), suggesting a separate origin for the QCG. These data point towards chemically evolved felsic igneous rocks being the source of the QCG. Consequently, we propose that the Malene QCG represent metamorphosed felsic volcaniclastic sediments that underwent hydrothermal alteration by heated seawater prior to metamorphism, which resulted in gain of Mg (and Fe?), loss of alkalis and lime, and possibly Eu and Sr. The overall trace-element characteristics of the QCG (elevated Ga, Zr, Nb, REE, etc.) are features shared by A-type granites and their volcanic equivalents. Such igneous rocks may represent the ultimate source material for the QCG protolith. 相似文献
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6.
In this paper, we provide a detailed account of our sample fusion, calibration and instrumentation methods for major-element whole-rock analysis by XRF, and we discuss several aspects of sample preparation and instrument performance that are important considerations for accurate analysis. The fusion procedure involves moderate capital costs and is easy to apply, yielding flat, polished, homogeneous glass discs as cast. The calibration method utilizes a least-squares procedure that rigorously fits data according to both compositional and counting statistical uncertainties. We use a side-window Rh tube for analyzing major elements (including Na) and employ real-time testing for constant count rate to reject spurious results.
The methods result in excellent analytical precision and reproducibility. The standards used for calibration lie within compositional and counting statistical uncertainties of best-fit straight lines. Analyses of replicate discs and repeated analyses of single discs show excellent long-term reproducibility over several months, approaching counting statistical uncertainties in several cases. Comparison with independent measurements made by other laboratories using instrumental neutron activation and X-ray fluorescence analyses shows excellent agreement with our results.
A side-window Rh tube gives increased detection limits for most major elements, but otherwise shows little difference in precision compared to a Cr tube. This means that major and trace elements can be analyzed without changing X-ray sources, which provides saving in terms of time and money, as well as being a convenience to the analyst. 相似文献
7.
R.F. Dymek A.L. Albee A.A. Chodos G.J. Wasserburg 《Geochimica et cosmochimica acta》1976,40(9):1115-1130
Detailed mineralogic and petrographic data are presented for four isotopically-dated basaltic rock fragments separated from the howardite Kapoeta. Clasts C and ρ have been dated at ~4.55 AE and ~ 4.60 AE respectively, and Clast ρ contains 244Pu and 129I decay products. These are both igneous rocks that preserve all the features of their original crystallization from a melt. They thus provide good evidence that the Kapoeta parent body produced basaltic magmas shortly after its formation (< 100 m.y.). Clast A has yielded a Rb-Sr age of ~ 3.89 AE and a similar age. This sample is extensively recrystallized, and we interpret the ages as a time of recrystallization, and not the time of original crystallization from a melt. Clast B has yielded a Rb-Sr age of ~ 3.63 AE, and an age of ? 4.50 AE. This sample is moderately recrystallized, and the Rb-Sr age probably indicates a time of recrystallization, whereas the age more closely approaches the time of crystallization from a melt. Thus, there is no clearcut evidence for ‘young’ magmatism on the Kapoeta parent body.Kapoeta is a ‘regolith’ meteorite, and mineral-chemical and petrographic data were obtained for numerous other rock and mineral fragments in order to characterize the surface and near-surface materials on its parent body. Rock clasts can be grouped into two broad lithologic types on the basis of modal mineralogy—basaltic (pyroxene- and plagioclase-bearing) and pyroxenitic (pyroxenebearing). Variations in the compositions of pyroxenes in rock and mineral clasts are similar to those in terrestrial mafic plutons such as the Skaergaard, and indicate the existence of a continuous range in rock compositions from Mg-rich orthopyroxenites to very iron-rich basalts. The FeO and MnO contents of all pyroxenes in Kapoeta fall near a line with FeO/MnO ~ 35, suggesting that the source rocks are fundamentally related. We interpret these observations to indicate that the Kapoeta meteorite represents the comminuted remains of differentiated igneous complexes together with ‘primary’ undifferentiated basaltic rocks. The presently available isotopic data are compatible with the interpretation that this magmatism is related to primary differentiation of the Kapoeta parent body. In addition, our observations preclude the interpretation that the Kapoeta meteorite is a simple mixture of eucrites and diogenites.The FeO/MnO value in lunar pyroxenes (~60) is distinct from that of the pyroxenes in Kapoeta. Anorthositic rocks were not observed in Kapoeta, suggesting that plagioclase was not important in the evolution of the Kapoeta parent body, in contrast to the Moon. Both objects appear to have originated in chemically-distinct portions of the solar system, and to have undergone differentiation on different time scales involving differing materials. 相似文献
8.
