Post-Collisional Transition from Subduction- to Intraplate-type Magmatism in the Westernmost Mediterranean: Evidence for Continental-Edge Delamination of Subcontinental Lithosphere   总被引：14，自引：0，他引：14  

DUGGEN  S.; HOERNLE  K.; VAN DEN BOGAARD  P.; GARBE-SCHONBERG  D. 《Journal of Petrology》2005,46(6):1155-1201

Post-collisional magmatism in the southern Iberian and northwesternAfrican continental margins contains important clues for theunderstanding of a possible causal connection between movementsin the Earth's upper mantle, the uplift of continental lithosphereand the origin of circum-Mediterranean igneous activity. Systematicgeochemical and geochronological studies (major and trace element,Sr–Nd–Pb-isotope analysis and laser ⁴⁰Ar/³⁹Ar-agedating) on igneous rocks provide constraints for understandingthe post-collisional history of the southern Iberian and northwesternAfrican continental margins. Two groups of magmatic rocks canbe distinguished: (1) an Upper Miocene to Lower Pliocene (8·2–4·8Ma), Si–K-rich group including high-K (calc-alkaline)and shoshonitic series rocks; (2) an Upper Miocene to Pleistocene(6·3–0·65 Ma), Si-poor, Na-rich group includingbasanites and alkali basalts to hawaiites and tephrites. Maficsamples from the Si–K-rich group generally show geochemicalaffinities with volcanic rocks from active subduction zones(e.g. Izu–Bonin and Aeolian island arcs), whereas maficsamples from the Si-poor, Na-rich group are geochemically similarto lavas found in intraplate volcanic settings derived fromsub-lithospheric mantle sources (e.g. Canary Islands). The transitionfrom Si-rich (subduction-related) to Si-poor (intraplate-type)magmatism between 6·3 Ma (first alkali basalt) and 4·8Ma (latest shoshonite) can be observed both on a regional scaleand in individual volcanic systems. Si–K-rich and Si-poorigneous rocks from the continental margins of southern Iberiaand northwestern Africa are, respectively, proposed to havebeen derived from metasomatized subcontinental lithosphere andsub-lithospheric mantle that was contaminated with plume material.A three-dimensional geodynamic model for the westernmost Mediterraneanis presented in which subduction of oceanic lithosphere is inferredto have caused continental-edge delamination of subcontinentallithosphere associated with upwelling of plume-contaminatedsub-lithospheric mantle and lithospheric uplift. This processmay operate worldwide in areas where subduction-related andintraplate-type magmatism are spatially and temporally associated. KEY WORDS: post-collisional magmatism; Mediterranean-style back-arc basins; subduction; delamination; uplift of marine gateways  相似文献   

Geochemistry of carbonate cements in the Sag River and Shublik Formations (Triassic/Jurassic), North Slope, Alaska: implications for the geochemical evolution of formation waters     

PETER S. MOZLEY  KAJ HOERNLE 《Sedimentology》1990,37(5):817-836

Carbonate cements (calcite, siderite, dolomite, and ankerite) formed throughout the diagenetic history of the Sag River and Shublik Formations. The trace element and isotopic geochemistry of these cements varies as a function of the timing of precipitation. Earliest calcites, formed prior to significant compaction of the sediment, are relatively enriched in Mg (up to 4·4 mol%), and have ⁸⁷Sr/⁸⁶Sr values (mean = 0·707898) compatible with the original marine pore waters. Later calcites are relatively Fe-rich (up to 5·0 mol%) and are characterized by increasing ⁸⁷Sr/⁸⁶Sr values (up to 0·712823) and Sr content with decreasing age. The Fe content of zoned siderite and dolomite/ankerite rhombs increases towards the outside of the rhombs (i.e. increasing Fe content with decreasing age). These geochemical variations appear principally to result from changes in pore-water chemistry during diagenesis. The increase in ⁸⁷Sr/⁸⁶ Sr and Sr content of the cements is most likely due to interaction between pore waters and ⁸⁷ Sr-rich clay and possibly feldspar in Ellesmerian mudrocks (whole rock ⁸⁷Sr/⁸⁶ Sr signatures for the mudrocks are > 0·716). Pore-water Fe²⁺ concentration was probably controlled by diagenetic alterations involving Fe-bearing minerals (e.g. pyrite precipitation). A reconnaissance examination of carbonate cements in the overlying Kingak Shale indicates that similar alterations occurred in the Kingak. The low δ¹⁸ O value of some calcite cements (-11·96% PDB) suggests that an influx of meteoric water may have occurred in the mid-Neocomian, though the low value could also result from an abnormally high geothermal gradient associated with mid-Neocomian rifting.  相似文献   

