Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Multi-wavelength Diagnostics of Bombardment by Non-thermal Particles in Solar Flares     

Zhi Xu  Cheng Fang  Wei-Qun Can Astronomy Department of Nanjing University  Nanjing  Purple Mountain Observatory  Chinese Academy of Sciences  Nanjing 《中国天文和天体物理学报》2005,5(5):519-530

Chromospheric lines, including Ha, Lyα, Lyβand CaⅡK, CaⅡ8542, are systemically and quantitatively investigated with respect to the non-thermal excitation and ionization due to particle beam bombardment for a series of solar semi-empirical atmospheric models. As a result we propose to use the contrast in the integrated intensity of hydrogen lines to estimate the total energy flux of the bombarding beam during the solar flare impulsive phase. Partial frequency redistribution is considered in the Lyαline calculation and a smaller intensity enhancement in the Ha line-centers is found than in the previous results of Fang et al.  相似文献   

Shearing flows of a dry granular material—hypoplastic constitutive theory and numerical simulations     

Chung Fang  Yongqi Wang  Kolumban Hutter 《国际地质力学数值与分析法杂志》2006,30(14):1409-1437

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关于国有地了企业经营者实行年薪制的构想     

胡芳 《河南国土资源》1996,(2)

为建立社会主义市场经济的地矿工作新秩序，本文对国有地矿企业的经营者（厂长、经理）这一特殊群体进行了分析。着重研究了新形势下企业经营者实行年薪制的问题。指出年薪制就是以企业一个生产经营周期为单位确定经营者的报酬，这一周期通常为一年。进而阐述了为什么要实行企业经营者年薪制；企业经营者的收入应与职工工资完全脱钩；采用基础报酬加效益报酬的方法确定收入等等。并构想了实行经营者年薪制所需要的外部环境：建立经营者人才市场、经营者要能进能出、实行任职资格制度、建立风险机制、按劳动力市场经济规律办事。  相似文献   

从ROSAT数据中寻找河内X射线暂现源     

卢方军  孙学军 《中国天文和天体物理学报》1997,(3)

从ＲＯＳＡＴ巡天和定点观测结果的对比出发，发现了几个低银纬的巡天源表中的Ｘ射线源在定点观测中没有出现．本文计算了在这些位置的定点观测中出现点源的流强上限，发现比巡天源表中这些源的流强值低很多，这表明它们的流强变化很大，可能是Ｘ射线双星系统中的一类———Ｘ射线暂现源．  相似文献   

The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

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巴颜喀拉山东段及其邻区大地电磁测深成果地质解释     

庞存廉  方胜  夏元祁 《青海国土经略》1996,(1)

本文主要依据青海省囊歉至大河坝大地电磁测深成果,并结合重力资料对巴颜喀拉及南北两侧地区的壳幔结构进行了地质解释。指出了该区壳幔存在4个明显的低阻层,并简述了它们的形态特征,推断了其地质含意。认为昆中断裂带与昆南断裂带间是一个巨大的构造混杂岩带,影响深度亦很大。推断该区可能存在太古代地层。划出了8条壳幔断裂带,认为昆中断裂应是塔里木—华北板块与华南板块的分界线。  相似文献   

STUDY ON GIS FOR YIELD ESTIMATION BY REMOTE SENSING IN JILIN MAIZE BELT     

Liu Xiangnan  Huang Fang  Zhou Zhanao 《中国地理科学(英文版)》1996,6(4):351-358

ＳＴＵＤＹ　ＯＮ　ＧＩＳ　ＦＯＲ　ＹＩＥＬＤ　ＥＳＴＩＭＡＴＩＯＮ　ＢＹ　ＲＥＭＯＴＥ　ＳＥＮＳＩＮＧ　ＩＮ　ＪＩＬＩＮ　ＭＡＩＺＥ　ＢＥＬＴＳＴＵＤＹＯＮＧＩＳＦＯＲＹＩＥＬＤＥＳＴＩＭＡＴＩＯＮＢＹＲＥＭＯＴＥＳＥＮＳＩＮＧＩＮＪＩＬＩＮＭＡＩＺ...  相似文献   

DCMT光电扫描主测微器的设计与研究     

李志刚  李焕信  方福胜  朱紫  许林生 《时间频率学报》1993,(1)

DCMT主测微器不同于其它类型的子午环测微器,它具有自校准测定仪器参数的功能。该测微器采用了活动光栅的方案,其优点是能观测近极星和各类准直像;活动光栅另一个显著优点是不同赤纬星几乎可用相同的观测时间.对“V”形光栅的工作原理和误差进行了详细讨论,并给出了一组严格的公式。其系统误差来源有:光栅形状改正、光栅驱动方向相对于光栅的倾斜、光栅驱动方向相对于赤径方向的倾斜、星径曲率改正。  相似文献   

Modeling the distribution of aluminum speciation in acid soil solution equilibria with the mineral phase alunite     

S. Bi  S. An  W. Tang  M. Yang  H. Qian  J. Wang 《Environmental Geology》2001,41(1-2):25-36

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