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1.
R. D. Vis A. Mrowiec P. J. Kooyman K. Matsubara D. Heymann 《Meteoritics & planetary science》2002,37(10):1391-1399
Abstract— High‐resolution transmission electron microscopy micrographs of acid‐resistant residues of the Allende, Leoville, and Vigarano meteorites show a great variety of carbon structures: curved and frequently twisted and intertwined graphene sheets, abundant carbon black‐like particles, and hollow “sacs”. It is suggested that perhaps all of these are carriers for the planetary Q‐noble gases in these meteorites. Most of these materials are pyrocarbons that probably formed by the pyrolysis of hydrocarbons either in a gas phase, or on hot surfaces of minerals. An attempt was made to analyze for argon with particle‐induced x‐ray emission in 143 spots of grains of floating and suspended matter from freeze‐dry cycles of an Allende bulk sample in water, and floating “black balls” from sonication in water of samples from the Allende meteorite. The chemical compositions of these particles were obtained, but x‐ray signals at the wavelength of argon were obtained on only a few spots. 相似文献
2.
D. Heymann C.C.A.H. Van Der Stap R.N. Vis H. Verheul 《Meteoritics & planetary science》1987,22(1):3-15
Carbon contents of three Dark Inclusions (DI's) of the Allende meteorite, measured chemically, range from 0.56 to 1.17 weight %. When one includes the data reported by Bunch, Chang, and Ott (two DI's), the lower limit is 0.44%. The C-concentration map of a 1.6 × 1.6 mm2 area straddling the boundary of a DI and matrix, or else of a DI and its dark halo, obtained with a 12C (d,p)13 C nuclear microprobe, shows that the C-content of the core of the DI is very uniform, and that the C-content of the rim is 2.9 ± 0.3 times larger. Variability of C-content of matrix and matrix-like areas of Allende appears to be the rule. DI's cannot be reworked bulk Allende, or precursor for bulk Allende without the addition, respectively removal of significant amounts of carbon. However, some Type 1 DI's might be reworked Allende matrix or precursor matter for that matrix. 相似文献
3.
The output of material from 11 small drainage basins in the Keuper region of central Luxembourg is considered. Attention is given to differences between forested and cultivated basins. Whilst the output of suspended solids from the cultivated Mosergriecht catchment may be as much as five times higher than from the forested Keiwelsbaach, the solute load is only 50 per cent and the runoff 20 per cent higher. Relationships between dispersed clay in suspension and the water chemistry observed for the forested drainage basins are not present in the cultivated catchments. Water having a milky appearance and containing dispersed clay is of more frequent occurrence in forested basins where subsurface runoff occurs in macropores and cracks in the undisturbed soil. 相似文献
4.
During the last few years it has been shown that the results of model tests of harbour basins and moored ships are highly dependent on the correct reproduction of wave groups and the attached long waves. Although these bounded long waves are of second order and thus of a rather limited height, resonance and shoaling effects can increase their influence on the results of model investigations. In traditional first order wave generation, the boundary conditions at the wave board are not fulfilled for the bounded long waves, and consequently various spurious, free long waves are unintentionally produced. This paper outlines the general equations and the solution for a rotating and translating wave board. The translatory case is treated in detail, i.e. a physical interpretation of all the second order terms is given, and an approximate control signal for the suppression of spurious long waves for practical use is described. Finally, laboratory experiments successfully verify the various long wave terms and the effectiveness of the suppression terms. 相似文献
5.
