Sensitivity analysis of a deterministic water temperature model to forest canopy and soil temperature in Catamaran Brook (New Brunswick,Canada)     

Andr St‐Hilaire  Nassir El‐Jabi  Daniel Caissie  Guy Morin 《水文研究》2003,17(10):2033-2047

A coupled deterministic hydrological and water temperature model, CEQUEAU, was modified to include soil temperature and crown closure in its calculation of local advective terms in the heat budget. The modified model was than tested to verify its sensitivity to these modifications. An analysis of the heat budget of a small forested catchment in eastern Canada revealed that the advective term related to interflow plays a significant role in the daily water heat budget, providing on average 28% of the local advective budget (which also includes advective heat terms from surface runoff and groundwater) and nearly 14% of the total heat budget (which includes all radiative terms at the water surface, convection and evaporation, as well as the local advective terms). Relative sensitivity indices (RSIs) were used to verify the impact of the newly introduced parameters and variables. Among them, parameters related to the forest cover (crown closure and leaf area index) have a maximum RSI of ?0·6; i.e. a 100% increase in value produces a 60% decrease in the local advective term. Parameters with the greatest influence are the volume of water contributing to interflow and the amplitude of the net radiative flux at the soil surface, which, if doubled, would double the contribution of the local interflow advective term to the heat budget. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Nanoscale study of As biomineralization in an acid mine drainage system     

K. Benzerara  G. Morin  J. Miot  C. Casiot  F. Farges  G.E. Brown Jr. 《Geochimica et cosmochimica acta》2008,72(16):3949-3963

Spatial and seasonal variations of the oxidation of Fe(II) and As(III) have been previously documented in the Carnoulès (Gard, France) Acid Mine Drainage (AMD) by bulk analyses. These variations may be correlated with the variations in the activity of indigenous As(III)- and Fe(II)-oxidizing bacteria living in the As-rich Carnoulès water. The activity of these bacteria indeed plays an important role in the nature and composition of the solid phases that sequester arsenic at this site. In order to better understand the interactions of microbes with Fe and As in the Carnoulès AMD, we combined Transmission Electron Microscopy (TEM) and Scanning Transmission X-ray Microscopy (STXM) to collect near-edge X-ray absorption fine structure (NEXAFS) spectra at high spatial and energy resolution and to perform high spatial resolution imaging at the 30-50 nm scale. Spectromicroscopy was performed at the C K-edge, Fe L_2,3-edge, and As L_2,3-edge, which allowed us to locate living and/or mineralized bacterial cells and to characterize Fe and As oxidation states in the vicinity of those cells. TEM was used to image the same areas, providing higher resolution images and complementary crystallographic and compositional information through electron diffraction and EDXS analysis. This approach provides unique information on heterogeneous geochemical processes that occur in a complex microbial community in an AMD environment at the micrometer and submicrometer-scale. Bacterial cells in the Carnoulès AMD were frequently associated with mineral precipitates, and a variety of biomineralization patterns were observed. While many mineral precipitates were not associated with bacterial cells, they were associated with pervasive organic carbon. Finally, abundant biomineralized organic vesicles were observed in the Carnoulès AMD. Such vesicles may have been overlooked in highly mineralized extreme environments in the past and may represent an important component in a common biomineralization process in such environments.  相似文献   

Combining indicator trends to assess ongoing changes in exploited fish communities: diagnostic of communities off the coasts of France   总被引：1，自引：1，他引：1  

Rochet  Marie-Joelle; Trenkel  Verena; Bellail  Robert; Coppin  Franck; Le Pape  Olivier; Mahe  Jean-Claude; Morin  Jocelyne; Poulard  Jean-Charles; Schlaich  Ivan; Souplet  Arnauld; Verin  Yves; Bertrand  Jacques 《ICES Journal of Marine Science》2005,62(8):1647-1664

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Incorporation of Cr<Superscript>3+</Superscript> in dickite: a spectroscopic study     

E. Balan  T. Allard  G. Morin  G. Calas 《Physics and Chemistry of Minerals》2002,29(4):273-279

 We have investigated a well-ordered sample of natural Cr-bearing dickite from Nowa Ruda (Lower Silesia, Poland) using electron paramagnetic resonance (EPR) at X- and Q-band frequencies (9.42 and 33.97 GHz, respectively) and optical diffuse reflectance spectroscopy. The observation of the spin-forbidden transitions at 15500 and 14690 cm⁻¹ allows us to unambiguously identify the major contribution of octahedrally coordinated Cr³⁺ ions in the optical spectrum. The X- and Q-band EPR spectra show two superposed Cr³⁺ signals. The corresponding fine-structure parameters were determined at room temperature and 145 K. These results suggest the substitution of Cr³⁺ for Al³⁺ in equal proportions in the two unequivalent octahedral sites of the dickite structure. In kaolin group minerals, the distortion around Cr³⁺ ions (λ≈ 0.2–0.4) in Al sites is significantly less rhombic than that observed around Fe³⁺ ions (λ≈ 0.6–0.8). Received: 29 June 2001 / Accepted: 22 October 2001  相似文献   

