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Six roches standards de I'USGS : GXR-1 à GXR-6 ont été analysées par activation neutronique instrumentale (INAA) pour le dosage de 17 éléments traces et par fluorescence X (XRF) pour les autres éléments difficiles à doser par activation neutronique. Les travaux précédemment publiés par Gladney et al. ont été pris comme référence en particulier les valeurs recommandées (R.V.) qui sont généralement en bon accord avec nos résultats. Quelques remarques et corrections sont proposées pour expliquer certaines disparités.
Six United States Geological Survey's (USGS) Geochemical Exploration References Samples (GXR) have been analyzed by instrumental neutron activation analysis (INAA) for the determination of seventeen trace elements and by X-ray fluorescence spectrometry (XRFS) for other trace elements difficult to determine by INAA. Our results compare favourably with the values recommended by E.S. Gladney et al. Some suggestions and corrections are proposed to explain some discrepancies.  相似文献   
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A major, but gradual, reversal in the cryptic variation patternof the plagioclase and pyroxenes, of 13 mol% anorthite and 10mol% Mg/ (Mg + Fe) respectively, is documented in the Main Zoneof the western Bush veld Complex. These changes are accompaniedby a decrease in initial 87Sr/86Sr ratio from > 0.708 to< 0.707. The Pyroxenite Marker, a distinctive orthopyroxenitelayer, occurs close to the top of this reversed differentiationsequence. This is attributed to addition of less differentiatedmagma. On the basis of a mass balance calculation of the initial87Sr/ 86Sr ratios, it is estimated that the volume of magmaadded was comparable to that of the resident magma. Increases in the Fe2O3, TiO2, Al2O3, and Na2O contents of thepyroxenes above the level of magma addition indicate that thenew magma had a lower silica activity and higher fO2 than theresident magma. Quantification of the trace element and REEcontent of the two magmas is hampered by the very low proportionof trapped intercumulus component in these adcumulate rocks.However, semi-quantitative modelling indicates that the traceand REE signatures of the two magmas were similar, with moderateLREE enrichment and flat HREE profiles. The new magma had aslightly higher La/ Sm ratio than the resident magma, consistentwith its more alkaline nature. The new magma was probably added gradually, while 100–150m of cumulates formed. It probably intruded at an intermediatelevel within an existing stratified magma chamber, where itcooled and crystallized, and composite packets of liquid pluscrystals plunged to the base of the chamber. The cores of plagioclasegrains formed during this mixing interval show a wider rangeof compositions than in other sections, and plagioclase primocrystsfrom both magmas may be preserved within single samples. Therefore,although intimate physical mixing of packets of unknown sizeof the two magmas occurred, re-equilibration of the major oxidecomposition of the plagioclase primocrysts was not achieved.However, the data and calculations based on diffusion ratesindicate that partial Sr isotopic resetting of plagioclase mayhave occurred.  相似文献   
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The dynamic inversion of reflection seismic data is investigated with reference to the influence of noise on pseudo-impedance logs. Model traces are calculated with 0, 5, 15 and 50% noise, respectively. In solving the inversion problem, the algorithm of Marquardt and Levenberg is used in connection with singular value decomposition (SVD). The results are within a 1% error range so that there was no visible change in the logs. Further signal analysis show that there is no dependence on the phase content of the wavelet used if all other parameters of the model are known.  相似文献   
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This paper is concerned with an interpretation of the Bouguer anomaly on the Western flank of the Brabant Massif (Belgium). The position, shape, and density contrast of elementary bodies in the upper part of the earth's crust are determined in a purely numerical manner. A batholith-like body and a basin-type structure both adequately account for the observed surface field, at least from a one-sided geophysical and mathematical point of view. Since seismological control is lacking the two models are representative of the ambiguity and indeterminacy of the definitions of the geologic cause of the anomalous features, if the data are restricted to gravity information alone.  相似文献   
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Palaeoenvironmental records from permafrost sequences complemented by infrared stimulated luminescence (IRSL) and [Formula: See Text]Th/U dates from Bol'shoy Lyakhovsky Island (73°20'N, 141°30'E) document the environmental history in the region for at least the past 200 ka. Pollen spectra and insect fauna indicate that relatively wet grass-sedge tundra habitats dominated during an interstadial c. 200-170 ka BP. Summers were rather warm and wet, while stable isotopes reflect severe winter conditions. The pollen spectra reflect sparser grass-sedge vegetation during a Taz (Late Saalian) stage, c. 170-130 ka BP, with environmental conditions much more severe compared with the previous interstadial. Open Poaceae and Artemisia plant associations dominated vegetation at the beginning of the Kazantsevo (Eemian) c. 130 ka BP. Some shrubs (Alnus fruticosa, Salix, Betula nana) grew in more protected and wetter places as well. The climate was relatively warm during this time, resulting in the melting of Saalian ice wedges. Later, during the interglacial optimum, shrub tundra with Alnus fruticosa and Betula nana s.l. dominated vegetation. Climate was relatively wet and warm. Quantitative pollen-based climate reconstruction suggests that mean July temperatures were 4-5°C higher than the present during the optimum of the Eemian, while late Eemian records indicate significant climate deterioration.  相似文献   
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Late Quaternary sediments in a permafrost environment recovered from the Elgygytgyn Impact Crater were studied to determine regional palaeoenvironmental variability and infer past water-level changes of the crater lake. Stratigraphic analysis of a 5 m long permafrost core is based on various lithological (grain size, total organic carbon, magnetic susceptibility) and hydrochemical (oxygen isotope composition, major cation content) properties and pore ice content. The results show that alluvial sediments accumulated on top of cryogenically weathered volcanic rock. Changes in the hydrochemical properties reflect different stages of cryogenic weathering. The lithological characteristics mark the transition from an erosive site to a site with accumulation. This environmental change is linked to a relative lake level highstand at >13 000 yr BP, when a shoreline bar was formed leading to slope sedimentation. Lake level dropped by 4 m during the Holocene.  相似文献   
8.