Dieter Heymann Franco Cataldo Mark h. Thiemens Roelof Fokkens Nico m. m. Nibbering Ronald d. Vis 《Meteoritics & planetary science》2000,35(2):355-361
Abstract— Toluene extracts from two (CSn)x photopolymers were examined with high‐performance liquid chromatography (HPLC), matrix‐assisted laser desorption ionization time‐of‐flight (MALDI‐TOF) mass spectrometry, particle‐induced x‐ray emission (PIXE), and 12C(d,p)13C nuclear microprobing. the extracts contained elemental s and at least from 17 to 20 distinct cmsn compounds with m/z less than ～500 amu. Whereas H2S is the dominant S‐bearing compound of the normal jovian atmosphere, elemental S, CS, and CS2 were observed at Shoemaker‐Levy 9 cometary impact sites and at altitudes of the transiently disturbed jovian atmosphere where photodissociation and photopolymerization occur. It is uncertain whether the CS2 molecular densities were sufficiently large for both to occur, but photopolymerization could have occurred during larger impacts of Jupiter's history. Because the known stable CmSn compounds are yellow, orange and deep red, they could contribute significantly to the colors of the jovian clouds. 相似文献
6.
Late Holocene sedimentary changes in floodplain and shelf environments of the Tagus River (Portugal)
Geert-Jan Vis Cornelis Kasse Simon Jung Alexander Prick 《Proceedings of the Geologists' Association. Geologists' Association》2010,121(2):203-217
Sedimentary changes during the last ∼2500 years have been reconstructed from cored sedimentary records from the deltaic floodplain of the Lower Tagus Valley and the Tagus mudbelt on the continental shelf offshore Lisbon. We used a multi-proxy approach consisting of sedimentology, grainsize, pollen data and magnetic susceptibility. In the floodplain grainsize coarsened and sedimentation rate and magnetic susceptibility increased during the late Holocene due to an increased flooding frequency and/or intensity. On the Tagus shelf the mudbelt grainsize fined, together with a higher sedimentation rate and increased magnetic susceptibility. The fining grainsize is explained by an increased suspended sediment flux towards the shelf and subdued winnowing. Floodplain and shelf records were correlated by radiocarbon dating and changes in sediment characteristics. We identified four depositional phases (∼2300/∼1600/∼1100/∼670 cal BP) on the floodplain and the shelf. These are tentatively explained by land-use changes in the Tagus catchment. 相似文献
7.
Lukas Jonkers Furu Mienis Wim Boer Ian R. Hall Geert-Jan A. Brummer 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(8):1027-1038
North Atlantic sediment drifts are valuable archives for paleoceanographic reconstructions spanning various timescales. However, the short-term dynamics of such systems are poorly known, and this impinges on our ability to quantitatively reconstruct past change. Here we describe a high-resolution 319-day time-series of hydrodynamics and near-bottom (4 m) particulate matter flux variability at a 2600 m deep site with an extremely high sediment accumulation rate on the southern Gardar Drift in the North Atlantic. We compare our findings with the actual deposits at the site. The total annual particle flux amounted to ～360 g m?2 yr?1, varied from ～0.15 to >5.0 g m?2 day?1 and displayed strong seasonal compositional changes, with the highest proportion of fresh biogenic matter arriving after the spring bloom in June and July. Flux variability also depended on the changing input of lithogenic matter that had been (re)suspended for a longer time (decades). Active focussing of material from both sources is required to account for the composition and the magnitude of the total flux, which exceed observations elsewhere by an order of magnitude. The enhanced focussing or increased delivery appeared to be positively related to current velocity. The intercepted annual particle flux accounted for only 60% of the sediment accumulation rate of 600±20 g m?2 yr?1 (0.20±0.07 cm yr?1), indicating higher intra- and inter-annual variability of both the biogenic and lithogenic fluxes and/or advection of additional sediment closer to the seafloor (i.e. <4 m). This temporal variability in the composition and amount of material deposited highlights intra-annual changes in the flux of lithogenic material, but also underscores the importance of (reworked) sediment focussing and seasonality of the biogenic flux. All should be taken into account in the interpretation of the paleorecord from such depositional settings. 相似文献
8.
