排序方式： 共有7条查询结果，搜索用时 15 毫秒
1
1.
SATO HIROAKI; HOLTZ FRANCOIS; BEHRENS HARALD; BOTCHARNIKOV ROMAN; NAKADA SETSUYA 《Journal of Petrology》2005,46(2):339-354
High-temperature–pressure experiments were carried outto determine the chlorine–hydroxyl exchange partitioncoefficient between hornblende and melt in the 1992 Unzen dacite.Cl in hornblende and melt was analyzed by electron microprobe,whereas OH in hornblende and melt was calculated assuming anionstoichiometry of hornblende and utilizing the dissociation reactionconstant for H2O + O = 2(OH) in water-saturated melt, respectively.The partition coefficient strongly depends on the Mg/(Mg + Fe)ratio of hornblende, and is expressed as ln K1 = (Cl/OH)hb/(Cl/OH)melt= 2·37 – 4·6[Mg/(Mg + Fe)]hb at 2–3kbar and 800–850°C. The twofold variation in Cl contentin the oscillatory zoned cores of hornblende phenocrysts inthe 1991–1995 dacite cannot be explained by the dependenceof the Cl/OH partition coefficient on the Mg/(Mg + Fe)hb ratio,and requires c. 80% variation of the Cl/OH ratio of the coexistingmelt. Available experimental data at 200 MPa on Cl/OH fractionationbetween fluid and melt suggest that c. 1·2–1·8wt % degassing of water from the magma can explain the required80% variation in the Cl/OH ratio of the melt. The negative correlationbetween Al content and Mg/(Mg + Fe) ratio in the oscillatoryzoned cores of the hornblende phenocrysts is consistent withrepeated influx and convective degassing of the fluid phasein the magma chamber. KEY WORDS: chlorine; element partitioning; hornblende; oscillatory zoning; Unzen volcano 相似文献
2.
重金属污染土壤萃取方法选择及参数优化 总被引：7，自引：0，他引：7
土壤重金属污染是国际土壤与环境研究的热点和难点问题之一。重金属在土壤中存在的形态和各种形态的比例是决定其迁移性和生态影响的关键因素。常用的形态分析方法包括Tessier五步萃取法、BCR三步萃取法和水萃取法等。在比较三种萃取方法的基础上,在法国北部冶炼厂周围土壤和焦作矿区土壤污染研究中采用水乙酸两步萃取法,采用蒸馏水和0 11 mol/L的乙酸,液固比20,25 ℃条件下恒温振荡16 h。 相似文献
3.
ERIC LAJEUNESSE LUCE MALVERTI PIERRE LANCIEN LAWRENCE ARMSTRONG FRANCOIS MÉTIVIER STEPHEN COLEMAN CHARLES E. SMITH TIMOTHY DAVIES ALESSANDRO CANTELLI GARY PARKER 《Sedimentology》2010,57(1):1-26
The interaction of flow with an erodible bed in alluvial rivers and deep‐sea channels gives rise to a wide range of self‐formed morphologies, including channels, ripples, dunes, antidunes, alternate bars, multiple‐row bars, meandering and braiding. As the flow is invariably turbulent in field manifestations of these morphologies, there has been a tendency to assume that turbulence is necessary for them to form. While turbulence undoubtedly has an important influence when it is present, it is not necessary for any of these features. Indeed, all of these features can be formed by the morphodynamic interaction of purely laminar or nearly laminar flow with an erodible bed. This paper provides a survey and synthesis of a wide range of laminar or near‐laminar flow analogues of morphologies observed in the field. Laminar‐flow analogues of turbulent‐flow morphologies cannot and should not be expected to satisfy dynamic similarity in terms of all relevant dimensionless parameters. What is of more significance is the convergence of the underlying physics. It is illustrated in this paper that many existing theoretical frameworks for the explanation of turbulent‐flow morphodynamics require only relatively minor modification in order to adapt them to laminar flows. 相似文献
4.
Experimental Petrology of the 1991-1995 Unzen Dacite, Japan. Part I: Phase Relations, Phase Composition and Pre-eruptive Conditions 总被引：2，自引：0，他引：2
HOLTZ FRANCOIS; SATO HIROAKI; LEWIS JARED; BEHRENS HARALD; NAKADA SETSUYA 《Journal of Petrology》2005,46(2):319-337
Crystallization experiments were conducted on dry glasses fromthe Unzen 1992 dacite at 100–300 MPa, 775–875°C,various water activities, and fO2 buffered by the Ni–NiObuffer. The compositions of the experimental products and naturalphases are used to constrain the temperature and water contentsof the low-temperature and high-temperature magmas prior tothe magma mixing event leading to the 1991–1995 eruption.A temperature of 1050 ± 75°C is determined for thehigh-temperature magma based on two-pyroxene thermometry. Theinvestigation of glass inclusions suggests that the water contentof the rhyolitic low-temperature magma could be as high as 8wt % H2O. The phase relations at 300 MPa and in the temperaturerange 870–900°C, which are conditions assumed to berepresentative of the main magma chamber after mixing, showthat the main phenocrysts (orthopyroxene, plagioclase, hornblende)coexist only at reduced water activity; the water content ofthe post-mixing dacitic melt is estimated to be 6 ± 1wt % H2O. Quartz and biotite, also present as phenocrysts inthe dacite, are observed only at low temperature (below 800–775°C).It is concluded that the erupted dacitic magma resulted fromthe mixing of c. 35 wt % of an almost aphyric pyroxene-bearingandesitic magma (1050 ± 75°C; 4 ± 1 wt % H2Oin the melt) with 65 wt % of a phenocryst-rich low-temperaturemagma (760–780°C) in which the melt phase was rhyolitic,containing up to 8 ± 1 wt % H2O. The proportions of rhyoliticmelt and phenocrysts in the low-temperature magma are estimatedto be 65% and 35%, respectively. It is emphasized that the strongvariations of phenocryst compositions, especially plagioclase,can be explained only if there were variations of temperatureand/or water activity (in time and/or space) in the low-temperaturemagma. KEY WORDS: Unzen volcano; magma mixing; experimental study 相似文献
5.
