排序方式： 共有13条查询结果，搜索用时 78 毫秒
1.
The Kuroko deposits of NE Honshu are a key type deposit for the study of volcanogenic massive sulfide deposits. However, these deposits have not been studied in detail since the early 1980's and knowledge of their mode of formation is now dated. In this study, we present the analysis of 12 samples of the Kuroko deposits, 12 samples of submarine hydrothermal minerals from the Sunrise deposit and 6 samples from Suiyo Seamount, both of which are located on the Izu-Ogasawara (Bonin) Arc, for 27 elements. For the Kuroko deposit, Cd>Sb>Ag>Pb>Hg>As>Zn>Cu are highly enriched, Au>Te>Bi>Ba>Mo are moderately enriched, In>Tl are somewhat enriched and Fe is not significantly enriched relative to the average continental crust. Within each of these deposits, a similar pattern of element associations is apparent: Zn–Pb with As, Sb, Cd, Ag, Hg, Tl and Au; Fe–Cu–Ba with As, Sb, Ag, Tl, Mo, Te and Au; Si–Ba with Ag and Au; CaSO4. The enrichment of the chalcophilic elements in these deposits is consistent with hydrothermal leaching of these elements from the host rocks which are dominantly rhyolite–dacite in the case of the Kuroko deposits, rhyolite in the case of the Sunrise deposit and dacite–rhyolite in the case of the Suiyo Seamount deposit. However, this pattern of element enrichment is also similar to that observed in fumarolic gas condensates from andesitic volcanoes. This suggests that there may be a significant magmatic contribution to the composition of the hydrothermal fluids responsible for the formation of the Kuroko deposits, although it is not yet possible to quantify the relative contributions of these two sources of elements.The compositional data show that Sunrise and Suiyo Seamount deposits are much closer compositionally to the Kuroko deposits from NE Honshu than are the submarine hydrothermal deposits from the JADE site in the Okinawa Trough which contain, on average, significantly higher concentrations of Pb, Zn, Sb, As and Ag than each of these deposits. In spite of the greater similarity in tectonic setting of the Hokuroku Basin in which the Kuroko deposits formed to the Okinawa Trough (intracontinental rifted back-arc basin) compared to Myojin Knoll and Suiyo Seamount (active arc volcanoes), it appears that submarine hydrothermal deposits from Myojin Knoll and Suiyo Seamount are closer analogues of the Kuroko deposit than are those from the Okinawa Trough. The present data are consistent with the magmatic hydrothermal model for the formation of Kuroko-type deposits as formulated by Urabe and Marumo [Urabe, T., Marumo, K., 1991. A new model for Kuroko-type deposits of Japan. Episodes 14, 246–251]. 相似文献
2.
Sven Petersen Peter M. Herzig Thomas Kuhn Leander Franz Mark D. Hannington Thomas Monecke 《Marine Georesources & Geotechnology》2013,31(3):175-193
ABSTRACT From September to October 2002, shallow drilling, using the submersible (5 m) Rockdrill of the British Geological Survey and the German R/V Sonne revealed critical information on the subsurface nature of two distinct hydrothermal systems in the New Ireland fore-arc and the Manus Basin of Papua New Guinea. Drilling at Conical Seamount significantly extends the known surface extent of the previously discovered vein-style gold mineralization (up to 230 g/t Au) at this site. Drilling the conventional PACMANUS volcanic-hosted massive sulfide deposit recovered complexly textured massive sulfide with spectacular concentrations of gold in several core sections including 0.5 m @ 28 g/t Au, 0.35 m @ 30 g/t Au, and 0.20 m @ 57 g/t Au. Shallow drilling is a fast and cost efficient method that bridges the gap between surface sampling and deep (ODP) drilling and will become a standard practice in the future study of seafloor hydrothermal systems and massive sulfide deposits. 相似文献
3.
