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The fractionation of sulfur isotopes by the thermophilic chemolithoautotrophic Thermodesulfatator indicus was explored during sulfate reduction under excess and reduced hydrogen supply, and the full temperature range of growth (40-80 °C). Fractionation of sulfur isotopes measured under reduced H2 conditions in a fed-batch culture revealed high fractionations (24-37‰) compared to fractionations produced under excess H2 supply (1-6‰). Higher fractionations correlated with lower sulfate reduction rates. Such high fractionations have never been reported for growth on H2. For temperature-dependant fractionation experiments cell-specific rates of sulfate reduction increased with increasing temperatures to 70 °C after which sulfate-reduction rates rapidly decreased. Fractionations were relatively high at 40 °C and decreased with increasing temperature from 40-60 °C. Above 60 °C, fractionation trends switched and increased again with increasing temperatures. These temperature-dependant fractionation trends have not previously been reported for growth on H2 and are not predicted by a generally accepted fractionation model for sulfate reduction, where fractionations are controlled as a function of temperature, by the balance of the exchange of sulfate across the cell membrane, and enzymatic reduction rates of sulfate. Our results are reproduced with a model where fractionation is controlled by differences in the temperature response of enzyme reaction rates and the exchange of sulfate in and out of the cell.  相似文献   
3.
In this paper we describe the transport of pollution in groundwater in the neighbourhood of a well in a uniform background flow. We compute the rate at which contaminated particles reach the well as a function of the place of the source of pollution. The motion of a particle in a dispersive flow is seen as a random walk process. The Fokker-Planck equation for the random motion of a particle is transformed using the complex potential for the advective flow field. The resulting equation is solved asymptotically after a stretching transformation. Finally, the analytical solution is compared with results from Monte Carlo simulations with the random walk model. The method can be extended to arbitrary flow fields. Then by a numerical coordinate transformation the analytical results can still be employed.  相似文献   
4.
Evert Lagrou 《GeoJournal》2000,51(1-2):99-112
The paper describes the different capital city functions that are accomodated in Brussels. There are in fact five different capitals in Brussels in search of a place. Their locations are conditioned by Brussels' eventful history. The analysis subsequently focuses on the rather negative relation between the local public intellectuals and the city's European capital functions. The location of the European headquarters within the existing urban fabric – unlike Luxemburg and Strasbourg – has caused residential expulsion and further confrontations with the local community during all expansions.Brussels has the most politically decisive institutions. The competition with Luxemburg and Strasbourg has in the past given rise to dubious building processes and hidden agendas regarding the further construction of the necessary space for Europe.Unlike most other capitals Brussels has a low degree of esteem from its citizens. The After-May 68- Movement reacting initially against the CIAM-realisations during the 1970s, continues its activities up until today against two highly symbolic projects: the North Station area called the Manhattan Quarter and the European Headquarters. The movement launched the term Brusselization on the international forum and continues to promote the negative image of its city – notwithstanding the complete change of the official urban planning.The article is a plea for the integration of the actual one-sided advocacy planning within a more comprehensive urban planning approach where strong and soft functions are more in balance. This can also improve the quality of the new European campus now under consideration to accomodate the entry of the East European states in the Union.  相似文献   
5.
In an attempt to discriminate between tectonically induced sea-level changes and glacio-eustacy, the Ekklissia and Arakthos sections (Epirus, NW Greece) are examined, applying (dinocyst) palynology, sedimentology and magnetostratigraphy. The sections, located in the Pindos Foreland Basin, both comprise the transition from pelagic limestones to hemipelagic silty clays and turbidite sandstones, reflecting the onset of flysch sedimentation as a result of the Pindos thrust activity. Despite an overall tectonic overprint, relative changes of sea level can be reconstructed, using (i) continental/marine palynomorph ratios, (ii) relative abundance of inshore and offshore dinoflagellate cysts, and (iii) taxa indicative of relatively cold and warm sea-surface temperature, that can be calibrated against the Global Polarity Time Scale (GPTS). Increased fluxes of marginal marine and continental palynomorphs coincide with colder periods on a 'third-order' scale, which thus appear to be related to glacio-eustatic trends in sea-level. The larger scale is attributed to the increasing effect of tectonics and acts on a 'second-order scale'.  相似文献   
6.
