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1.
New basis for the constitutive modelling of aggregated soils   总被引:1,自引:1,他引:0  
Natural and compacted soils are usually characterized by aggregation of particles. The mechanical behaviour of these materials depends on soil structure. The oedometric compression tests performed on aggregated samples presented here showed that these materials exhibit a yield limit depending not only on stress history and stress state but also on soil structure. Evidence is provided using the neutron tomography technique. These results revealed that soil structure modification occurs together with plastic deformations. The experimental results are used to propose a new state parameter to quantify the soil structure. Based on pore-scale experimental observations, an evolution law for this parameter is proposed as a function of associated plastic strains. Considering both soil fabric and inter-particle bonding effects, a new yield limit depending on stress state, stress history and soil structure is introduced for the aggregated soils. Accordingly, a new constitutive framework consistent with strain hardening plasticity is proposed to consider soil structure effects in the modelling of aggregated soils.  相似文献   
2.
Environmental geochemistry of Zarshuran Au-As deposit, NW Iran   总被引:2,自引:1,他引:2  
Zarshuran deposit is the most famous and important As-Au mine in Iran. However, there is no information on the impact of mining activity on the surrounding environment, especially on water systems. This paper attempts to document the concentration of arsenic and associated elements in waters and sediments resulting from the mining history of Zarshuran, a period covering hundreds of years. Water and sediment samples collected from Zarshuran Stream indicate high content of some potentially toxic elements, especially of As which ranges from 0.028 to 40 ng/l in water and 182 to 36,000 mg/kg in sediment samples. Mining activity, exposure of a large volume of mining wastes to weathering, and the anomalously high background of trace metals in the mining area are considered to be the main sources of heavy metal pollution.  相似文献   
3.
International Journal of Earth Sciences - Regional seismic reflection profiles, deep exploratory wells, and outcrop data have been used to study the structure and stratigraphic architecture of the...  相似文献   
4.
This paper focuses on the suitability of spring water for drinking and irrigation purposes in a part of eastern Himalaya, south Sikkim. There are many anthropogenic and geogenic factors contributing as a source of major cations and anions in the spring water. The spring water chemistry show a variation in EC, pH, TDS, Temperature, Na+, K+, Mg2+, Ca2+, Fe2+, Pb, Mn, Cu, HCO3-, Cl-, PO43-, NO3-, F- and SO42-. Mainly two types of water quality indexing has been used, one for suitability of spring water for drinking purposes and the other for irrigation purposes. For drinking purposes, Piper diagram used for determination of water type, water quality index (WQI) for quality monitoring and saturation index for mineral dissolution in water. % Na, RSC (Residual Sodium Carbon) and SAR (sodium absorption ratio) have been used for irrigation suitability. Piper diagram shows that CaHCO3 type of water was dominant in the study area. The WQI depicted excellent category and SAR, percent sodium and RSC (Residual Sodium Carbon) depict excellent, good and permissible category for irrigation purposes. Principle component analysis (PCA) was used to determine the major influencing factor responsible for the variability in the parameters analysed of spring water.  相似文献   
5.
Pavement design in Senegal is based on a linear elastic behavior of pavement materials and the hypothesis of a static loading. However, previous works on the mechanical behavior of road materials showed that this one is reversible after several loading cycles and depends on the applied stress. The described behavior is from then on, purely nonlinear. One of the objectives of this research is to determine the parameters of response of lateritic pavement materials submitted to road traffic by using FEM. Therefore, experiments were made on gravel lateritic soils from Dougar, Sébikotane, Mont-Rolland, Pâ Lo and Ngoundiane. The Young’s modulus of the materials was defined in unconfined compression test while repeated load triaxial test was performed to determine the resilient modulus of the gravels and the appropriate model (Uzan model). An implementation was realized with Cast3M©. The importance of the nonlinearity was revealed in a very clear way and was crucial in the construction of the calculation algorithm. The observations for certain conditions showed that the values of the critical responses are more important for the linear model than for the nonlinear model. However, this trend should be validated by further studies.  相似文献   
6.