The Austurhorn intrusive complex in southeastern Iceland representsthe evolved hypabyssal remains of an eroded Tertiary (6–7Ma) central volcano. The complex consists of a layered gabbrointrusion, a composite granophyric stock, and abundant maficand felsic dikes. Mineralogical and geochemical trends amongcontemporaneous, compositionally diverse liquids from the complexprovide insight into the genesis of evolved basalts and rhyolitesin Iceland that are difficult to infer from studies of onlylavas. Mafic and felsic samples have comparable ranges in incompatibletrace element ratios (Ba/La and P/Ce) and Sr- and Pb-isotopes(O'Nions and Pankhurst, 1973; B. Hanan, pers. comm., 1988),suggesting derivation from a common parental composition. Majorand trace element variations throughout the Austurhorn suiteare consistent with fractional crystallization of the observedphenocrysts. Quartz-normative basalts were derived from parentalbasalt containing 7.8 wt.% MgO by extensive low-pressure crystallizationof olivine, augite, plagioclase, magnetite, and ilmenite. Thefractionating assemblage is consistent with the observed mineralogyof associated gabbro. Moreover, the cumulus mineralogy of thegabbro provides evidence for fractionation processes in a compositionalinterval not represented by dikes and sills (i.e., 54–63wt.% SiO2).Diversity among the mafic dikes reflects severaladditional factors: (1) crystallization under conditions ofvariable oxygen fugacity; (2) separate mantle melting eventsthat produce different Ce/Yb values; (3) contamination of somemafic dikes at depth, presumably by interaction with felsicmagmas. Major and trace element trends among most felsic samples canbe modeled by fractionation of the observed mineral phases:plagioclase, K-feldspar, clinopyroxene, ilmenite, apatite, allanite,and zircon. Although crustal melting has been proposed for generatingIcelandic rhyolites, most Austurhorn felsic samples are unlikeliquids derived by melting of hydrated basalts. In particular,apatite and zircon have controlled the abundances of Zr, Hf,and the REE in the felsic rocks, but they are unlikely to beresidual phases during partial melting of basalt. One felsicdike, interpreted as a melt of an evolved source, shows petrographicevidence of in situ anatexis and also has anomalous trace elementabundances and unusually high 206Pb/204Pb.  相似文献   
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ROBERT MEYER 《Sedimentology》1976,23(2):235-253
In the eastern Paris Basin, on the boundary of two French ‘départements’, Marne and Meuse, the Cretaceous deposits begin with Wealden facies assigned to the Valanginian. This is overlain by marine Hauterivian and Lower Barremian. Several techniques have been used for studying these deposits: light-microscope, scanning electron microscope, grain-size analysis, chemical and mineralogical analysis. Environmental interpretations of the various facies are based on sedimentological, geochemical and pedological criteria (fossil soils are present). Clay minerals are dominantly illite and kaolinite. In the soil horizons kaolinite is dominant. A mixed-layer illite-smectite appears at the base of the transgression. Under marine influence a more stable illite dominant suite is formed. The Wealden sediments appear to have been deposited in a very mature flood-plain. Part of the sequence was subjected to weathering in situ by soil processes under a warm climate with repeated wetting and drying. Paraconformably above, the marine Hauterivian is the product of a shallow sea that tended to form lagoons. A true marine environment was established in the Lower Barremian, when mixing homogenized the sediments.  相似文献   
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