The Four Plutonic Belts of the Transhimalaya-Himalaya: a Chemical, Mineralogical, Isotopic, and Chronological Synthesis along a Tibet-Nepal Section 总被引：31，自引：0，他引：31
DEBON FRANCOIS; FORT PATRICK LE; SHEPPARD SIMON M. F.; SONET JACQUES 《Journal of Petrology》1986,27(1):219-250
The geochemistry (major, trace element, O- and Sr-isotope ratios)and petrology of the Transhimalaya, North Himalaya, High Himalayaand ‘Lesser Himalaya’ plutonic belts are comparedbased on the analyses of up to 492 samples. The composite Transhimalaya batholith is subalkaline or monzoniticin character rather than calc-alkaline. Its genesis was probablyclosely related to subduction processes associated with strike-slipmovement. It was emplaced on both sides of the boundary betweenan earlier metavolcanic arc and a continental margin. Two principalperiods of magmatic activity occurred: Upper Cretaceous and,particularly in this region, Eocene at the time of the India-Eurasiacollision when sediments may have become involved in the subductionprocess. Magmatic differentiation, characterized by two superimposedstages of evolution, and hybridization processes, involvingboth basic and acidic magmas, can account for the genesis ofthe different plutonic units. Although a continental contributionis implied, the isotopic data (6.8 < 18O < 9?2; 0?704< 87Sr/86Sr, < 0?707) preclude a significant contributionfrom either old crust or surface derived sediments. The North, High and ‘Lesser’ Himalaya plutonic beltsare fundamentally different and correspond to aluminous associationsof two groups of ages (Lower Palaeozoic for the ‘LesserHimalaya’ and part of the North Himalaya; Upper Cenozoicfor the High Himalaya and part of the North Himalaya). Theyare all high-18O (9 < 18O < 14) granites and adamelliteswith high initial 87Sr/86Sr, ratios (0?709 to < 0?740). TheLower Palaeozoic group was generated within the Gondwana continentalcrust, independent of any true orogenesis, with a probable butlimited contribution from the mantle. High Himalaya and NorthHimalaya Cenozoic plutons are directly linked to the activityof the Main Central Thrust. They were derived by similar anatecticprocesses of the same continental source rocks. The small butdistinct chemical and mineralogical differences among the plutonsare related to the increase in the intensity of anatexis ongoing towards the north and the east. 相似文献
6.
The formation of platy olivine spinifex, the texture that characterizeskomatiite lavas, has long been enigmatic. A major problem isthat the dendritic morphology of the olivine resembles thatof crystals grown in laboratory experiments at high coolingrates (>50°C/h), but at the position where these texturesform, up to several meters below the komatiite flow top, thecooling rate cannot have been greater than 1–5°C/h.We performed experiments that demonstrate that the platy habitof spinifex olivine or pyroxene is a consequence of slow coolingof ultramafic magma in a thermal gradient (7–35°C/cm).The charges were cooled at rates between 2 and 1428°C/hand, even at the low cooling rates, the thermal gradient ledto constrained growth and the development of preferentiallyoriented dendritic crystals with morphologies like those innatural platy spinifex-textured lavas. Under these conditions,olivine starts to crystallize at temperatures well below theequilibrium liquidus temperature (37°C < –T<56°C) depending on the composition of the starting material.When the cooling rate is high, the thermal gradient has a negligibleeffect on the texture and the crystals have a random orientation,like that in the upper parts of komatiite flows. KEY WORDS: komatiite; spinifex; cooling rate; experimental petrology; thermal gradient 相似文献
7.
An Experimental Investigation of the Influence of Water and Oxygen Fugacity on Differentiation of MORB at 200 MPa 总被引：10，自引：2，他引：10
Crystallization experiments were performed at 200 MPa in thetemperature range 1150–950°C at oxygen fugacitiescorresponding to the quartz–fayalite–magnetite (QFM)and MnO–Mn3O4 buffers to assess the role of water andfO2 on phase relations and differentiation trends in mid-oceanridge basalt (MORB) systems. Starting from a primitive (MgO9·8 wt %) and an evolved MORB (MgO 6·49 wt %),crystallization paths with four different water contents (0·35–4·7wt % H2O) have been investigated. In primitive MORB, olivineis the liquidus phase followed by plagioclase + clinopyroxene.Amphibole is present only at water-saturated conditions below1000°C, but not all fluid-saturated runs contain amphibole.Magnetite and orthopyroxene are not stable at low fO2 (QFM buffer).Residual liquids obtained at low fO2 show a tholeiitic differentiationtrend. The crystallization of magnetite at high fO2 (MnO–Mn3O4buffer) results in a decrease of melt FeO*/MgO ratio, causinga calc-alkaline differentiation trend. Because the magnetitecrystallization temperature is nearly independent of the H2Ocontent, in contrast to silicate minerals, the calc-alkalinedifferentiation trend is more pronounced at high water contents.Residual melts at 950°C in a primitive MORB system havecompositions approaching those of oceanic plagiogranites interms of SiO2 and K2O, but have Ca/Na ratios and FeO* contentsthat are too high compared with the natural rocks, implyingthat fractionation processes are necessary to reach typicalcompositions of natural oceanic plagiogranites. KEY WORDS: differentiation; MORB; oxygen fugacity; water activity; oceanic plagiogranite 相似文献
1