The Niers valley was part of the Rhine system that came into existence during the maximum Saalian glaciation and was abandoned at the end of the Weichselian. The aim of the study was to explain the Late Pleniglacial and Late Glacial fluvial dynamics and to explore the external forcing factors: climate change, tectonics and sea level. The sedimentary units have been investigated by large‐scale coring transects and detailed cross‐sections over abandoned channels. The temporal fluvial development has been reconstructed by means of geomorphological relationships, pollen analysis and 14C dating. The Niers‐Rhine experienced a channel pattern change from braided, via a transformational phase, to meandering in the early Late Glacial. This change in fluvial style is explained by climate amelioration at the Late Pleniglacial to Late Glacial transition (at ca. 12.5 k 14C yr BP) and climate‐related hydrological, lithological and vegetation changes. A delayed fluvial response of ca. 400 14C yr (transitional phase) was established. The channel transformations are not related to tectonic effects and sea‐level changes. Successive river systems have similar gradients of ca. 35–40 cm km?1. A meandering river system dominated the Allerød and Younger Dryas periods. The threshold towards braiding was not crossed during the Younger Dryas, but increased aeolian activity has been observed on the Younger Dryas point bars. The final abandonment of the Niers‐Rhine was dated shortly after the Younger Dryas to Holocene transition. Traces of Laacher See pumice have been found in the Niers valley, indicating that the Niers‐Rhine was still in use during the Younger Dryas. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
7.
In the transformation from tidal systems to freshwater coastal landscapes, plants act as eco-engineering species that reduce hydrodynamics and trap sediment, but nature and timing of the mechanisms of land creation along estuaries remains unclear. This article focuses on the Old Rhine estuary (The Netherlands) to show the importance of vegetation in coastal landscape evolution, predominantly regarding tidal basin filling and overbank morphology. This estuary hosted the main outflow channel of the river Rhine between ca 6500 to 2000 cal bp , and was constrained by peat during most of its existence. This study reconstructs its geological evolution, by correlating newly integrated geological data and new field records to varying conditions. Numerical modelling was performed to test the inferred mechanisms. It was found that floodbasin vegetation and resulting organic accumulation strongly accelerated back-barrier infill, by minimizing tidal influence. After tidal and wave transport had already sufficiently filled the back-barrier basin, reed rapidly expanded from its edges under brackish conditions, as shown by diatom analysis and datings. Reed growth provided a positive infilling feedback by reducing tidal flow and tidal prism, accelerating basin infilling. New radiocarbon dates show that large-scale crevassing along the Old Rhine River – driven by tidal backwater effect – only started as nutrient-rich river water transformed the floodbasin into an Alder carr in a next phase of estuary evolution. Such less dense vegetation promotes crevassing as sediments are more easily transported into the floodbasin. As river discharge increased and estuary mouth infilling progressed, crevasse activity diminished around 3800 to 3000 cal bp , likely due to a reduced tidal backwater effect. The insights from this data-rich Holocene study showcase the dominant role that vegetation may have in the long-term evolution of coastal wetlands. It provides clues for effective use of vegetation in vulnerable wetland landscapes to steer sedimentation patterns to strategically adapt to rising water levels.  相似文献   
8.