Water Flows Toward Power: Socioecological Degradation of Lake Urmia,Iran   总被引:1,自引:0,他引:1  
Water is an invaluable resource, and equitable access to it is a fundamental human right. Disenfranchised groups often lose access to water resources because their interests are not well represented by decision makers. Excluding these groups from resource management policy often results in myopic decisions that contribute to further ecosystem damage. We describe the ecological degradation of Lake Urmia in Iran, which has recently experienced increased salinity and declining water quantity. The lake is a UNESCO Biosphere Reserve and Ramsar site, and supports unique biodiversity in the region. The lake's decline is driven by the destruction of Zagros forests and the government's water policies, which diverted water to more politically connected agricultural land users, increasing social inequity and prompting more deforestation. The most straightforward restoration solution is to discontinue the diversions and allow critical inflows to recharge Lake Urmia, preserving the lake and wetlands for migratory birds, tourists, and local communities.  相似文献   
7.
Nitrate contamination in irrigation groundwater,Isfahan, Iran   总被引:1,自引:1,他引:0  
Groundwater is one of the major sources of water in Isfahan. Efficient management of these resources requires a good understanding of its status. This paper focuses on the hydrochemistry and also it wants to assess the nitrate concentration in irrigation groundwater of Isfahan suburb. All the groundwater samples are grouped into three categories, including Na-Cl + Ca-Cl (63 %), Na-SO4 + Ca-SO4 (23 %) and Ca-HCO3 (14 %). According to the EC and SAR, the most dominant classes are C3S1, C4S2 and C4S3. 55 % of samples indicate very high salinity and medium to very high alkalinity that is not suitable for irrigation. 84 % of the groundwater samples show nitrate contents higher than HAV (13 mg l?), while more than 25 % exceeded the maximum contamination level (44.27 mg l?) according to EPA regulations. The horizontal and vertical distribution patterns of nitrate in groundwater samples show a surficial origin for nitrate contamination. The high nitrate content can be attributed to the agricultural activities along with domestic sewage and industrial wastewaters in populated area. Based on results, using high nitrate groundwater for irrigation can minimize the requirement for inorganic fertilizers and reduce the cost of cultivation and nitrate contamination.  相似文献   
8.
Geotechnical and Geological Engineering - Soil erosion is one of the major environmental problems in the Middle East and North Africa (MENA) region. Favoured by the harmful effects of climate...  相似文献   
9.
In order to better understand the long-term speciation and fractionation of Zn in soils, we investigated three soils naturally enriched in Zn (237–864 mg/kg Zn) from the weathering of Zn-rich limestones (40–207 mg/kg Zn) using extended X-ray absorption fine structure (EXAFS) spectroscopy and sequential extractions. The analysis of bulk EXAFS spectra by linear combination fitting (LCF) indicated that Zn in the oolitic limestones was mainly present as Zn-containing calcite (at site Dornach), Zn-containing goethite (Gurnigel) and Zn-containing goethite and sphalerite (Liestal). Correspondingly, extraction of the powdered rocks with 1 M NH4-acetate at pH 6.0 mobilized only minor fractions of Zn from the Gurnigel and Liestal limestones (<30%), but most Zn from the Dornach rock (81%). In the Dornach soil, part of the Zn released from the dissolving limestone was subsequently incorporated into pedogenic hydroxy-interlayered vermiculite (Zn-HIV, 30%) and Zn-containing kaolinite (30%) and adsorbed or complexed by soil organic and inorganic components (40%). The Gurnigel and Liestal soils contained substantial amounts of Zn-containing goethite (50%) stemming from the parent rock, smaller amounts (20%) of Zn-containing kaolinite (and possibly Zn-HIV), as well as adsorbed or complexed Zn-species (30%). In the soil from Liestal, sphalerite was only found in trace amounts, indicating its dissolution during soil formation. In sequential extractions, large percentages of Zn (55–85%) were extracted in recalcitrant extraction steps, confirming that Zn-HIV, Zn-containing kaolinite and Zn-containing goethite are highly resistant to weathering. These Zn-bearing phases thus represent long-term hosts for Zn in soils over thousands of years. The capability of these phases to immobilize Zn in heavily contaminated soils may however be limited by their uptake capacity (especially HIV and kaolinite) or their abundance in soil.  相似文献   
10.
X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [FeII4FeIII2(OH)12CO3: GR1(CO3)], which completely converted into ferrous-carbonate hydroxide (FeII2(OH)2CO3: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO3) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO3) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO3) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)2 phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)2 nanoparticles as oligomers binding to the edges of Fe(OH)6 octahedra at the edges of the octahedral layers of Fe(OH)2. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.  相似文献   
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