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A new phase equilibria geobarometer determines magmatic storage and crystallization conditions, including pressure, temperature, oxygen fugacity (\({f_{{{\text{o}}_2}}}\)), and the presence of a fluid phase for glass-bearing rocks containing the assemblage plagioclase?+?pyroxene(s). This newly developed geobarometer can better constrain crystallization conditions of shallow (<?500 MPa; <~?20 km), glass-bearing andesites to dacites. The geobarometer utilizes rhyolite-MELTS to determine crystallization conditions in natural pumice and scoria samples. The validity of the geobarometer is tested by comparing it to results from experiments. Uncertainties are assessed using Monte Carlo simulations. We apply the geobarometer to the plag?+?opx?+?cpx-bearing system of Mt. Ruapehu, in the southern Taupo Volcanic Zone, New Zealand. The samples from Mt. Ruapehu are tested from ~?5 to ~?400 MPa and from super-liquidus to 90% crystalline (~ 1200 to ~ 700 °C). Mt. Ruapehu serves as a methodological testing ground for the geobarometer, and results from our geobarometer agree with recent Mt. Ruapehu studies. Results show a distribution of crystallization pressures ranging from 50 to 150 MPa (~?2.0 to 5.9 km) for different eruptions, with modes of 110 MPa (~ 4.3 km) and 130 MPa (~ 5.1 km). These are consistent with field interpretations of different eruptive styles based on juvenile clast textures and previous knowledge of the magma plumbing system. Mt. Ruapehu magmas are fluid saturated, with \({f_{{{\text{o}}_2}}}\) of ΔQFM ~ + 1 (NNO).  相似文献   
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Geotechnical and Geological Engineering - Dispersive soils are susceptible to phenomena of internal and external erosion when in contact with relatively pure water due to its particle’s...  相似文献   
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Uppermost Jurassic limestones of the South‐East Basin (France) are organized into four facies associations that were deposited in four distinct zones: (1) peritidal lagoonal limestones; (2) bioclastic and reefal limestones; (3) pelagic lime mudstones; (4) lime mudstones/calcarenites/coarse breccias. Calcarenite deposits of zone 4 exhibit sedimentary structures that are diagnostic of deposition under wave‐induced combined flow. In subzone 4a, both vertical and lateral transitions from lime mudstone/calcarenite to breccia indicate in situ brecciation under wave‐cyclic loading. Breccias were produced by heterogeneous liquefaction of material previously deposited on the sea floor. Deposits in subzone 4a record relatively long periods (>400 kyr) of sedimentation below wave base, alternating with periods of deposition under wave‐induced currents and periods of in situ deformation. In this zone, storm waves were attenuated by wave–sediment interaction, and wave energy was absorbed by the deformation of soft sediment. With reference to present‐day wave attenuation, water depths in this zone ranged between 50 and 80 m. Landwards of the attenuation zone, in zone 3, storm waves were reduced to fair‐weather wave heights. Storm wave base was not horizontal and became shallower landwards. As a consequence, water depth and wave energy were not linearly related. On a small area of the seaward edge of subzone 4a, cobbles were removed by traction currents and redeposited in subzone 4b. There, they formed a 100‐m‐thick wedge, which prograded over 3 km and was built up by the stacking of 5‐ to 20‐m‐thick cross‐stratified sets of coarse breccia. This wedge records the transport and redeposition of cobbles by a high‐velocity unidirectional component of a combined flow. The increase in flow velocity in a restricted area is proposed to result from flow concentration in a channel‐like structure of the downwelling in the gulf formed by the basin. In more distal subzone 4c, the hydrodynamic effect of wave‐induced currents was quasi‐permanent, and brecciation by wave–sediment interaction occurred only episodically. This indicates that, seawards of the attenuation zone, hydrodynamic storm wave base was deeper than mechanical storm wave base. Uppermost Jurassic carbonates were deposited and soft‐sediment deformed on a hurricane‐dominated ramp of very gentle slope and characterized by a zone of storm wave degeneration, located seawards of a zone of sedimentation below wave base.  相似文献   
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Most of the streams in the Mediterranean region are temporary, following predictable seasonal of flooding and drying, with a transition from lotic conditions to shallow lentic conditions. The goal of our study was to assess the nitrogen and phosphorus dynamics in channel-bed processes of temporary streams between floods. Results show that, during winter, temperatures ranged between 9.5 and 11.2 °C and oxygen concentration ranged from 8.0 to 9.5 mg L−1, whereas, during summer, temperatures varied between 21.2 and 26.8 °C and oxygen between 1.2 and 5.3 mg L−1, with oxygen depletion in the pools during the night. The nitrate concentrations were far more abundant during winter (February), while ammonium concentration increased after stream fragmentation into pools (especially in July when oxygen depletion conditions favoured ammonification). Results on sediment profiles showed that the most active sediment layers for NH4-N are the top 2–3 cm, corresponding to the sediment depositional sites of the stream. Phosphate concentrations had larger variability, yet concentrations decreased from winter to spring and increased again in summer, when the shallow water pools were formed. Sediment profiles at the sediment depositional sites showed that PO4-P was more dynamic in the first 6 cm.

