排序方式： 共有23条查询结果，搜索用时 15 毫秒
1.
Zusammenfassung Bei dem Versuch, die Kristallstruktur von Bonchevit zu bestimmen, stellte sich heraus, daß dieses Mineral—bis dahin PbBi4S7—aus zwei Phasen besteht. Der Hauptanteil wurde eindeutig als Galenobismutit identifiziert. Der Rest wies nach den Gitterkonstanten (a0=13,58±0,02 Å, b0=20,51±0,07 Å, c0=4,09±0,07 Å) auf ein bisher unbekanntes Mineral hin. Die Raumgruppe ist Bbmm. Ein indiziertes Pulverdiagramm und die dazugehörigen d-Werte werden angegeben.Die Emissionsspektralanalyse zeigt Pb und Bi als Hauptkomponenten, Cu und Ag als Nebenkomponenten und Spuren von Zn und Sn. Die Strukturanalyse führte zu der Formel Me5S6, wobei die Me-Atome etwa gleich schwer sind, so daß als chemischo Formel nur Pb3Bi2S6 mit Z=4 in Frage kommt.Strukturell gehört das Mineral in die Gruppe Andorit-Ramdohrit-Fizelyit. Die Verwandtschaft bzw. Identität des Minerals mit anderen Mineralen und synthetischen Verbindungen wird diskutiert.
Mineralogical data on a sulphosalt from the Rhodope mountains, Bulgaria
Summary During an attempt to determine the crystal structure of bonchevite, this mineral was found to consist of two phases. Previously it was thought to have the composition PbBi4S7. The main constituent could unambiguously be identified as galenobismutite. For the rest the lattice constants (a0=13.58±0,02 Å, b0=20.51±0,07 Å, c0=4.09±0.07 Å), indicated a new mineral. Space group is Bbmm. An indexed powder diagram (with d-values) is given.The emission spectrographic analysis shows Pb and Bi to be main components, Cu and Ag to be minor components, and traces only of Zn and Sn. The structure analysis has led to the formula Me5S6, with Me-atoms of approximately the same atomic number; therefore, the chemical formula has to be Pb3Bi2S6, with Z=4.In a structural classification the mineral belongs to the andoriteramdohrite-fizelyite-group. The relationships to or the identity with other minerals and synthetic compounds are discussed.相似文献
2.
Tornadoes have occurred in the territory of the Czech Republic throughout history. Although their frequency and intensity are not as high as in the USA, they can cause severe damage as well. That is why a systematic effort to document individual occurrences of this dangerous meteorological phenomenon as far as possible back into the past began in the 1990s. The aim of this investigation is to extend the first European catalogue of tornadoes originally published by Wegener [Wegener A., 1917. Wind-und Wasserhosen in Europe], by the addition of these cases from the Czech Republic.This paper adds further to Setvák, Šálek and Munzar [Setvák M., Šálek M., Munzar J., 2003. Tornadoes within the Czech Republic—from medieval chronicles to the internet society. Atmos. Res. 67–68, 589–605], who reported the earliest documented tornado in the land of the Czech Republic which occurred in AD 1119 in Prague. In so doing, it presents recently discovered tornado cases from the 16th to the early 20th centuries, found in a variety of historical sources since the last ECSS conference held in Prague in 2002. In particular we will focus on the case from Jablonec nad Nisou (northern Bohemia) in 1925, which was probably the first case in the Czech Republic with accompanying photographic documentation of damage caused by a tornado. 相似文献
3.
F. Francés 《Stochastic Hydrology and Hydraulics》1998,12(4):267-283
Due to the social and economic implications, flood frequency analysis must be done with the highest precision. For this reason,
the most suitable statistical model must be selected, and the maximum amount of information must be used. Floods in Mediterranean
rivers can be produced by two different mechanisms, which forces the use of a non-traditional distribution like the TCEV.
The information can be increased by using additional non-systematic data, or with a regional analysis, or both. Through the
statistical gain concept, it has been shown that in most cases the use of additional non-systematic information can decrease
the quantile estimation error in about 50%. In a regional analysis, the␣benefit of additional information in one station,
is propagated to the rest of␣the␣stations with only a small decrease with respect to the at-site equivalent analysis. 相似文献
4.