We present MUSE, a software framework for combining existing computational tools for different astrophysical domains into a single multiphysics, multiscale application. MUSE facilitates the coupling of existing codes written in different languages by providing inter-language tools and by specifying an interface between each module and the framework that represents a balance between generality and computational efficiency. This approach allows scientists to use combinations of codes to solve highly coupled problems without the need to write new codes for other domains or significantly alter their existing codes. MUSE currently incorporates the domains of stellar dynamics, stellar evolution and stellar hydrodynamics for studying generalized stellar systems. We have now reached a “Noah’s Ark” milestone, with (at least) two available numerical solvers for each domain. MUSE can treat multiscale and multiphysics systems in which the time- and size-scales are well separated, like simulating the evolution of planetary systems, small stellar associations, dense stellar clusters, galaxies and galactic nuclei. In this paper we describe three examples calculated using MUSE: the merger of two galaxies, the merger of two evolving stars, and a hybrid N-body simulation. In addition, we demonstrate an implementation of MUSE on a distributed computer which may also include special-purpose hardware, such as GRAPEs or GPUs, to accelerate computations. The current MUSE code base is publicly available as open source at http://muse.li.  相似文献   
9.
We use numerically modelled data sets to investigate the sensitivity of electromagnetic interferometry by multidimensional deconvolution to spatial receiver sampling. Interferometry by multidimensional deconvolution retrieves the reflection response below the receivers after decomposition of the fields into upward and downward decaying fields and deconvolving the upward decaying field by the downward decaying field. Thereby the medium above the receiver level is replaced with a homogeneous half‐space, the sources are redatumed to the receiver level and the direct field is removed. Consequently, in a marine setting the retrieved reflection response is independent of any effect of the water layer and the air above. A drawback of interferometry by multidimensional deconvolution is a possibly unstable matrix inversion, which is necessary to retrieve the reflection response. Additionally, in order to correctly separate the upward and the downward decaying fields, the electromagnetic fields need to be sampled properly. We show that the largest possible receiver spacing depends on two parameters: the vertical distance between the source and the receivers and the length of the source. The receiver spacing should not exceed the larger of these two parameters. Besides these two parameters, the presence of inhomogeneities close to the receivers may also require a dense receiver sampling. We show that by using the synthetic aperture concept, an elongated source can be created from conventionally acquired data in order to overcome these strict sampling criteria. Finally, we show that interferometry may work under real‐world conditions with random noise and receiver orientation and positioning errors.  相似文献   
10.
The complexity of most geological and geophysical problems prompts sometimes the use of non linear mathematical methods to handle them. An adaptive neuro fuzzy inference system (ANFIS) that combines fuzzy logic with neural networks, is applied here to study a paleoclimate section from the Quaternary sedimentary fill of the Lake Mucubají (western Venezuela). The purpose of this work is to find a set of numerical relationships that could predict the possible connections between oxygen isotope (δ18O) values from two different locations in the northern hemisphere (Ammersee in southern Germany and an ice core from the Greenland Ice Core Project — GRIP) and rock-magnetic parameters measured in Mucubají samples (i.e. mass-specific magnetic susceptibility — χ, magnetic remanence S-ratio, mass-specific saturation isothermal remanent magnetization — SIRM and anhysteretic remanent magnetization — ARM). The best inferences in terms of coefficient of determionation R2 and the Root Mean-Square Error (RMSE) are obtained using those magnetic data as input that include information about magnetite grain size distributions, e.g., SIRM and ARM in FIS structures [1χ, 4ARM] and [4ARM, 1SIRM]. A comparison between Ammersee and GRIP actual data, as well as their corresponding inferences for the FIS structure [4ARM, 1SIRM], reveals a reasonable good inference of global trends for both records, overlooking the regional and/or local paleoclimate forcings that might have affected Ammersee. A better correlation between global isotope paleoclimate records and magnetic proxies, is perhaps prevented by the role played by local and regional paleoclimate and tectonism in Mucubají. We also argue that the ratio of ARM over SIRM appears to be related in a complex way to the onset and to the end of the Younger Dryas. Our novel approach to the assessment of a specific paleoclimate case study shows the potential of the ANFIS technique in solving problems where traditional univariate and multivariate linear regression methods could prove inadequate.  相似文献   
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