Uniting space, ground, and underwater measurements for improved estimates of rain rate   总被引：1，自引：0，他引：1  

Amitai  E. Nystuen  J.A. Liao  L. Meneghini  R. Morin  E. 《Geoscience and Remote Sensing Letters, IEEE》2004,1(2):35-38

Global precipitation is monitored from a variety of platforms including spaceborne, ground-, and ocean-based platforms. Intercomparisons of these observations are crucial to validating the measurements and providing confidence for each measurement technique. Probability distribution functions of rain rates are used to compare satellite and ground-based radar observations. A preferred adjustment technique for improving rain rate distribution estimates is identified using measurements from ground-based radar and rain gauges within the coverage area of the radar. The underwater measurement of rainfall shows similarities to radar measurements, but with intermediate spatial resolution and high temporal resolution. Reconciling these different measurement techniques provides understanding and confidence for all of the methods.  相似文献   

Native and artificial radiation-induced defects in montmorillonite. An EPR study     

S. Sorieul  T. Allard  G. Morin  B. Boizot  G. Calas 《Physics and Chemistry of Minerals》2005,32(1):1-7

A natural montmorillonite containing radiation-induced defects was studied with Electron Paramagnetic Resonance (EPR) spectroscopy (X- and Q-band). A first dominant native defect, namely native defect 1, is identified. It gives rise to an orthorhombic spectrum with g_x= 2.004 ± 0.005 g_y= 2.010 ± 0.003, g_z= 2.065 ± 0.002. Simulation of the EPR spectrum at X- and Q-band reveals a second native defect with isotropic spectrum at g= 2.019 ± 0.005. Both are electron holes trapped on oxygen atoms of the structure. The native defect 1 is located on an oxygen-silicon bond or a non-bonding orbital parallel to the c* axis. These defects are annealed at 500°C and the half-life determined for native defect 1 is circa 3,000 years. Irradiations with beta rays produced two additional hole centers of lower stability and distinct EPR parameters. Artificial irradiations show that montmorillonite can be used as a dosimeter in a large dose range.  相似文献   

A severe autumn storm over the middle-east: synoptic and mesoscale convection analysis     

U. Dayan  B. Ziv  A. Margalit  E. Morin  D. Sharon 《Theoretical and Applied Climatology》2001,69(1-2):103-122

Summary  At times, a pronounced trough of low barometric pressure extends from equatorial Africa northward, over the Red Sea and the eastern Mediterranean countries, i.e., the Red Sea Trough. The associated weather is usually hot and dry, and consequently the atmosphere becomes conditionally unstable. In cases in which additional moisture is supplied and dynamic conditions become supportive, as the case analyzed here, intense thunderstorms occur, with extreme rain rates, hail and floods. The storm herein analyzed caused extensive damage both in casualties and property and evolved in two main consecutive phases: In the first a Mesoscale Convective System that moved from Sinai northward over Israel dominated, and in the second deep convection was organized mainly along a cold front. Data analysis indicates several synoptic-scale factors that had a supportive effect on the storm formation and intensification: Conditional instability established by the Red Sea trough, mid-level moisture transport from Northern Africa, and upper-level divergence imparted by both polar and subtropical jet streams over the Middle-East. Mesoscale features were further investigated by means of a hydro-meteorological observational analysis with high spatio-temporal resolution using raingauge and radar data, and satellite imagery. It is shown that local factors, particularly topographic effects, play a major role in the evolution, intensity and spatial organization of the convective activity. Our findings support results of a numerical study of another autumn rainstorm associated with the Red Sea trough. In the present case we identify an additional contributing factor, i.e., a mid-latitude upper-level trough that further intensified the storm as it was approaching the Middle-East. Received July 4, 2000 Revised January 16, 2001  相似文献   

Determination des intervalles de confiance de la loi Pearson III par les statistiques d'ordre     

B. Bobee  G. Morin 《Journal of Hydrology》1973,20(2):137-153

The knowledge of the distribution functions of the order statistics for the Pearson III law and its derived forms is used for determining the confidence intervals associated with this law.This method is used to establish the tables and graphs for the confidence intervals of this law and its derived forms.  相似文献   

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model     

André Burnol  Francis Garrido  Philippe Baranger  Catherine Joulian  Marie-Christine Dictor  Françoise Bodénan  Guillaume Morin  Laurent Charlet 《Geochemical transactions》2007,8(1):12

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.  相似文献   

Hydraulic Properties of Coal and Related Materials, Northern Great Plains   总被引：1，自引：0，他引：1  

Bernd W. Rehm  Gerald H. Groenewold  Kevin A. Morin 《Ground water》1980,18(6):551-561

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