Combined Trace Element and Pb-Nd-Sr-O Isotope Evidence for Recycled Oceanic Crust (Upper and Lower) in the Iceland Mantle Plume   总被引：2，自引：0，他引：2  

KOKFELT  THOMAS FIND; HOERNLE  KAJ; HAUFF  FOLKMAR; FIEBIG  JENS; WERNER  REINHARD; GARBE-SCHONBERG  DIETER 《Journal of Petrology》2006,47(9):1705-1749

We present the results of a comprehensive major element, traceelement and Sr–Nd–Pb–O isotopic study of post-glacialvolcanic rocks from the Neovolcanic zones on Iceland. The rocksstudied range in composition from picrites and tholeiites, whichdominate in the main rift systems, to transitional and alkalicbasalts confined to the off-rift and propagating rift systems.There are good correlations of rock types with geochemical enrichmentparameters, such as La/Sm and La/Yb ratios, and with long-termradiogenic tracers, such as Sr–Nd–Pb isotope ratios,indicating a long-lived enrichment/depletion history of thesource region. ⁸⁷Sr/⁸⁶Sr vs ¹⁴³Nd/¹⁴⁴Nd defines a negative array.Pb isotopes define well-correlated positive arrays on both ²⁰⁶Pb/²⁰⁴Pbvs ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb diagrams, indicating mixing ofat least two major components: an enriched component representedby the alkali basalts and a depleted component represented bythe picrites. In combined Sr–Nd–Pb isotopic spacethe individual rift systems define coherent mixing arrays withslightly different compositions. The enriched component hasradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb > 19·3) and very similargeochemistry to HIMU-type ocean island basalts (OIB). We ascribethis endmember to recycling of hydrothermally altered upperbasaltic oceanic crust. The depleted component that is sampledby the picrites has unradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb < 17·8),but geochemical signatures distinct from that of normal mid-oceanridge basalt (N-MORB). Highly depleted tholeiites and picriteshave positive anomalies in mantle-normalized trace element diagramsfor Ba, Sr, and Eu (and in some cases also for K, Ti and P),negative anomalies for Hf and Zr, and low ¹⁸O_olivine values(4·6–5·0) below the normal mantle range.All of these features are internally correlated, and we, therefore,interpret them to reflect source characteristics and attributethem to recycled lower gabbroic oceanic crust. Regional compositionaldifferences exist for the depleted component. In SW Icelandit has distinctly higher Nb/U (68) and more radiogenic ²⁰⁶Pb/²⁰⁴Pbratios (18·28–18·88) compared with the NErift (Nb/U 47; ²⁰⁶Pb/²⁰⁴Pb = 18·07–18·47).These geochemical differences suggest that different packagesof recycled oceanic lithosphere exist beneath each rift. A thirdand minor component with relatively high ⁸⁷Sr/⁸⁶Sr and ²⁰⁷Pb/²⁰⁴Pbis found in a single volcano in SE Iceland (Öræfajökullvolcano), indicating the involvement of recycled sediments inthe source locally. The three plume components form an integralpart of ancient recycled oceanic lithosphere. The slope in theuranogenic Pb diagram indicates a recycling age of about 1·5Ga with time-integrated Th/U ratios of 3·01. Surprisingly,there is little evidence for the involvement of North AtlanticN-MORB source mantle, as would be expected from the interactionof the Iceland plume and the surrounding asthenosphere in formof plume–ridge interaction. The preferential samplingof the enriched and depleted components in the off-rift andmain rift systems, respectively, can be explained by differencesin the geometry of the melting regions. In the off-rift areas,melting columns are truncated deeper and thus are shorter, whichleads to preferential melting of the enriched component, asthis starts melting deeper than the depleted component. In contrast,melting proceeds to shallower depths beneath the main rifts.The longer melting columns also produce significant amountsof melt from the more refractory (lower crustal/lithospheric)component. KEY WORDS: basalts; trace element and Sr, Nd, Pb, O isotope geochemistry; Iceland plume; isotope ratios; oceanic crustal recycling; partial melting; plume–ridge interaction  相似文献   