In Mediterranean temporary streams, nutrient dynamics vary seasonally, as the system transits from lotic conditions to shallow lentic conditions, evidencing the regeneration of nutrients from organic and inorganic matter during the flow cessation period.  相似文献   

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Air temperature was monitored at 13 sites across the urban perimeter of a Brazilian midsize city in winter 2011. In this study, we show that the urban heat island (UHI) develops only at night and under certain weather conditions, and its intensity depends not only on the site's land cover but also on the meteorological setting. The urban heat island intensity was largest (6.6 °C) under lingering high-pressure conditions, milder (3.0 °C) under cold anticyclones and almost vanished (1.0 °C) during the passage of cold fronts. The cooling rates were calculated to monitor the growth and decay of the UHI over each specific synoptic setting. Over four contiguous days under the effect of a lingering high-pressure event, we observed that the onset of cooling was always at about 2 h before sunset. The reference site attained mean cooling rate of ?2.6 °C h?1 at sunset, whilst the maximum urban rate was ?1.2 °C h?1. Under a 3-day cold anticyclone episode, cooling also started about 2 h before sunset, and the difference between maximum rural (?2.0 °C h?1) and urban (?1.0 °C h?1) cooling rates diminished. Under cold-front conditions, the cooling rate was homogeneous for all sites and swang about zero throughout the day. The air temperature has a memory effect under lingering high-pressure conditions which intensified the UHI, in addition to the larger heat storage in the urban area. Cold anticyclone conditions promoted the development of the UHI; however, the cold air pool and relatively light winds smoothed out its intensity. Under the influence of cold fronts, the urban fabric had little effect on the city's air temperature field, and the UHI was imperceptible.  相似文献   
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The objective of the present study is to assess the influence of iron ore mining on Fe concentrations in fluvial sediments of the Gualaxo do Norte River basin (Minas Gerais State, Brazil). Initially background values were determined for Fe by means of the boxplot representation, the iterative 2σ technique and the calculated distribution function, using geochemical data obtained for alluvial terraces. Geochronologic analyses in carbonaceous materials attested for the proposed background values. After that, chemical analyses of active drainage sediments collected along the entire basin were carried out and a geochemical map of the study area was prepared. The mean background value for Fe is relatively high (8.2 wt %), when compared to the Fe concentration in the Earth’s crust (5.6 wt %). Such background value is strongly associated with the geological characteristics of the region. It was observed that most of the high Fe concentrations were detected in active sediments collected in the main river of the basin and not in its tributaries. This suggests that Fe enrichment is not only linked to the local geology but also to possible increase resulting from accidental leakage of iron ore mining tailings from containment dams and lakes upstream. It is suggested that measures that help stop or minimize such impact be adopted. The large capacity of Fe to adsorb and form complexes with toxic metals implicates in environmental hazards that may not be restricted only to the Gualaxo do Norte river basin, but may affect the other basins downstream.  相似文献   
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Inlet stabilization is a common practice in Brazil, as it is worldwide. In this paper we present results of the analysis of the stabilization practices of the Camacho Inlet, located in Santa Catarina State, southern Brazil. This inlet is maintained intermittently, in accordance with a regime designed to benefit both local fishermen and rice farmers. Fishermen require this inlet to be open as a navigation channel during the fishing season; rice farmers needs it closed during the irrigation period to allow the pumping of fresh water from the Congonhas River which drains into the Camacho’s backbarrier lagoon. An additional complication arises from the tendency of this inlet to close naturally due to infilling by dune migration. Aerial images spanning a 65 year time period (1938-2003) were analyzed, demonstrating the variability in the inlet’s width between 0 (closed) and 360 m. The analysis of inlet stability and user needs indicate that an appropriate solution is the implementation of an annual inlet dredging program in the austral autumn. This would allow for the inlet to remain open from May to September and then close naturally for the rest of the year, providing for a backbarrier fresh water reservoir during the irrigation period.  相似文献   
10.
Synthetic streamflow data is vital for the energy sector, as it feeds stochastic optimisation models that determine operational policies. Considered scenarios should differ from each other, but be the same from a statistical point of view, i.e., the scenarios must preserve features of the original time series such as the mean, variance, and temporal dependence structures. Traditionally, linear models are applied for this task. Recently, the advent of copulas has led to the emergence of an alternative that overcomes the drawbacks of linear models. In this context, we propose a methodology based on vine copulas for the stochastic simulation of periodic streamflow scenarios. Copula-based models that focus on single-site inflow simulation only consider lag-one time dependence. Therefore, we suggest an approach that incorporates lags that are greater than one. Furthermore, the proposed model deals with the strong periodicity that is commonly present in monthly streamflow time series. The resulting model is a non-linear periodic autoregressive model. Our results indicate that this model successfully simulates scenarios, preserving features that are observed in historical data.  相似文献   
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