Mafic orthopyroxene monzodiorite (jøtunite) lithologies are exposed in the St. Urbain plutonic suite as a marginal facies to quartz mangerite and massif anorthosite intrusive bodies and as dikes within a variety of host rocks. High concentrations of Ti, Fe, P, K, Ba, Nb, La, Ce, Zn, Ga, Zr and Y characterize these rocks and are distinctive of many mafic lithologies associated with anorthosite massifs worldwide. Characteristically low concentrations of Ni and Cr, in conjuction with low Mg numbers, have been used by previous investigators as evidence for either partial melting of mafic granulitic lower crust or extensive fractional crystallization of a mantle-derived magma. In an attempt to distinguish between these competing models, we note that jøtunite display many features that bear a strong resemblance to continental tholeiitic flood basalts, including chemical signatures on normalized multi-element (‘spider’) diagrams. Ratios of incompatible trace elements and patterns on rare earth and ‘spider’ diagrams collectively indicate that the jøtunite rocks were derived from an enriched, rather than depleted, mantle source. Enrichment may have occured by subduction-derived fluids or by mixture with a plume component prior to partial melting so that isotopic and trace-element compositions are decoupled. Small amounts of partial melting of mafic granulite has been advanced as an alternative model; we show, however, that the experimental data on which this model is built are not applicable. Our preferred model begins with partial melting of a trace-element enriched mantle source that fractionates olivine at high to moderate pressures. Increasing concentrations of P (and Ti) eventually caused a contraction of the olivine stability field in favor of orthopyroxene. Fractional crystallization may yield the series of rocks from anorthosite, leuconorite, oxide-apatite gabbronorite, to jøtunite. Mafic magmas emplaced into continental crust are typically attributed to incipient rifting or mantle upwelling, which are features common to many models for the genesis of anorthosite and related rocks. 相似文献
9.
We report new field and petrographic observations, and mineral-chemical data, on the amphibolite-facies Buksefjorden and
granulite-facies Nordland anorthosites, which occur in different tectonostratigraphic terranes within the Archaean gneiss
complex of SW Greenland. The Buksefjorden body [from the Akulleq (middle) terrane] is dominated by plagioclase and Ca-amphibole,
but shows widespread effects of retrograde hydration (epidote, chlorite). Most plagioclase compositions are in the An60–82 range, with the majority of samples showing average core compositions ∼An76, whereas rims or recrystallized margins are ∼An65. Most grains in the An70–82 range display optically visible Huttenlocher intergrowths. Amphiboles at Buksefjorden are mainly magnesio-hornblende with
X
Mg ranging from 0.70 to 0.45. The Nordland anorthosite [from the Akia (northern) terrane] is also dominated by plagioclase and
Ca-amphibole, but contains additional clinopyroxene (∼Ca47Mg38Fe15) as well as minor orthopyroxene (∼En68), spinel and corundum. Plagioclase at Nordland shows an equilibrated, equigranular texture, consistent with prolonged slow
cooling from high temperatures. Despite this textural equilibration, plagioclase at Nordland shows a striking range of compositions
from An28 to An97, most of which is found in single thin sections. A distinctive feature is the presence of discrete anorthite (+ spinel ±
corundum) domains in some samples. Although a number of explanations may apply, we consider these domains to result from prograde
mass transfer reactions involving Ca-amphibole and plagioclase. Amphibole compositions at Nordland show similar X
Mg to those at Buksefjorden, but are more aluminous, alkalic, and titanian. This shift to more pargasitic compositions is consistent
with the contrasts in metamorphic grade between the two anorthosite bodies. At Buksefjorden, there is no correlation between
the amount of modal Ca-amphibole and plagioclase composition, which would be expected if amphibole was produced solely through
metamorphism. Our results suggest, alternatively, that the primary igneous mineralogy of these rocks may have been plagioclase
(∼An76) + hornblende + pyroxene + magnetite. The primary mineralogy at Nordland is less certain, but it is noteworthy that no rocks
contain anorthite of unambiguous igneous origin, in contrast to some other occurrences of Archaean anorthosites.
Received: 17 January 1996 / Accepted: 12 March 1997 相似文献
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