The Cocos and Carnegie Aseismic Ridges: a Trace Element Record of Long-term Plume-Spreading Center Interaction   总被引：4，自引：0，他引：4  

HARPP  KAREN S.; WANLESS  VIRGINIA D.; OTTO  ROBERT H.; HOERNLE  KAJ; WERNER  REINHARD 《Journal of Petrology》2005,46(1):109-133

The aseismic Cocos and Carnegie Ridges, two prominent bathymetricfeatures in the eastern Pacific, record 20 Myr of interactionbetween the Galápagos hotspot and the adjacent GalápagosSpreading Center. Trace element data determined by inductivelycoupled plasma-mass spectrometry in >90 dredged seamountlavas are used to estimate melt generation conditions and mantlesource compositions along the ridges. Lavas from seamount provinceson the Cocos Ridge are alkalic and more enriched in incompatibletrace elements than any in the Galápagos archipelagotoday. The seamount lavas are effectively modeled as small degreemelts of a Galápagos plume source. Their eruption immediatelyfollows the failure of a rift zone at each seamount province'slocation. Thus the anomalously young alkalic lavas of the CocosRidge, including Cocos Island, are probably caused by post-abandonmentvolcanism following either a ridge jump or rift failure, andnot the direct activity of the Galápagos plume. The seamountshave plume-like signatures because they tap underlying mantlepreviously infused with Galápagos plume material. Whereasplume heterogeneities appear to be long-lived, tectonic rearrangementsof the ridge plate boundary may be the dominant factor in controllingregional eruptive behavior and compositional variations. KEY WORDS: mantle plume; mid-ocean ridge; Galápagos; abandoned rift; partial melting of the mantle  相似文献   

The Role of Partial Melting in the 15-Ma Geochemical Evolution of Gran Canaria: A Blob Model for the Canary Hotspot   总被引：5，自引：4，他引：5  

