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The Upper Jurassic Tordillo Formation is exposed along the western edge of the Neuquén Basin (west central Argentina) and consists of fluvial strata deposited under arid/semiarid conditions. The pebble composition of conglomerates, mineralogical composition of sandstones and pelitic rocks, and major- and trace-element geochemistry of sandstones, mudstones, and primary pyroclastic deposits are evaluated to determine the provenance and tectonic setting of the sedimentary basin. Conglomerates and sandstones derived almost exclusively from volcanic sources. The stratigraphic sections to the south show a clast population of conglomerates dominated by silicic volcanic fragments and a predominance of feldspathic litharenites. This framework composition records erosion of Triassic–Jurassic synrift volcaniclastic rocks and basement rocks from the Huincul arch, which was exhumed as a result of Late Jurassic inversion. In the northwestern part of the study area, conglomerates show a large proportion of mafic and acidic volcanic rock fragments, and sandstones are characterised by a high content of mafic volcanic rock fragments and plagioclase. These data suggest that the source of the sandstones and conglomerates was primarily the Andean magmatic arc, located west of the Neuquén Basin. The clay mineral assemblage is interpreted as the result of a complex set of factors, including source rock, climate, transport, and diagenesis. Postdepositional processes produced significant variations in the original compositions, especially the fine-grained deposits. The Tordillo sediments are characterised by moderate SiO2 contents, variable abundances of K2O and Na2O, and a relatively high proportion of ferromagnesian elements. The degree of chemical weathering in the source area, expressed as the chemical index of alteration, is low to moderate. The major element geochemistry and Th/Sc, K/Rb, Co/Th, La/Sc, and Cr/Th values point to a significant input of detrital volcanic material of calcalkaline felsic and intermediate composition. However, major element geochemistry is not useful for interpreting the tectonic setting. Discrimination plots based on immobile trace elements, such as Ti, Zr, La, Sc, and Th, show that most data lie in the active continental margin field. Geochemical information is not sufficiently sensitive to differentiate the two different source areas recognized by petrographic and modal analyses of conglomerates and sandstones.  相似文献   
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The role of the major biogeochemical processes in Hg cycling at the sediment–water interface was investigated in the Grado Lagoon (Northern Adriatic Sea). This wetland system has been extensively contaminated from the Idrija Hg Mine (Slovenia) through the Isonzo River suspended load carried by tidal fluxes. Three approaches were used to study the sediment–water exchange of total Hg (THg), methylmercury (MeHg), reactive Hg (RHg) and dissolved gaseous Hg (DGHg): (1) estimation of diffusive fluxes from porewater and overlying water concentrations, (2) measurements of benthic fluxes using a deployed light benthic chamber in situ and (3) measurements of benthic fluxes during oxic–anoxic transition with a laboratory incubation experiment. The THg solid phase, ranging between 9.5 and 14.4 μg g−1, showed slight variability with depth and time. Conversely, MeHg contents were highest (up to 21.9 ng g−1) at the surface; they tended to decrease to nearly zero concentration with depth, thus suggesting that MeHg production and accumulation occur predominantly just below the sediment–water interface. Porewater MeHg concentrations (0.9–7.9 ng L−1, 0.15–15% of THg) varied seasonally; higher contents were observed in the warmer period. The MeHg diffusive fluxes (up to 17 ng m−2 day−1) were similar to those in the nearby Gulf of Trieste [Covelli, S., Horvat, M., Faganeli, J., Brambati, A., 1999. Porewater distribution and benthic flux of mercury and methylmercury in the Gulf of Trieste (Northern Adriatic Sea). Estuar. Coast. Shelf Sci. 48, 415–428], although the lagoon sediments contained four-fold higher THg concentrations. Conversely, the THg diffusive fluxes in the lagoon (up to 110 ng m−2 day−1) were one- to two-fold higher than those previously estimated for the Gulf of Trieste. The diurnal MeHg benthic fluxes were highest in summer at both sites (41,000 and 33,000 ng m−2 day−1 at the fishfarm and in the open lagoon, respectively), thus indicating the influence of temperature on microbial processes. The diurnal variations of dissolved THg and especially MeHg were positively correlated with O2 and inversely with DIC, suggesting an