Decomposition of Hudson estuary macrophytes: Photosynthetic pigment transformations and decay constants     

Thomas S. Bianchi  Stuart Findlay 《Estuaries and Coasts》1991,14(1):65-73

Plant pigment decay constants were determined for four macrophytes collected from the Hudson Estuary.Typha angustifolia andScirpus fluviatilis were used as representatives of emergent aquatic vegetation (EAV), andPotamogeton sp. andVallisneria americana were used to represent submerged aquatic vegetation (SAV). Litter bags were maintained in an environmental chamber in the dark for 104 d. The fastest rate of total mass loss was in the SAVV. americana and slowest in the EAVT. angustifolia. Changes in carotenoid and chloropigment concentration resulting from microbial and meiofaunal heterotrophy in each of the macrophytes were quantified using reverse-phase, high-performance liquid chromatography (RP-HPLC) techniques. Chlorophyllc and the carotenoid, fucoxanthin, provided useful biomarkers in determining the presence of epiphytic diatom growth, which only occurred on the SAV. The highest concentrations of phaeophorbidea, commonly used as an indication of metazoan grazing, were found in the SAVV. americana. Low concentrations of phaeophorbidea in the SAVPotamogeton sp. indicate inefficient use of this SAV by meiofaunal grazers. Lutein decayed slower than all other carotenoids in both EAV and SAV. Microcosm studies such as this are necessary to further understand the mechanisms and kinetics of photosynthetic pigment transformations in natural systems.  相似文献   

Preservation conditions and the use of sediment pigments as a tool for recent ecological reconstruction in four Northern European estuaries   总被引：4，自引：0，他引：4  

N. Reuss  D.J. Conley  T.S. Bianchi 《Marine Chemistry》2005,95(3-4):283-302

Down-core sediment pigment concentrations from four Northern European estuaries were measured using high-performance liquid chromatography (HPLC) to investigate phytoplankton community structure and preservation conditions over the last ca. 100 years where all sites have experienced different levels of eutrophication. Phytoplankton pigments have been shown to be useful biomarkers for phytoplankton community structure and abundance due to their taxonomic specificity. The pigment concentrations and sediment pigment inventory showed large variation between the four sites. Concentrations ranged from more than 6000 nmol/g OC to less than 100 nmol/g OC and the inventory integrated over the top 10 cm from more than 300 nmol/cm² to less than 30 nmol/cm² for total identified pigments. Good pigment preservation in Mariager Fjord (Denmark) reflected the almost permanently anoxic conditions. Pigments in Laajalahti (Finland) showed peak concentrations around the time of highest nitrogen loading events known from historical and modelled records over the past 100 years. In contrast, poor down-core preservation of pigments (especially carotenoids) was observed in the Ems-Dollard (The Netherlands) and Himmerfjärden (Sweden) estuaries. The Ems-Dollard site is an intertidal mudflat that experiences daily exposure to light and air, which enhances pigment degradation. In Himmerfjärden, resuspension is an important process affecting both the sedimentation rate and degradation properties. The different preservation conditions at the four sites were supported by the differences in two degradation indicators; the ratio of pheopigment-a to chlorophyll-a and total carotenoids to total pigments. Class-specific carotenoid pigments represented the dominant algal groups reported from each site, however, no distinct down-core changes in the pigment composition were observed at any of the four sites. This indicated that changes in plankton community structure on the group level have been limited over this time period or masked by low preservation of pigments.  相似文献   

Particulate and dissolved amino acids in the lower Mississippi and Pearl Rivers (USA)     

Shuiwang Duan  Thomas S. Bianchi 《Marine Chemistry》2007

In this study, we present seasonal changes (monthly samples from September 2001 to August 2003) in the abundance and composition of dissolved and particulate amino acids, at one station in the lower Mississippi and Pearl Rivers (LA, MS: USA). Spatial changes over a 4-day transmit from river km 390 to river mouth (Head of Passes, LA) in the Mississippi River, and a two-day downstream sampling from Jackson (MS) to Stennis Space Center (MS) were also determined. Temporal data in the lower Mississippi River showed significantly lower concentrations of dissolved combined amino acids (DCAA, 0.8 to 2.2 μM) and dissolved amino acids in high molecular weight fraction (HMW DAA, 0.2–0.4 μM) than in the Pearl River (DCAA, 1.4–4.3 μM; HMW DAA, 0.4–1.4 μM). Dissolved free amino acids (DFAA) were significantly lower than DCAA in both rivers, and displayed minimal seasonal variability. DCAA, HMW DAA, and particulate amino acids (PAA) were generally higher during high-flow periods, which may have suggested dominance in terrestrial sources. Carbon-normalized yield of PAA (%C-PAA) was generally higher during low-flow conditions and positively correlated with chlorophyll-a (chl-a), reflective of in situ sources. Downstream variability in the lower Mississippi River showed stable DCAA concentrations, a decline in PAA (from 1.06 to 0.43 μM), and a gradual increase in mole percent of non-protein amino acids (%NPAA). This likely reflected bacterial degradation of phytoplankton biomass during falling discharge. Nitrogen-normalized yield of PAA (%N-PAA) was inversely correlated with PAA (R = − 0.7, n = 48), indicative of short-term sedimentation and resuspension events. Conversely, downstream decreases in DCAA and middle-reach peaks of PAA and %N-PAA in the Pearl River, likely resulted from photochemical degradation of DOM as well as algal production during base-flow conditions. The comparisons in abundance and composition of DAA and PAA in these different river systems provides important information on in situ nitrogen and carbon cycling as related to riverine inputs of organic matter to coastal ocean.  相似文献   

