Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal     

A. van Geen  K. Radloff  Z. Aziz  Z. Cheng  M.R. Huq  K.M. Ahmed  B. Weinman  S. Goodbred  H.B. Jung  Y. Zheng  M. Berg  P.T.K. Trang  L. Charlet  J. Metral  D. Tisserand  S. Guillot  S. Chakraborty  A.P. Gajurel  B.N. Upreti 《Applied Geochemistry》2008

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.  相似文献   

Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry     

Martha Gledhill  Constant M. G. van den Berg 《Marine Chemistry》1995,50(1-4)

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.  相似文献   

Non-local impact of large-scale engineering in harbors and gulfs on the environment     

Eduard  Svetlana  Valentin 《Ocean Engineering》2002,29(7):739-752

A system of numerical tools to predict the non-local long-term impact of large-scale constructions on the environment is described. The predictions have to be results of successive examination of free water oscillations, turbulent boundary layers on the sea bottom, and turbulent pulsation effects on sediment transport. Numerical results related to free water oscillations in diverse gulfs are shown, and non-local effects of the dam construction are found for an example of the Baltic Sea. Feasibility of suggested tools for turbulent flow is manifested.  相似文献   

Quasi-linear theory of waves and ship wave resistance in restricted waters   总被引：2，自引：0，他引：2  

Eduard Amromin  Svetlana Kovinskaya  Igor Mizine 《Ocean Engineering》2004,31(10):53-1244

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A Gamma/Dirichlet model for estimating uncertainty in age-specific abundance of Norwegian spring-spawning herring     

Host  Gudmund; Berg  Erlend; Schweder  Tore; Tjelmeland  Sigurd 《ICES Journal of Marine Science》2002,59(4):737-748

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An integral equation approach for 2.5-dimensional forward and inverse electromagnetic scattering     

Aria Abubakar  Peter M van den Berg  Tarek M Habashy 《Geophysical Journal International》2006,165(3):744-762

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Towards non-linear inversion for characterization of time-lapse phenomena through numerical modelling     

A. Abubakar  P.M. van den Berg  J.T. Fokkema 《Geophysical Prospecting》2003,51(4):285-293

We compare two geophysical survey measurements of the same type made at different times in order to characterize the change in the geological medium during the elapsed time. The aim of this study is to develop a strategy using a full non-linear inversion algorithm as the interpretation tool. In this way, not only the location and the form of the changes are recovered, but also the changes in the material parameters of the geological medium can be estimated. In order to solve this fully non-linear problem, the so-called ‘multiplicative regularized contrast source inversion’ (MR-CSI) method is employed. The unique property of this iterative method is that it does not solve the forward problem at each iterative step. This makes it possible to use the non-linear inversion algorithm for large-scale computation problems. The numerical results show that by taking into account the non-linear nature of the problem, interpretation of the time-lapse data can be significantly improved, compared with that obtained using linear inversion.  相似文献   

Smithsonian institution's global volcanism network     

Eduard Venzke 《Bulletin of Volcanology》2005,68(1):93-94

Information included in this summary is based on more detailed reports published in the Bulletin of the Global Volcanism Network, vol. 30, no. 2, February 2005 (on the Internet at ). Edited by scientists at the Smithsonian, this Bulletin includes reports provided by a worldwide network of correspondents. The reports contain the names and contact information for all sources. Please note that these reports are preliminary and subject to change as events are studied in more detail. The Global Volcanism Program welcomes further reports of current volcanism, seismic unrest, monitoring data, and field observations.  相似文献   

Seismic velocities of granulite-facies xenoliths from Central Ireland: Implications for lower crustal composition and anisotropy     

Riana van den Berg  J. Stephen Daly  Matthew H. Salisbury   《Tectonophysics》2005,407(1-2):81-99

V_p and V_s values have been measured experimentally and calculated for granulite-facies lower crustal xenoliths from central Ireland close to the Caledonian Iapetus suture zone. The xenoliths are predominantly foliated and lineated metapelitic (garnet–sillimanite–K-feldspar) granulites. Their metapelitic composition is unusual compared with the mostly mafic composition of lower crustal xenoliths world-wide. Based on thermobarometry, the metapelitic xenoliths were entrained from depths of c. 20–25 ± 3.5 km and rare mafic granulites from depths of 31–33 ± 3.4 km. The xenoliths were emplaced during Lower Carboniferous volcanism and are considered to represent samples of the present day lower crust.V_p values for the metapelitic granulites range between 6.26 and 7.99 km s^{− 1} with a mean value of 7.09 ± 0.4 km s^{− 1}. Psammite and granitic orthogneiss samples have calculated V_p values of 6.51 and 6.23 km s^{− 1}, respectively. V_s values for the metapelites are between 3.86 and 4.34 km s^{− 1}, with a mean value of 4.1 ± 0.15 km s^{− 1}. The psammite and orthogneiss have calculated V_s values of 3.95 and 3.97 km s^{− 1}, respectively.The measured seismic velocities correlate with density and with modal mineralogy, especially the high content of sillimanite and garnet. V_p anisotropy is between 0.15% and 13.97%, and a clear compositional control is evident, mainly in relation to sillimanite abundance. Overall V_s anisotropy ranges from 1% to 11%. Poisson's ratio (σ) lies between 0.25 and 0.35 for the metapelitic granulites, mainly reflecting a high V_p value due to abundant sillimanite in the sample with the highest σ. Anisotropy is probably a function of deformation associated with the closure of the Iapetus ocean in the Silurian as well as later extension in the Devonian. The orientation of the bulk strain ellipsoid in the lower crust is difficult to constrain, but lineation is likely to be NE–SW, given the strike-slip nature of the late Caledonian and subsequent Acadian deformation.When corrected for present-day lower crustal temperature, the experimentally determined V_p values correspond well with velocities from the ICSSP, COOLE I and VARNET seismic refraction lines. Near the xenolith localities, the COOLE I line displays two lower crustal layers with in situ V_p values of 6.85–6.9 and 6.9–8.0 km s^{− 1}, respectively. The upper (lower velocity) layer corresponds well with the metapelitic granulite xenoliths while the lower (higher velocity) layer matches that of the basic granulite xenoliths, though their metamorphic pressures suggest derivation from depths corresponding to the present-day upper mantle.  相似文献   

Distinguishing the effect of diapir growth on magnetic fabrics of syn‐diapiric overburden rocks: Basque–Cantabrian basin,Northern Spain          下载免费PDF全文

Ruth Soto  Elisabet Beamud  Eduard Roca  Eloi Carola  Ylenia Almar 《地学学报》2017,29(3):191-201

An analysis of Anisotropy of Magnetic Susceptibility was done on Aptian–Albian sediments from the Basque–Cantabrian basin. Samples were collected from 39 sites in the halokinetic sequences of the Bakio, Bermeo, Guernica and Mungia diapirs; 28 sites were sampled close to diapirs, and 11 sites were far from the diapir edges. The magnetic foliation is parallel to bedding, suggesting it reflects depositional and compaction processes, whereas the orientation of magnetic lineation varies. Far from the diapir edges, the magnetic lineation is interpreted as being related to the regional Pyrenean compression. Close to diapir edges, the observed behaviour shows that diapirs, predominantly formed by rigid ophites, have acted as buttresses, with shadow areas at their northern faces being protected from the Pyrenean compression. The high sensitivity of AMS makes it a very useful tool to distinguish deformation in halokinetic sequences related to diapir growth from that related to subsequent compression.  相似文献