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1.
Alicja Wudarska Ewa S&#x;aby Michael Wiedenbeck Jaime D. Barnes Magali Bonifacie Neil C. Sturchio Grard Bardoux Frdric Couffignal Johannes Glodny Linnea Heraty Timm John Christof Kusebauch Sathish Mayanna Franziska D. H. Wilke Ewa Deput 《Geostandards and Geoanalytical Research》2021,45(1):121-142
Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca10(PO4)6(F,Cl,OH)2 solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for 37Cl/35Cl homogeneity using SIMS followed by δ37Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean 37Cl/35Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ37ClSMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 103δ37ClSMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25. 相似文献
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Franziska D.H. Wilke Patrick J. O'Brien Uwe Altenberger Matthias Konrad-Schmolke M. Ahmed Khan 《Lithos》2010,114(1-2):70-85
Metabasites were sampled from rock series of the subducted margin of the Indian Plate, the so-called Higher Himalayan Crystalline, in the Upper Kaghan Valley, Pakistan. These vary from corona dolerites, cropping out around Saif-ul-Muluk in the south, to coesite–eclogite close to the suture zone against rocks of the Kohistan arc in the north. Bulk rock major- and trace- element chemistry reveals essentially a single protolith as the source for five different eclogite types, which differ in fabric, modal mineralogy as well as in mineral chemistry. The study of newly-collected samples reveals coesite (confirmed by in situ Raman spectroscopy) in both garnet and omphacite. All eclogites show growth of amphiboles during exhumation. Within some coesite-bearing eclogites the presence of glaucophane cores to barroisite is noted whereas in most samples porphyroblastic sodic–calcic amphiboles are rimmed by more aluminous calcic amphibole (pargasite, tschermakite, and edenite). Eclogite facies rutile is replaced by ilmenite which itself is commonly surrounded by titanite. In addition, some eclogite bodies show leucocratic segregations containing phengite, quartz, zoisite and/or kyanite. The important implication is that the complex exhumation path shows stages of initial cooling during decompression (formation of glaucophane) followed by reheating: a very similar situation to that reported for the coesite-bearing eclogite series of the Tso Morari massif, India, 450 km to the south-east. 相似文献
3.
Franziska?Ziska Birgit?QuackEmail author Susann?Tegtmeier Irene?Stemmler Kirstin?Krüger 《Journal of Atmospheric Chemistry》2017,74(2):245-260
Halogenated Very Short-lived Substances (VSLS), such as bromoform, dibromomethane and methyl iodide, are naturally produced in the oceans and are involved in ozone depletion in the troposphere and the stratosphere. The effect of climate change on the oceanic emissions of these compounds is not well quantified. Based on present-day observed global oceanic and atmospheric concentrations, and historic and future data from three CMIP5 models, past and future sea-to-air fluxes of these VSLS are calculated. The simulations are used to infer possible effects of projected changes of physical forcing on emissions in different oceanic regimes. CMIP5 model output for 1979–2100 from the historical scenario and the RCP scenarios 2.6 and 8.5 are used as input data for the emission calculations. Of the parameters that have the main influence on the sea-to-air fluxes, the global sea surface temperatures show a steady increase during the twenty-first century, while the projected changes of sea surface wind speed is very small. The calculated emissions based on the historical CMIP5 model runs (1979–2005) increased over the 26 year period and agree well with the emissions based on ERA-Interim data. The future sea-to-air fluxes of VSLS generally increase during the twenty-first century under the assumption of constant concentration fields in the ocean and atmosphere. The multi-model mean global emissions of bromoform increase by 29.4% (9.0%) between 1986 and 2005 and 2081–2100 under RCP 8.5 (2.6) and dibromomethane and methyl iodide emissions increase by 23.3% (6.4%) and 5.5% (1.5%), respectively. Uncertainties of the future emission estimates, driven by ongoing environmental changes such as changing oceanic productivity (not considered in this study) are discussed. 相似文献
4.