Carbon cycling in a shallow turbid estuary of southeast Texas: The use of plant pigment biomarkers and water quality parameters     

Thomas S. Bianchi  M. Baskaran  Joseph DeLord  M. Ravichandran 《Estuaries and Coasts》1997,20(2):404-415

Particulate organic carbon (POC), dissolved organic carbon (DOC), and plant pigments (chlorophylls and carotenoids) were measured approximately bimonthly from March 1992 to October 1993 in the Sabine-Neches estuary (Sabine Lake region), located on the Texas-Louisiana border. High freshwater inflow into this shallow turbid estuary results in the shortest hydraulic residence time (ca. 7 d) of all Texas estuaries (Baskaran et al. in press). Annual averages of chlorophyll-a (3.0 μg l^?1) and particulate organic carbon (1.1 mg l^?1) in the water column were extremely low in comparison to other shallow estuaries. The highest chlorophyll-a concentrations were observed in October 1993, in the mid and lower regions of the estuary, during the lowest river discharge. Zeaxanthin and fucoxanthin concentrations suggested that much of the chlorophyll-a during this low flow period was represented by cyanobacteria and diatoms that entered from the Gulf of Mexico. The range of DOC concentrations was generally high (4.4–20.9 mg l^?1) and were significantly correlated with POC, but not with chlorophyll-a concentrations. When total suspended particulate (TSP) concentrations were below 20 to 30 mg l^?1, there were significant increases in %POC and %PON of the TSP. The unusually high POC: chlorophyll-a ratios (highest value of 1423) suggested that much of the POC contained low concentrations of chlorophyll-a that had degraded during transport from wetlands in the Sabine and Neches rivers. Based on these data, this estuary can be characterized as a predominantly heterotrophic system, with low light penetrance, short particle-residence times, high DOC, and low inputs from autochthonous carbon sources.  相似文献   

Seismic studies of the Brasília fold belt at the western border of the São Francisco Craton, Central Brazil, using receiver function, surface-wave dispersion and teleseismic tomography     

Marcelo Assumpo  Meijian An  Marcelo Bianchi  George S.L. Frana  Marcelo Rocha  Jos Roberto Barbosa  Jesús Berrocal 《Tectonophysics》2004,388(1-4):173

The Tocantins Province in Central Brazil is composed of a series of SSW–NNE trending terranes of mainly Proterozoic ages, which stabilized in the Neoproterozoic in the final collision between the Amazon and São Francisco cratons. No previous information on crustal seismic properties was available for this region. Several broadband stations were used to study the regional patterns of crustal and upper mantle structure, extending the results of a recent E–W seismic refraction profile. Receiver functions and surface wave dispersion showed a thin crust (33–37 km) in the Neoproterozoic Magmatic Arc terrane. High average crustal Vp/Vs ratios (1.74–1.76) were consistently observed in this unit. The foreland domain of the Brasília foldbelt, on the other hand, is characterized by thicker crust (42–43 km). Low Vp/Vs ratios (1.70–1.72) were observed in the low-grade foreland fold and thrust zone of the Brasília belt adjacent to the São Francisco craton. Teleseismic P-wave tomography shows that the lithospheric upper mantle has lower velocities beneath the Magmatic Arc and Goiás Massif compared with the foreland zone of the belt and São Francisco craton. The variations in crustal thickness and upper mantle velocities observed with the broadband stations correlate well with the measurements along the seismic refraction profile. The integration of all seismic observations and gravity data indicates a strong lithospheric contrast between the Goiás Massif and the foreland domain of the Brasília belt, whereas little variation was found across the foldbelt/craton surface boundary. These results support the hypothesis that the Brasília foreland domain and the São Francisco craton were part of a larger São Francisco-Congo continental plate in the final collision with the Amazon plate.  相似文献   