important influence of benthic photosynthetic activities on lagoon benthic Hg cycling, possibly through the production of organic matter promptly available for methylation. The results from the dark chamber incubated in the laboratory showed that the regeneration of dissolved THg was slightly affected by the oxic–anoxic transition. Conversely, the benthic flux of MeHg was up to 15-fold higher in sediments overlain by O2 depleted waters. In the anoxic phase, the MeHg fluxes proceeded in parallel with Fe fluxes and the methylated form reached approximately 100% of dissolved THg. The MeHg is mostly released into overlying water (mean recycling efficiency of 89%) until the occurrence of sulphide inhibition, due to scavenging of the available Hg substrate for methylation. The results suggest that sediments in the Grado Lagoon, especially during anoxic events, should be considered as a primary source of MeHg for the water column.  相似文献   
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Quantitative sinkhole hazard assessments in karst areas allow calculation of the potential sinkhole risk and the performance of cost-benefit analyses. These estimations are of practical interest for planning, engineering, and insurance purposes. The sinkhole hazard assessments should include two components: the probability of occurrence of sinkholes (sinkholes/km2 year) and the severity of the sinkholes, which mainly refers to the subsidence mechanisms (progressive passive bending or catastrophic collapse) and the size of the sinkholes at the time of formation; a critical engineering design parameter. This requires the compilation of an exhaustive database on recent sinkholes, including information on the: (1) location, (2) chronology (precise date or age range), (3) size, and (4) subsidence mechanisms and rate. This work presents a hazard assessment from an alluvial evaporite karst area (0.81 km2) located in the periphery of the city of Zaragoza (Ebro River valley, NE Spain). Five sinkholes and four locations with features attributable to karstic subsidence where identified in an initial investigation phase providing a preliminary probability of occurrence of 0.14 sinkholes/km2 year (11.34% in annual probability). A trenching program conducted in a subsequent investigation phase allowed us to rule out the four probable sinkholes, reducing the probability of occurrence to 0.079 sinkholes/km2 year (6.4% in annual probability). The information on the severity indicates that collapse sinkholes 10–15 m in diameter may occur in the area. A detailed study of the deposits and deformational structures exposed by trenching in one of the sinkholes allowed us to infer a modern collapse sinkhole approximately 12 m in diameter and with a vertical throw of 8 m. This collapse structure is superimposed on a subsidence sinkhole around 80 m across that records at least 1.7 m of synsedimentary subsidence. Trenching, in combination with dating techniques, is proposed as a useful methodology to elucidate the origin of depressions with uncertain diagnosis and to gather practical information with predictive utility about particular sinkholes in alluvial karst settings: precise location, subsidence mechanisms and magnitude, and timing and rate of the subsidence episodes.  相似文献   
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Debris and mudflows are some of the main geological hazards in the mountain foothills of the Chilean capital city of Santiago. There, the risk of flows triggered in the basins of ravines that drain the range into the city increases with time due to the city growth. A multivariate statistical study based on the logistic regression method is presented. The model provides equations that allow the computation of combined meteorological triggering factors associated with a probability of rain-induced flow occurrence. Daily rainfall, accumulated rainfall and the snowfall level, traditionally considered as the relevant factors, are analysed for a 25-year period. The results show a strong relevance of the rainfall on the day of the flow event over the other factors. However, the relatively low probabilities returned for some real flow events suggest that the model does not capture all the significant variables and the problem is more complex than as it has been traditionally assumed, and further investigations are needed to develop predictive models of flow triggering.  相似文献   
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Unusual large-scale phytoplankton blooms in the equatorial Pacific   总被引:1,自引:0,他引:1  