F. J. Chirindja T. Dahlin N. Perttu F. Steinbruch R. Owen 《Hydrogeology Journal》2016,24(6):1583-1592
This study focusses on the hydrogeology of Urema Graben, especially possible interactions between surface water and groundwater around Lake Urema, in Gorongosa National Park (GNP). Lake Urema is the only permanent water source for wildlife inside GNP, and there are concerns that it will disappear due to interferences in surface-water/groundwater interactions as a result of changes in the hydraulic environment. As the lake is the only permanent water source, this would be a disaster for the ecosystem of the park. The sub-surface geology in Urema Graben was investigated by 20 km of electrical resistivity tomography (ERT) and three magnetic resonance sounding (MRS) surveys. The average depth penetration was 60 and 100 m, respectively. The location of the ERT lines was decided based on general rift morphology and therefore orientated perpendicular to Urema Graben, from the transitional areas of the margins of the Barue platform in the west to the Cheringoma plateau escarpments in the east. ERT and MRS both indicate a second aquifer, where Urema Lake is a window of the first upper semi-confined aquifer, while the lower aquifer is confined by a clay layer 30–40 m thick. The location and depth of this aquifer suggest that it is probably linked to the Pungwe River which could be a main source of recharge during the dry season. If a dam or any other infra-structure is constructed in Pungwe River upstream of GNP, the groundwater level will decrease which could lead to drying out of Urema Lake. 相似文献
5.
The Thiem equation of radial groundwater flow to a well is more than 100 years old and is still commonly used. Here, deviations caused by some of its simplifications are quantified by comparing the analytical to a numerical model that allows the implementation of more complex geometries. The assumption of horizontal flow in the Thiem equation, which necessitates uniform inflow over the entire screen length of the fully penetrating well, was found to cause deviations from actual pumping wells where the pump is placed above the screen, resulting in non-uniform inflow and additional drawdown. The same applies to partially penetrating wells, where inflow peaks and additional drawdown occur, especially when the well is screened in the lower part of the aquifer. The use of the Thiem equation in the near-field of a well should thus be restricted to situations where the screen inflow is relatively uniformly distributed, e.g. when it covers large portions of the aquifer thickness. The presence of a gravel pack and a background gradient, on the other hand, are of limited importance. 相似文献
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Measuring snow ablation rates in alpine terrain with a mobile multioffset ground‐penetrating radar system 
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下载免费PDF全文 Ground‐penetrating radar (GPR) has become a promising technique in the field of snow hydrological research. It is commonly used to measure snow depth, density, and water equivalent over large distances or along gridded snow courses. Having built and tested a mobile lightweight set‐up, we demonstrate that GPR is capable of accurately measuring snow ablation rates in complex alpine terrain. Our set‐up was optimized for efficient measurements and consisted of a multioffset radar with four pairs of antennas mounted to a plastic sled, which was small enough to permit safe and convenient operations. Repeated measurements at intervals of 2 to 7 days were taken during the 2014/2015 winter season along 10 profiles of 50 to 200 m length within two valleys located in the eastern Swiss Alps. Resulting GPR‐based data of snow depth, density, and water equivalent, as well as their respective change over time, were in good agreement with concurrent manual measurements, in particular if accurate alignment between repeated overpasses could be achieved. Corresponding root‐mean‐square error (RMSE) values amounted to 4.2 cm for snow depth, 17 mm for snow water equivalent, and 22 kg/m3 for snow density, with similar RMSE values for corresponding differential data. With this performance, the presented radar set‐up has the potential to provide exciting new and extensive datasets to validate snowmelt models or to complement lidar‐based snow surveys. 相似文献
8.