Patrick Mercier-Langevin Mark D. Hannington Beno?t Dub�� Val��rie B��cu 《Mineralium Deposita》2011,46(5-6):509-539
Volcanogenic massive sulfide deposits contain variable amounts of gold, both in terms of average grade and total gold content, with some VMS deposits hosting world-class gold mines with more than 100?t Au. Previous studies have identified gold-rich VMS as having an average gold grade, expressed in g/t, exceeding the total abundance of base metals, expressed in wt.%. However, statistically meaningful criteria for the identification of truly anomalous deposits have not been established. This paper presents a more extensive analysis of gold grades and tonnages of 513 VMS deposits worldwide, revealing a number of important features in the distribution of the data. A large proportion of deposits are characterized by a relatively low gold grade (<2?g/t), with a gradual decrease in frequency towards maximum gold grades, defining a log-normal distribution. In the analysis presented in this paper, the geometric mean and geometric standard deviation appear to be the simplest metric for identifying subclasses of VMS deposits based on gold grade, especially when comparing deposits within individual belts and districts. The geometric mean gold grade of 513 VMS deposits worldwide is 0.76?g/t; the geometric standard deviation is +2.70?g/t Au. In this analysis, deposits with more than 3.46?g/t Au (geometric mean plus one geometric standard deviation) are considered auriferous. The geometric mean gold content is 4.7?t Au, with a geometric standard deviation of +26.3?t Au. Deposits containing 31?t Au or more (geometric mean plus one geometric standard deviation) are also considered to be anomalous in terms of gold content, irrespective of the gold grade. Deposits with more than 3.46?g/t Au and 31?t Au are considered gold-rich VMS. A large proportion of the total gold hosted in VMS worldwide is found in a relatively small number of such deposits. The identification of these truly anomalous systems helps shed light on the geological parameters that control unusual enrichment of gold in VMS. At the district scale, the gold-rich deposits occupy a stratigraphic position and volcanic setting that commonly differs from other deposits of the district possibly due to a step change in the geodynamic and magmatic evolution of local volcanic complexes. The gold-rich VMS are commonly associated with transitional to calc-alkaline intermediate to felsic volcanic rocks, which may reflect a particularly fertile geodynamic setting and/or timing (e.g., early arc rifting or rifting front). At the deposit scale, uncommon alteration assemblages (e.g., advanced argillic, aluminous, strongly siliceous, or potassium feldspar alteration) and trace element signatures may be recognized (e.g., Au?CAg?CAs?CSb ± Bi?CHg?CTe), suggesting a direct magmatic input in some systems. 相似文献
4.
Cornel E. J. de Ronde Gary J. Massoth David A. Butterfield Bruce W. Christenson Junichiro Ishibashi Robert G. Ditchburn Mark D. Hannington Robert L. Brathwaite John E. Lupton Vadim S. Kamenetsky Ian J. Graham Georg F. Zellmer Robert P. Dziak Robert W. Embley Vesselin M. Dekov Frank Munnik Janine Lahr Leigh J. Evans Ken Takai 《Mineralium Deposita》2011,46(5-6):541-584
Brothers volcano, of the Kermadec intraoceanic arc, is host to a hydrothermal system unique among seafloor hydrothermal systems known anywhere in the world. It has two distinct vent fields, known as the NW Caldera and Cone sites, whose geology, permeability, vent fluid compositions, mineralogy, and ore-forming conditions are in stark contrast to each other. The NW Caldera site strikes for ??600?m in a SW?CNE direction with chimneys occurring over a ??145-m depth interval, between ??1,690 and 1,545?m. At least 100 dead and active sulfide chimney spires occur in this field and are typically 2?C3?m in height, with some reaching 6?C7?m. Their ages (at time of sampling) fall broadly into three groups: <4, 23, and 35?years old. The chimneys typically occur near the base of individual fault-controlled benches on the caldera wall, striking in lines orthogonal to the slopes. Rarer are massive sulfide crusts 2?C3?m thick. Two main types of chimney predominate: Cu-rich (up to 28.5?wt.