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The lack of temporal resolution and accurate chronology of Southern Ocean marine cores has hampered comparison of glacial millennial-scale oscillations between the Southern Ocean, Antarctic ice and other records from both hemispheres. In this study, glacial climate variability is investigated over the last 50 ka using a multi-proxy approach. A precise chrono-stratigraphy was developed on the high-sedimentation rate core MD94-103 (Indian Southern Ocean, 45°35′S 86°31′E, 3560 m water depth) by geomagnetic synchronization between the later core and NAPIS75, and 14C dates. High-resolution time-series of δ18O in planktonic foraminifera Globigerina bulloides and Neogloboquadrina pachyderma, and sea surface temperatures (SSTs) estimated from the alkenone UK37 index and foraminifera assemblages have been generated. Temporal evolution of the two temperature proxy records is notably different during the last glacial period. While foraminifera data indicate a consistent cooling towards the last glacial maximum, anomalous warm glacial alkenone temperatures suggest a strong advection of warm “detrital” alkenones by surface waters of the Agulhas current. Superimposed to this general trend, during Heinrich events, foraminiferal SSTs point to warmer surface waters, while concurrent alkenone SSTs exhibit apparent coolings probably caused by enhanced local alkenone production. By analogy to modern observations, possible influence of ENSO-like conditions on the subantarctic Southern Ocean SSTs is discussed.  相似文献   
2.
Numerical simulation of groundwater flow used for the estimation of hydraulic and hydrologic parameters which is an important tool for the management of aquifers. This study presents the results of a mathematical model developed for the simulation of groundwater flow in Nahavand plain aquifer in the southwest Hamadan province. For this purpose Groundwater Modeling Software (GMS) was used which supports the MODFLOW-2000 code. After gathering required data such as the hydrological, hydrogeological and topography maps, a 3D hydrogeological model of plain was constructed with borehole and surface elevation data. Then MODFLOW was used for simulation of flow. After initial simulation of the flow, the model was calibrated in steady state with trial-and-error and parameter estimation methods the observed head of groundwater table monitoring data of 1997. Results of calibration show that error between observed head and computed head is in allowable range. Also results of computed head with model show that groundwater flow is in the direction of the dominate slope (southeast to northwest). Finally MODPATH code which simulates advective transport of particles was used for estimation of flow path and source of contaminants.  相似文献   
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This study investigates the conditions of occurrence and petrographic characteristics of low‐Mg calcite (LMC) from cold seeps of the Gulf of Mexico at a water depth of 2340 m. Such LMC mineral phases should precipitate in calcite seas rather than today's aragonite sea. The 13C‐depleted carbonates formed as a consequence of anaerobic oxidation of hydrocarbons in shallow subsurface cold seep environments. The occurrence of LMC may result from brine fluid flows. Brines are relatively Ca2+‐enriched and Mg2+‐depleted (Mg/Ca mole ratio <0.7) relative to seawater, where the Mg/Ca mole ratio is ~5, which drives high‐Mg calcite and aragonite precipitation. The dissolution of aragonitic mollusk shells, grains and cements was observed. Aerobic oxidation of hydrocarbons and H2S is the most likely mechanism to explain carbonate dissolution. These findings have important implications for understanding the occurrence of LMC in deep water marine settings and consequently their counterparts in the geological record.  相似文献   
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Summary Geochemical data for 870 ore samples of 14 nickel sulphide (NiS) deposits from throughout the major Archaean Kambalda ore field, Western Australia, reveal highly heterogeneous Ni tenor (wt% Ni in 100wt% sulphide) variation that is difficult to explain solely by magmatic processes. The Ni tenor values for the deposits range from 6.2wt% Ni (Helmut deposit) to 19.7wt% Ni (Carnilya Hill deposit), close to the range for within single deposits (9.7–19.3wt% Ni). Contents of Ni and platinum-group elements (PGE) broadly increase with decreasing Fe and with increasing abundance of metamorphic pyrite+magnetite±silicates. In turn, the abundance of the metamorphic phases appears to be complexly related to structural setting, metamorphic grade, alteration type, and proximity to felsic intrusion. Chondrite-normalised multi-element plots of deposit compositions reveal relative depletions in Au, As, Bi, and Te.The relationship of increasing Ni content with secondary phase abundance indicates a strong role for metamorphic modification in the tenor variation. Replacement of pyrrhotite by pyrite+magnetite±chlorite during oxidation reduced the abundance of Fe sulphide relative to Ni sulphide and increased the Ni tenor of the residual sulphide. The extent of the oxidation reflects the extent of alteration fluid ingress along deformation structures and fabrics during talc-carbonate alteration, regional metamorphism, and felsic intrusion related to D3. The relative depletions of Au, As, Bi and Te combined with relative enrichments of these metals in nearby orogenic gold deposits mean that NiS deposits could represent metal reservoirs for Archaean gold hydrothermal systems.  相似文献   
6.
New records of past sea surface temperatures (SSTs) were derived in the 30-50 kyr B.P. time interval from a core located at 45°S in the Southern Indian Ocean, MD94-103. To investigate the climatic phasing between the Southern Indian Ocean, the Greenland and the Antarctic ice, the magnetic signal of core MD94-103 was synchronized at better than millennial accuracy in the vicinity of the Laschamp geomagnetic to a reference record, NAPIS-75, already placed on the GISP2 age model. Coccolithophorid and diatom species abundances both point to a cooling of surface waters during H4. Specific diatoms also indicate lower salinity waters during the same time interval. These observations do not support the idea that the South hemisphere warmed 1.5-2 kyr before the North hemisphere (Nature 394 (1998) 739). Rather, alkenone-derived SSTs suggest that cold conditions have characterized the surface waters in the south latitudes during H4 and H5, and that temperature at evaporation sites contributed to the isotopic events A1 and A2 visible in the isotopic records of central Antarctica (Earth Planet. Sci. Lett. 177 (2000) 219). SSTs obtained from foraminifera assemblages depict somewhat different temperature patterns, possibly indicative of water stratification.  相似文献   
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Nowadays, there are many new methods for slope stability analysis; including probabilistic methods assessing geotechnical uncertainties to develop safety factors. In this paper, a reliability index analysis for the Sungun copper mine slope stability is evaluated based on three methods of uncertainties consisting Taylor series method, Rosenblueth point estimate method and Monte-Carlo simulation method. Sungun copper mine will be one of the Iran’s biggest mines with final pit’s height of 700 meters. For this study two of its main slopes were assessed, one dipping to the NE (030) and the other to the SE (140). Probability density function of cohesion and angle of friction for the slopes were developed using limit equilibrium methods. These shear strengths were then used to determine the probability density function of safety factor and reliability index using the probabilistic methods. Results of the probabilistic analysis indicate that with ascending values of the uncertainties the reliability index decreases. Furthermore, it was determined that with the Monte Carlo simulation the seed number used has little effect on the reliability index of the safety factor especially with seed numbers in excess of 1200. Variations in the overall reliability index of safety factor were observed between the two slopes and this difference is explained by the differences in complexities of the geology within the cross-section.  相似文献   
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9.
Ezat Heydari   《Tectonophysics》2008,451(1-4):56-70
At least 12 km of strata ranging in age from the latest Precambrian to the Recent are exposed in the Zagros Mountains of Iran. This sedimentary cover is characterized by distinct stratal packages separated by major unconformities forming twelve supersequences. They are informally named as: (1) Late Precambrian – Cambrian Hakhamanesh Supersequence, (2) Ordovician Kourosh Supersequence, (3) Silurian Camboojiyeh Supersequence, (4) Devonian Darioush Supersequence, (5) Mississippian – Pennsylvanian Khashayar Supersequence, (6) Permian – Triassic Ashk Supersequence, (7) Jurassic Farhad Supersequence, (8) Early Cretaceous Mehrdad Supersequence, (9) Late Cretaceous Ardavan Supersequence, (10) Paleocene – Oligocene Sassan Supersequence, (11) Oligocene – Miocene Ardeshir Supersequence, and (12) Miocene – Pleistocene Shapour Supersequence. These supersequences and their correlatives in neighboring areas have been used to infer tectonic events. The dominant interpretation has been that local or regional epeirogenic movements were responsible for the formation of these supersequences. Unconformities are considered as indications that epeirogenic movements associated with tectonic events affected the area. The present investigation provides an alternative to the established view of the Phanerozoic supersequences of the Zagros Mountains.