C. Medici A. Butturini S. Bernal E. Vázquez F. Sabater J. I. Vélez F. Francés 《水文研究》2008,22(18):3814-3828
A progressive perceptual understanding approach was used to identify a model structure able to represent the non‐linear behaviour of the hydrological cycle in a small intermittent Mediterranean stream. The initial lumped model structure consisting of a series of four connected water tanks (LU3) progressed to a model with five tanks (LU4), and finally to a semidistributed model structure (SD4) in which spatial variability of the evapotranspiration according to the vegetation cover and to the local aspect was considered. In the final model structure, which gave the best fit (Nash–Sutcliffe efficiency index = 0·78), an additional tank representing the riparian zone was included (SD4‐R). Results showed that the abrupt changes of the riparian water table during summer and the formation of a perched water table during the transition from dry to wet conditions were the main mechanisms leading to the non‐linear hydrological behaviour. The transpiration process from the saturated zone and the spatial variability of evapotranspiration resulted in key factors successfully representing the annual water balance. The spatial and temporal validations carried out for each of the four model structures considered in this study supported the hypothesis adopted during the calibration process. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
5.
Spatial scale effect on the upper soil effective parameters of a distributed hydrological model 总被引：1，自引：0，他引：1
Nonlinear dynamics and spatial variability in hydrological systems make the formulation of scaling theories difficult. Therefore, the development of knowledge related to scale effects, scaling techniques, parameterization and linkages of parameters across scales is highly relevant. The main purpose of this work is to analyse the spatial effect of the static storage capacity parameter Hu and the saturated hydraulic conductivity parameter ks from microscale (sub‐grid level) to mesoscale (grid level) and its implication to the definition of an optimum cell size. These two parameters describe the upper soil water characteristics in the infiltration process conceptualization of the TETIS hydrological model. At microscale, the spatial heterogeneity of Hu and ks was obtained generating random parameter fields through probability distribution functions and a spatial dependence model with pre‐established correlation lengths. The effective parameters at mesoscale were calculated by solving the inverse problem for each parameter field. Results indicate that the adopted inverse formulation allows transferring the nonlinearity of the system from microscale to the mesoscale via non‐stationary effective parameters. Their values at each cell and time step are in the range of zero to the mean value of the parameter at microscale. The stochastic simulations showed that the variance of the estimated effective parameters decreases when the ratio between mesoscale cell size and correlation length at microscale increases. For a ratio greater than 1, we found cell sizes having the characteristics of a representative elementary area (REA); in such case, the microscale variability pattern did not affect the system response at mesoscale. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
6.
A new method is presented for the self-noise estimation of a seismometer using a single, side-by-side, reference instrument
and taking into consideration the misalignment in the orientation of both seismometers. The self-noise of seismometers is
extracted directly from the measurements without using any information relating to the transfer functions. This procedure
can be applied if the self-noise of the reference seismometer is well known and defined, or if the self-noise of the reference
seismometer is sufficiently below the self-noise of the tested instrument and can be neglected. The latter case applies to
this study. An algorithm is also developed where we apply self-noise data in order to determine the orientation misalignment
between two seismometers, which is then resolved in three-dimensional space. This new method provides an estimate of the self-noise
and can also be used to extract some parameters of the installed seismic system in comparison with the reference seismic system,
such as generator constants and seismometer orientation or to eliminate unwanted noise sources, which have their origin in
the seismic station’s design. The new technique was applied to the CMG-3ESPC and CMG-40T seismometers, where an STS-2 instrument
served as the reference seismometer. 相似文献
7.
Determination of a seismometer’s generator constant, azimuth, and orthogonality in three-dimensional space using a reference seismometer 总被引：2，自引：0，他引：2
To accurately predict the performance of a seismometer, knowledge of its key parameters is required. We present a new method that requires a single reference instrument to estimate some of the important parameters of the seismometer, such as the ratio of the generator constants, the orthogonality deviation, and the rotation in space and in the horizontal plane with regards to the reference instrument. The procedure is performed in the three-dimensional spaces where the Euler rotation theorem is applied in order to define a transformation, which is then used to transform the detection of the reference seismometer as well as the detection of the instrument under test. The estimated transformation matrix is defined as an upper triangular matrix, where its elements contain the information regarding the parameters of the tested seismometer, which are then evaluated using the Euler angles. The new method has been verified on a pair consisting of two STS-2 seismometers and on a pair consisting of one CMG-3T and one STS-2 seismometer. 相似文献
8.