Markus Tum Franziska Strauss Ian McCallum Kurt Günther Erwin Schmid 《Carbon balance and management》2012,7(1):1-13
Background
Accurate, high-resolution mapping of aboveground carbon density (ACD, Mg C ha-1) could provide insight into human and environmental controls over ecosystem state and functioning, and could support conservation and climate policy development. However, mapping ACD has proven challenging, particularly in spatially complex regions harboring a mosaic of land use activities, or in remote montane areas that are difficult to access and poorly understood ecologically. Using a combination of field measurements, airborne Light Detection and Ranging (LiDAR) and satellite data, we present the first large-scale, high-resolution estimates of aboveground carbon stocks in Madagascar.Results
We found that elevation and the fraction of photosynthetic vegetation (PV) cover, analyzed throughout forests of widely varying structure and condition, account for 27-67% of the spatial variation in ACD. This finding facilitated spatial extrapolation of LiDAR-based carbon estimates to a total of 2,372,680 ha using satellite data. Remote, humid sub-montane forests harbored the highest carbon densities, while ACD was suppressed in dry spiny forests and in montane humid ecosystems, as well as in most lowland areas with heightened human activity. Independent of human activity, aboveground carbon stocks were subject to strong physiographic controls expressed through variation in tropical forest canopy structure measured using airborne LiDAR.Conclusions
High-resolution mapping of carbon stocks is possible in remote regions, with or without human activity, and thus carbon monitoring can be brought to highly endangered Malagasy forests as a climate-change mitigation and biological conservation strategy. 相似文献9.
ABSTRACTThe administration of U.S. President Donald Trump has promised to stop the ongoing spiralling down of the U.S. coal industry. We discuss the origins of the decline and assess the effects of policy interventions by the Trump administration. We find that, with fierce competition from natural gas and renewables, a further decrease of coal consumption must be expected by the old and inefficient U.S. coal-fired electricity generation fleet. By contrast, we consider the overly optimistic (for coal producers) view of the U.S. Energy Information Agency, and test whether the tide for the U.S. coal industry could turn as a result of three potential support measures: (i) revoking the Clean Power Plan (CPP); (ii) facilitating access to the booming Asian market; and (iii) enhanced support for Carbon Capture, Transport and Storage (CCTS) technology. We investigate the short-term and long-term effects on U.S. coal production using a comprehensive partial equilibrium model of the world steam coal market, COALMOD-World (Holz, Haftendorn, Mendelevitch, & von Hirschhausen, 2016). We find that revoking the CPP could stop the downward trend of steam coal consumption in the U.S., but even allowing for additional exports, will not lead to a return of U.S. coal production to the levels of the 2000s, that is, over 900?Mt per year. When global steam coal use is aligned with the 2°C climate target, U.S. steam coal production drops to around 100?Mt per year by 2030 and below 50?Mt by 2050, even if CCTS is available and exports via the U.S. West Coast is possible.Key policy insights
Declining U.S. coal use is primarily caused by competition from natural gas and renewables not by environmental regulation of the coal sector.
Without substantial policy support, U.S. coal-fired generation capacity will continue to decline rapidly.
Revoking the Clean Power Plan will lead to about one eighth higher U.S. coal production in the next years.
Carbon Capture, Transport and Storage does not prevent the rapid decline of coal use required under stringent climate policy.
Even in the most extreme pro-coal scenarios with additional export possibilities, U.S. coal production will not return to its pre-2010 levels.
10.
Anna W. McCallum Gary C.B. Poore Alan Williams Franziska Althaus Tim O'Hara 《Marine Ecology》2013,34(3):298-312
The use of environmental data in biogeographic studies of the deep sea is providing greater insight into the processes underlying large‐scale patterns of diversity. Recent surveys of Australia's western continental margin (~100–1100 m) provide systematic sampling of invertebrate megafauna along a gradient of 22° of latitude (13–35° S). Diversity patterns of decapod crustaceans were examined and we investigated the relative importance of environmental and spatial predictor variables on both species richness (alpha diversity) and species turnover. Distance‐based linear models (DistLM) indicated a suite of variables were important in predicting species turnover, of which temperature and oxygen were the most influential. These reflected the oceanographic features that dominate distinct depth bathomes along the slope. The numbers of species within samples were highly variable; a small but significant increase in diversity towards the tropics was evident. Replicated sampling along the margin at ~100 m and ~400 m provided an opportunity to compare latitudinal patterns of diversity at different depths. On the shallow upper slope (~400 m) temperature was disassociated from latitude and the latter proved to be the best predictor of sample species richness. The predictive power of latitude over other variables indicates that proximity to the highly diverse Indo‐West Pacific (IWP) may be important, especially considering that almost 40% of species in this study had a wide IWP distribution. In the management of Australia's marine environments, geomorphic surrogates have been emphasised when defining areas for protection. We found sea‐floor characteristics were relatively less important in predicting richness or community composition. 相似文献