A good correlation exists between the lithofacies of supersequences in the Zagros Mountains and the second-order eustatic sea-level changes. Deposition of deep-water, marine shales occurred during periods of eustatic sea-level rise. Platform-wide unconformities coincided with eustatic sea-level lows. In fact, supersequences of the Zagros Mountains are nearly identical to those described from the North American Craton and the Russian Platform suggesting that these stratal packages are global. These observations suggest that supersequences of the Zagros Mountains formed by second order eustatic sea-level changes and not by local or regional epeirogenic movements.

Although tectonic events did not produce supersequences of the Zagros Mountains, they influenced regional lithofacies patterns through the formation of intrashelf depressions such as the Hormoz Salt Basin during the Precambrian and the Dezful Embayment and the Lorestan Basin during the Mesozoic. Tectonic events also affected sedimentation during the Tertiary collision of Arabia and the Central Iran microplate through uplift, erosion, and the formation of the Zagros Foreland Basin. The results of this investigation necessitate a re-evaluation of the role and the significance of pre-Tertiary tectonic events commonly used to interpret the geological evolution of the Zagros Mountains.  相似文献   

10.
New technologies such as microwaves have gained a large deal of attention from scientists and industries who sought increased rate of production processes. In this study, microwave irradiation was utilized to produce a novel KOH/Ca12Al14O33 nanocatalyst used for biodiesel production. As support, calcium aluminate was prepared by microwave combustion method using different fuels including urea, glycine, sorbitol, and citric acid. The samples were then impregnated by KOH to improve their catalytic activities for microwave-enhanced transesterification of canola oil for biodiesel production. Results of XRD, BET, FTIR, TG, EDX, and FE-SEM analyses showed differences in physicochemical properties of the samples when using different fuels with different flame characteristics and combustion temperatures. Only the urea-fueled sample showed the crystalline structure of monocalcium aluminate (CaAl2O4), with the other samples exhibiting amorphous structure of CaO–Al2O3. However, all samples, except for that prepared by citric acid, transformed to crystalline structure of Ca12Al14O33 by calcination during KOH impregnation. Among the samples, the KOH/Ca12Al14O33 nanocatalyst prepared by sorbitol showed the highest activity in microwave-enhanced biodiesel production because of its large surface area, pore size, and basicity, converting 93.4% of canola oil to biodiesel at a methanol-to-oil molar ratio of 18, catalyst concentration of 4 wt%, and microwave output power of 450 W in 60 min of reaction time. Moreover, the sample showed well-distributed particle sizes without any agglomeration, so that it could easily maintain its level of activity for several rounds of use.  相似文献   
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