Patricija Mozetič Cosimo Solidoro Gianpiero Cossarini Giorgio Socal Robert Precali Janja Francé Franco Bianchi Cinzia De Vittor Nenad Smodlaka Serena Fonda Umani 《Estuaries and Coasts》2010,33(2):362-375
The results of the updated and quality-checked data base of field observations on chlorophyll a (Chl a) collected in the period 1970–2007 in the Northern Adriatic Sea are presented. From the last decade, SeaWiFS satellite information
was also considered. Results demonstrate a global tendency towards Chl a reduction in the period of investigation, which is more marked in the eutrophic area under the influence of the Po River.
In the rest of the basin, which presents meso- or oligotrophic characteristics, long-term changes are more difficult to detect.
The long-term field dataset can be divided into two periods: the last decade characterized by the strong decrease observed
in the whole northern Adriatic and the earlier period with no or slight increase. The recent substantial reduction of Chl
a concentrations is confirmed all over the basin (−0.11 mg m−3 year−1) from satellite-derived information. Results are consistent with recently evidenced decrease in concentrations of phosphate
and ammonia and point to the existence of oligotrophication in the Northern Adriatic. Results indicate forcefully that the
still common perception of the Adriatic Sea as a very eutrophic basin is no longer appropriate, at least for its northern
part and in recent years. 相似文献
9.
Poličnik Helena Batič Franc Ribarič Lasnik Cvetka 《Journal of Atmospheric Chemistry》2004,49(1-3):223-230
Many lichens are very sensitive to air pollution due to their symbiotic nature. However, they are generally less sensitive to toxic effects of trace elements; therefore they can be used as accumulator organisms for estimating concentrations of these elements in the environment. Heavy metal accumulation in lichens is a commonly used bioindication method for assessing heavy metal ambient levels. An active biomonitoring method was used for the determination of short-term accumulation of zinc, lead, arsenic and cadmium by epiphytic lichens transplanted at different localities in Slovenia polluted by heavy metals. The atomic absorption spectrophotometry method was used for the determination of heavy metal content in lichen thalli. The content of heavy metals in lichens collected in the background area with clean air (Rogla, Pohorje Mountains) was used as the reference value. Lichens were transplanted from Rogla using the branch transplantation technique for a period of 6 months in the surroundings of Slovenian thermal power plants (Velenje, otanj, Zavodnje, Veliki Vrh, Vnajnarje, and Dobovec) and close to the lead and zinc ore smelter at erjav. The monthly accumulation of heavy metals was comparable within years at selected locations. Heavy metal pollution was the highest at erjav despite of remediation of lead and zinc ore smelter. The monthly accumulation of all four heavy metals was statistically significantly higher in lichens exposed at erjav than at other localities. 相似文献
10.
Use of Systematic, Palaeoflood and Historical Data for the Improvement of Flood Risk Estimation. Review of Scientific Methods 总被引：2，自引：0，他引：2
Gerardo Benito Michel Lang Mariano Barriendos M. Carmen Llasat Felix Francés Taha Ouarda Varyl Thorndycraft Yehouda Enzel Andras Bardossy Denis Coeur Bernard Bobée 《Natural Hazards》2004,31(3):623-643
The catastrophic floods recently occurring in Europe warn of the critical need forhydrologic data on floods over long-time scales. Palaeoflood techniques provideinformation on hydrologic variability and extreme floods over long-time intervals(100 to 10,000 yr) and may be used in combination with historical flood data (last1,000 yr) and the gauge record (last 30–50 yr). In this paper, advantages anduncertainties related to the reconstruction of palaeofloods in different geomorphologicalsettings and historical floods using different documentary sources are described.Systematic and non-systematic data can be combined in the flood frequency analysisusing different methods for the adjustment of distribution functions. Technical toolsintegrating multidisciplinary approaches (geologic, historical, hydraulic and statistical)on extreme flood risk assessment are discussed. A discussion on the potential theoreticalbases for solving the problem of dealing with non-systematic and non-stationary data ispresented. This methodology is being developed using new methodological approachesapplied to European countries as a part of a European Commission funded project (SPHERE). 相似文献