Multi-hazard assessment in Europe under climate change   总被引：2，自引：0，他引：2  

Giovanni Forzieri  Luc Feyen  Simone Russo  Michalis Vousdoukas  Lorenzo Alfieri  Stephen Outten  Mirco Migliavacca  Alessandra Bianchi  Rodrigo Rojas  Alba Cid 《Climatic change》2016,137(1-2):105-119

  相似文献   

Impact of model complexity and multi-scale data integration on the estimation of hydrogeological parameters in a dual-porosity aquifer     

Elena Tamayo-Mas  Marco Bianchi  Majdi Mansour 《Hydrogeology Journal》2018,26(6):1917-1933

This study investigates the impact of model complexity and multi-scale prior hydrogeological data on the interpretation of pumping test data in a dual-porosity aquifer (the Chalk aquifer in England, UK). In order to characterize the hydrogeological properties, different approaches ranging from a traditional analytical solution (Theis approach) to more sophisticated numerical models with automatically calibrated input parameters are applied. Comparisons of results from the different approaches show that neither traditional analytical solutions nor a numerical model assuming a homogenous and isotropic aquifer can adequately explain the observed drawdowns. A better reproduction of the observed drawdowns in all seven monitoring locations is instead achieved when medium and local-scale prior information about the vertical hydraulic conductivity (K) distribution is used to constrain the model calibration process. In particular, the integration of medium-scale vertical K variations based on flowmeter measurements lead to an improvement in the goodness-of-fit of the simulated drawdowns of about 30%. Further improvements (up to 70%) were observed when a simple upscaling approach was used to integrate small-scale K data to constrain the automatic calibration process of the numerical model. Although the analysis focuses on a specific case study, these results provide insights about the representativeness of the estimates of hydrogeological properties based on different interpretations of pumping test data, and promote the integration of multi-scale data for the characterization of heterogeneous aquifers in complex hydrogeological settings.  相似文献   

Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans     

Mariana Vezzone  Ricardo Cesar  Helena Polivanov  Aline Serrano  Danielle Siqueira  Leticia Abreu  Miriam Bianchi  Maria Elizabeth Correia  Zuleica Castilhos  Tácio de Campos 《Environmental Earth Sciences》2018,77(21):743

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.  相似文献   

Hydrodynamic and isotopic investigations for evaluating the mechanisms and amount of groundwater seepage through a rockslide dam     

Marco Petitta  Gabriele Scarascia Mugnozza  Maurizio Barbieri  Gianluca Bianchi Fasani  Carlo Esposito 《水文研究》2010,24(24):3510-3520

This study addresses the influence of landslide dams on surface water drainage and groundwater flow. In the study area of Scanno Lake and Sagittario River (Central Italy), a limestone rockslide‐avalanche formed a lake, which has an outlet that is occasionally active, showing infiltration into the rockslide dam. Several springs are present at the lake's base and are partly fed by seepage through the rockslide debris. Piezometric surveys, discharge measurements, pumping tests and chemical analyses are tools used to build a conceptual model of the groundwater flow and to evaluate the flow through the rockslide debris. Seasonal water isotopic signatures validate the assumed model, showing a mixing of infiltration recharge and groundwater seepage throughout the rockslide debris. Various recharge areas have been found for springs, pointing out those directly fed by the rockslide debris aquifer. Hypotheses about seasonal groundwater mixing between the regional carbonate aquifer and the rockslide debris aquifer are supported by isotope results. Seasonal changes in groundwater table level due to recharge and surface losses from seasonal outlet have been correlated with isotopic groundwater composition from the rockslide debris aquifer and the downstream springs; this relationship highlights the role of the rockslide dam body on the hydrodynamics of the studied area. Relationships between surface waters and groundwater in the area have been completely understood on the basis of water isotopic fingerprinting, finally obtaining a complete evaluation of groundwater renewable resources and its regimen. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Evaluation of antifouling properties of non-toxic marine paints     

Abdellatif Mellouki  Armand Bianchi  Alain Perichaud  Georges Sauvet 《Marine pollution bulletin》1989,20(12):612-615

The most common way to prevent biofouling of immersed surfaces is to coat the exposed surfaces with a paint containing a biocide acting on marine organisms by diffusion into the surrounding water. However diffusion of toxins into the marine environment causes pollution and serious economic problems. This paper outlines the anti-microfouling properties of some insolubilized quaternary ammonium salts (grafted onto a vinyl copolymer by means of a covalent non-hydrolyzable bond). After immersion times in sea-water up to 4 months, the microbial cover was limited to bacterial forms, without microalgae or cyanobacteria as observed on the untreated, or tin-salt painted surfaces. Bacteria are mostly on unicell forms and numerous areas appear free of any microorganisms. As microbiofouling is an obligate step to macrofouling, this unleachable antifouling treatment could result in a prolonged protection.  相似文献