Hydrographic changes in the NW Arabian Sea are mainly controlled by the monsoon system. This results in a strong seasonal and vertical gradient in surface water properties, such as temperature, nutrients, carbonate chemistry and the isotopic composition of dissolved inorganic carbon (δ13CDIC). Living specimens of the planktic foraminifer species Globigerina bulloides and Globigerinoides ruber, were collected using depth stratified plankton tows during the SW monsoon upwelling period in August 1992 and the NE monsoon non-upwelling period in March 1993. We compare their distribution and the stable isotope composition to the seawater properties of the two contrasting monsoon seasons. The oxygen isotope composition of the shells (δ18Oshell) and vertical shell concentration profiles indicate that the depth habitat for both species is shallower during upwelling (SW monsoon period) than during non-upwelling (NE monsoon period). The calcification temperatures suggest that most of the calcite is precipitated at a depth level just below the deep chlorophyll maximum (DCM), however above the main thermocline. Consequently, the average calcification temperature of G. ruber and G. bulloides is lower than the sea surface temperature by 1.7±0.8 and 1.3±0.9 °C, respectively. The carbon isotope composition of the shells (δ13Cshell) of both species differs from the in situ δ13CDIC found at the calcification depths of the specimens. The observed offset between the δ13Cshell and the ambient δ13CDIC results from (1) metabolic/ontogenetic effects, (2) the carbonate chemistry of the seawater and, for symbiotic G. ruber, (3) the possible effect of symbionts or symbiont activity. Ontogenetic effects produce size trends in Δδ13Cshell–DIC and Δδ18Oshell–w: large shells of G. bulloides (250–355μm) are 0.33‰ (δ13C) and 0.23‰ (δ18O) higher compared to smaller ones (150–250 μm). For G. ruber, this is 0.39‰ (δ13C) and 0.17‰ (δ18O). Our field study shows that the δ13Cshell decreases as a result of lower δ13CDIC values in upwelled waters, while the effects of the carbonate system and/or temperature act in an opposite direction and increase the δ13Cshell as a result lower [CO32−] (or pH) values and/or lower temperature. The Δδ13Cshell–DIC [CO32−] slopes from our field data are close to those reported literature from laboratory culture experiments. Since seawater carbonate chemistry affects the δ13Cshell in an opposite sense, and often with a larger magnitude, than the change related to productivity (i.e. δ13CDIC), higher δ13Cshell values may be expected during periods of upwelling. 相似文献
9.
Abstract— Carbon in the petrologic matrices of a number of ordinary chondrites of groups H, L, and LL, and of types 3 through 6 was studied with a nuclear microprobe and a Raman microprobe. The majority of the matrices had carbon contents in the narrow range between 0.03 and 0.2 wt%. The carbon content decreased only slightly with increasing petrologic type. Carbon-rich coats around troilite and/or metal phases occured in five meteorites. Poorly ordered carbon was found in the matrices. The carbon in the meteorites of higher petrologic types was slightly better ordered than in the meteorites of lower types. The narrow range of carbon contents and the similarity of the structural form of carbon in the matrices of the measured ordinary chondrites, which represent all groups and types, imply that their matrices may contain a common component, which might be of interstellar origin. 相似文献
10.
ABSTRACTGoodness-of-fit measures are important for an objective evaluation of runoff model performance. The Kling-Gupta efficiency (RKG), which has been introduced as an improvement of the widely used Nash-Sutcliffe efficiency, considers different types of model errors, namely the error in the mean, the variability, and the dynamics. The calculation of RKG is implicitly based on the assumptions of data linearity, data normality, and the absence of outliers. In this study, we propose a modification of RKG as an efficiency measure comprising non-parametric components, i.e. the Spearman rank correlation and the normalized flow–duration curve. The performances of model simulations for 100 catchments using the new measure were compared to those obtained using RKG based on a number of statistical metrics and hydrological signatures. The new measure resulted overall in better or comparable model performances, and thus it was concluded that efficiency measures with non-parametric components provide a suitable alternative to commonly used measures. 相似文献