Unusual large-scale accumulations of phytoplankton occurred across 10,000 km of the equatorial Pacific during the 1998 transition from El Niño to La Niña. The forcing and dynamics of these phytoplankton blooms were studied using satellite-based observations of sea surface height, temperature and chlorophyll, and mooring-based observations of winds, hydrography and ocean currents. During the bloom period, the thermocline (nutricline) was anomalously shallow across the equatorial Pacific. The relative importance of processes that enhanced nutrient flux into the euphotic zone differed between the western and eastern regions of the blooms. In the western bloom region, the important vertical processes were turbulent vertical mixing and wind-driven upwelling. In contrast, the important processes in the eastern bloom region were wave-forced shoaling of nutrient source waters directly into the euphotic zone, along-isopycnal upwelling, and wind-driven upwelling. Advection by the Equatorial Undercurrent spread the largest bloom 4500 km east of where it began, and advection by meridional currents of tropical instability waves transported the bloom hundreds of kilometers north and south of the equator. Many processes influenced the intricate development of these massive biological events. Diverse observations and novel analysis methods of this work advance the conceptual framework for understanding the complex dynamics and ecology of the equatorial Pacific.  相似文献   
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Fish assemblages from two beaches, one in the inner and the other in the outer Sepetiba Bay (latitude: 22°54′–23°04′S; longitude: 43°34′–44°10′W), Southeast Brazil, were sampled by beach seine net, simultaneously, on both seasonal and diel scales, between August 1998 and June 1999. Sites were selected to encompass different environmental conditions which reflect the two bay zones, thus providing a comprehensive assessment of the factors influencing surf zone fish assemblages, and their spatial, seasonal and diel variations. A total of 55 fish species was recorded, mostly young-of-the-year. Anchoa tricolor, Micropogonias furnieri, Gerres aprion, Diapterus rhombeus, Harengula clupeola, Atherinella brasiliensis and Mugil liza were numerically dominant and contributed to 95.2% of the total fish catches. Strong differences in fish assemblages were observed between the two areas, with higher number of species in the outer bay. Increases in fish numbers occurred in winter, while the highest biomass occurred in winter and summer. Transparency, followed by salinity, was responsible for most of the spatial variability and played an important role in structuring fish assemblages. Overall, diel patterns did not reveal any significant trends; however, if we consider each season separately, an increase in fish numbers during the day with peak at sunset was observed in winter, and a higher biomass occurred at night in winter and summer. Species preferences for various combinations of environmental variables are responsible for shifts in the structure and overall abundance of assemblages and dictated some patterns. The sciaenid M. furnieri, the second most abundant species, occurred only in the inner zone, being more abundant in winter. The species of Engraulidae were more abundant in the outer zone in winter/spring during the day. The gerreids G. aprion and D. rhombeus occurred mainly in summer. Overall, temporal fluctuations act more at a specific level than at a structural one, and may be linked to some particular stages of the fish life cycle, but do not significantly influence the spatial organization.  相似文献   
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Trace element concentrations (Pb, Cd, Mn, Fe, and Zn) were measured along four surface water transects across the continental shelf off Baja California, to evaluate the magnitude of heavy metal contamination in the coastal waters along the US-Mexican boundary. These initial measurements of trace elements in Mexican neritic waters revealed offshore concentration gradients, with the highest levels in coastal waters with high salinities and nutrient concentrations. There were also longshore gradients, with lower concentrations in the southern locations. Although the relative enrichment of metals detected at nearshore stations along the US-Mexican border appeared to correspond to wastewater discharges in that area, these trace metal enhancements were found to be primarily associated with physical oceanographic processes (upwelling and advection), rather than anthropogenic inputs. This was demonstrated both by metal-nutrient correlations and multivariate statistical analyses. Mass balance calculations also indicated that about 1% of Cd, 9% of Zn, and 29% of Pb were from urban discharges within the area.  相似文献   
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