HOERNLE  KAJ; SCHMINCKE  HANS-ULRICH 《Journal of Petrology》1993,34(3):599-626

The subaerial portion of Gran Canaria, Canary Islands, was builtby three cycles of volcanism: a Miocene Cycle (8•5–15Ma), a Pliocene Cycle (1•8–6•0 Ma), and a QuaternaryCycle (1•8–0 Ma). Only the Pliocene Cycle is completelyexposed on Gran Canaria; the early stages of the Miocene Cycleare submarine and the Quaternary Cycle is still in its initialstages. During the Miocene, SiO₂ saturation of the mafic volcanicsdecreased systematically from tholeiite to nephelinite. Forthe Pliocene Cycle, SiO₂ saturation increased and then decreasedwith decreasing age from nephelinite to tholeiite to nephelinite.SiO₂ saturation increased from nephelinite to basanite and alkalibasalt during the Quaternary. In each of these cycles, increasingmelt production rates, SiO₂ saturation, and concentrations ofcompatible elements, and decreasing concentrations of some incompatibleelements are consistent with increasing degrees of partial meltingin the sequence melilite nephelinite to tholeiite. The maficvolcanics from all three cycles were derived from CO₂-rich garnetlherzolite sources. Phlogopite, ilmenite, sulfide, and a phasewith high partition coefficients for the light rare earth elements(LREE), U, Th, Pb, Nb, and Zr, possibly zircon, were residualduring melting to form the Miocene nephelinites through tholeiites;phlogopite, ilmenite, and sulfide were residual in the sourceof the Pliocene–Quaternary nephelinites through alkalibasalts. Highly incompatible element ratios (e.g., Nb/U, Pb/Ce,K/U, Nb/Pb, Ba/Rb, Zr/Hf, La/Nb, Ba/Th, Rb/Nb, K/Nb, Zr/Nb,Th/Nb, Th/La, and Ba/La) exhibit extreme variations (in manycases larger than those reported for all other ocean islandbasalts), but these ratios correlate well with degree of melting.Survival of residual phases at higher degrees of melting duringthe Miocene Cycle and differences between major and trace elementconcentrations and melt production rates between the Mioceneand Pliocene tholeiites suggest that the Miocene source wasmore fertile than the Pliocene–Quaternary source(s). We propose a blob model to explain the multi-cycle evolutionof Canary volcanoes and the temporal variations in chemistryand melt production within cycles. Each cycle of volcanism representsdecompression melting of a discrete blob of plume material.Small-degree nephelinitic and basanitic melts are derived fromthe cooler margins of the blobs, whereas the larger-degree tholeiiticand alkali basaltic melts are derived from the hotter centersof the blobs. The symmetrical sequence of mafic volcanism fora cycle, from highly undersaturated to saturated to highly undersaturatedcompositions, reflects melting of the blob during its ascentbeneath an island in the sequence upper margin-corelower margin.Volcanic hiatuses between cycles and within cycles representperiods when residual blob or cooler entrained shallow mantlematerial fill the melting zone beneath an island.  相似文献   

The Petrology of the Tholeiites through Melilite Nephelinites on Gran Canaria, Canary Islands: Crystal Fractionation, Accumulation, and Depths of Melting   总被引：2，自引：5，他引：2  

HOERNLE  KAJ; SCHMINCKE  HANS-ULRICH 《Journal of Petrology》1993,34(3):573-597

We report major and trace element X-ray fluorescence (XRF) datafor mafic volcanics covering the 15-Ma evolution of Gran Canaria,Canary Islands. The Miocene (12–15 Ma) and Pliocene-Quaternary(0–6 Ma) mafic volcanics on Gran Canaria include picrites,tholeiites, alkali basalts, basanites, nephelinites, and melilitenephelinites. Olivineclinopyroxene are the major fractionatingor accumulating phases in the basalts. Plagioclase, Fe–Tioxide, and apatite fractionation or accumulation may play aminor role in the derivation of the most evolved mafic volcanics.The crystallization of clinopyroxene after olivine and the absenceof phenocrystic plagioclase in the Miocene tholeiites and inthe Pliocene and Quaternary alkali basalts and basanites withMgO>6 suggests that fractionation occurred at moderate pressure,probably within the upper mantle. The presence of plagioclasephenocrysts and chemical evidence for plagioclase fractionationin the Miocene basalts with MgO<6 and in the Pliocene tholeiitesis consistent with cooling and fractionation at shallow depth,probably during storage in lower-crustal reservoirs. Magma generationat pressures in excess of 3•0–3•5 GPa is suggestedby (a) the inferred presence of residual garnet and phlogopiteand (b) comparison of FeO¹ cation mole percentages and the CIPWnormative compositions of the mafic volcanics with results fromhigh-pressure melting experiments. The Gran Canaria mafic magmaswere probably formed by decompression melting in an upwellingcolumn of asthenospheric material, which encountered a mechanicalboundary layer at {small tilde}100-km depth.  相似文献