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The effect of ductile deformation on the kinetics and mechanisms of the aragonite-calcite transformation 总被引：2，自引：0，他引：2
Abstract The effect of ductile deformation (dislocation creep) on the kinetics of the aragonite-calcite transformation has been studied at 1 atm (330° C and 360° C) and 900-1500 MPa (500° C) using undeformed and either previously or simultaneously deformed samples (500° C and a strain rate of 10-6 s). Deformation enhances the rate of the transformation of calcite to aragonite, but decreases the rate of transformation of aragonite to calcite. The difference results from a dependence of transformation rate on grain size, coupled with a difference in the accommodation mechanisms, climb versus recry-stallization, of these minerals during dislocation creep. Dislocation climb is relatively easy in calcite and thus plastic strain results in high dislocation densities without significant grain size reduction. The rate of transformation to aragonite is enhanced primarily because of the increase in nucleation sites at dislocations and subgrain boundaries. In aragonite, on the other hand, dislocation climb is difficult and thus plastic strain produces extensive dynamic recry-stallization resulting in a substantial grain size reduction. The transformation of aragonite is inhibited because the increase in calcite nucleation sites at dislocations and/or new grain boundaries is more than offset by the inability of calcite to grow across high angle grain boundaries. Thus the net effect of ductile deformation by dislocation creep on the kinetics of polymorphic phase transformations depends on the details of the accommodation mechanism. 相似文献
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Garnet-field Melting and Late-stage Refertilization in 'Residual' Abyssal Peridotites from the Central Indian Ridge 总被引：17，自引：0，他引：17
HELLEBRAND ERIC; SNOW JONATHAN E.; HOPPE PETER; HOFMANN ALBRECHT W. 《Journal of Petrology》2002,43(12):2305-2338
The role of residual garnet during melting beneath mid-oceanridges has been the subject of many recent investigations. Toaddress this issue from the perspective of melting residues,we obtained major and trace element mineral chemistry of residualabyssal peridotites from the Central Indian Ridge. Many clinopyroxeneshave ratios of middle to heavy rare earth elements (MREE/HREE)that are too low to be explained by melting in the stabilityfield of spinel peridotite alone. Several percent of meltingmust have occurred at higher pressures in the garnet peridotitestability field. Application of new trace element partitioningmodels, which predict that HREE are compatible in high-pressureclinopyroxene, cannot fully explain the fractionation of theMREE from the HREE. Further, many samples show textural andchemical evidence for refertilization, such as relative enrichmentsof highly incompatible trace elements with respect to moderatelyincompatible trace elements. Therefore, highly incompatibleelements, which are decoupled from major and moderately incompatibletrace elements, are useful to assess late-stage processes, suchas melt entrapment, melt–rock reaction and veining. Moderatelyincompatible trace elements are less affected by such late-stageprocesses and thus useful to infer the melting history of abyssalperidotites. KEY WORDS: abyssal peridotites; mantle melting; garnet 相似文献
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The Buck Creek ultramafic body, North Carolina, includes aluminous lenses that have been described as troctolites. These lenses preserve mineral assemblages which record several different stages of metamorphism. The first stage is characterized by anhydrous reactions between olivine and plagioclase to produce coronas of orthopyroxene+ clinopyroxene/spinel symplectite. Thermo barometric results indicate minimum pressures of c. 6 kbar and c. 800 oC. Sapphirine replaces spinel in some clinopyroxene symplectites, and occurs as anhedral grains within amphibole, observations which in combination suggest peak metamorphic conditions of c. 9-10 kbar and c. 850 oC. Sapphirine-bearing hydrous assemblages formed at the expense of the coronas, indicating a second metamorphic episode involving deeper burial, deformation and hydration. Schistose rocks from the margins of the lenses are composed of anorthite+amphibole+margarite+corundum, and probably record a later, lower P-T event. Whole rock analyses for the Buck Creek lenses suggest an accumulate protolith of magnesian olivine and calcic plagioclase. Trace element data for the troctolites are consistent with data for adjacent amphibolites in suggesting that the Buck Creek mafic and ultramafic cumulates crystallized from magmas derived from a mantle source similar to that which produces modern intraplate or rift-related basalts. We propose that the Buck Creek ultramafics represent basal cumulates(± uppermost mantle) from ocean crust formed in a marginal basin in the latest Precambrian. Subduction-induced burial to at least 18 km under dry conditions induced corona formation. Collisional events of the Taconic orogeny thrust the Buck Creek rocks into the orogenic pile to at least 30 km depth and hydrated them along zones of weakness, locally producing P-T -PH2O conditions appropriate for formation of sapphirine and hydrated assemblages, but still preserving some dry symplectites. 相似文献
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