% Cu) and, more commonly, Zn-rich (up to 43.8?wt.% Zn). Geochemical results show that Mo, Bi, Co, Se, Sn, and Au (up to 91?ppm) are correlated with the Cu mineralization, whereas Cd, Hg, Sb, Ag, and As are associated with the dominant Zn-rich mineralization. The Cone site comprises the Upper Cone site atop the summit of the recent (main) dacite cone and the Lower Cone site that straddles the summit of an older, smaller, more degraded dacite cone on the NE flank of the main cone. Huge volumes of diffuse venting are seen at the Lower Cone site, in contrast to venting at both the Upper Cone and NW Caldera sites. Individual vents are marked by low-relief (??0.5?m) mounds comprising predominately native sulfur with bacterial mats. Vent fluids of the NW Caldera field are focused, hot (??300°C), acidic (pH????2.8), metal-rich, and gas-poor. Calculated end-member fluids from NW Caldera vents indicate that phase separation has occurred, with Cl values ranging from 93% to 137% of seawater values. By contrast, vent fluids at the Cone site are diffuse, noticeably cooler (??122°C), more acidic (pH?1.9), metal-poor, and gas-rich. Higher-than-seawater values of SO4 and Mg in the Cone vent fluids show that these ions are being added to the hydrothermal fluid and are not being depleted via normal water/rock interactions. Iron oxide crusts 3?years in age cover the main cone summit and appear to have formed from Fe-rich brines. Evidence for magmatic contributions to the hydrothermal system at Brothers includes: high concentrations of dissolved CO2 (e.g., 206?mM/kg at the Cone site); high CO2/3He; negative ??D and ??18OH2O for vent fluids; negative ??34S for sulfides (to ?4.6??), sulfur (to ?10.2??), and ??15N2 (to ?3.5??); vent fluid pH values to 1.9; and mineral assemblages common to high-sulfidation systems. Changing physicochemical conditions at the Brothers hydrothermal system, and especially the Cone site, occur over periods of months to hundreds of years, as shown by interlayered Cu?+?Au- and Zn-rich zones in chimneys, variable fluid and isotopic compositions, similar shifts in 3He/4He values for both Cone and NW Caldera sites, and overprinting of ??magmatic?? mineral assemblages by water/rock-dominated assemblages. Metals, especially Cu and possibly Au, may be entering the hydrothermal system via the dissolution of metal-rich glasses. They are then transported rapidly up into the system via magmatic volatiles utilizing vertical (??2.5?km long), narrow (??300-m diameter) ??pipes,?? consistent with evidence of vent fluids forming at relatively shallow depths. The NW Caldera and Cone sites are considered to represent stages along a continuum between water/rock- and magmatic/hydrothermal-dominated end-members. 相似文献
5.
6.
The sulfur isotopic composition of sulfides and barite from hydrothermal deposits at the Valu Fa Ridge back-arc spreading
center in the southern Lau Basin has been investigated. Sulfide samples from the White Church area at the northern Valu Fa
Ridge have δ34S values averaging +3.8‰ (n= 10) for bulk sphalerite-chalcopyrite mineralization and +4.8‰ for pyrite (n= 10). Barite associated with the massive sulfides exhibits an average of +20.7‰ (n= 10). Massive sulfides from the active Vai Lili hydrothermal field at the central Valu Fa Ridge have much higher δ34S ratios averaging +8.0‰ for bulk sphalerite-chalcopyrite mineralization (n= 5), +9.3‰ for pyrite samples (n= 5), and +8.0‰ and +10.9‰ for a chalcopyrite and a sphalerite separate, respectively. The isotopic composition of barite
from the Vai Lili field is similar to that of barite from the White Church area and averages +21.0‰ (n= 8). Sulfide and barite samples from the Hine Hina area at the southern Valu Fa Ridge have δ34S values that are considerably lighter than those observed for samples from the other areas and average −4.9‰ for pyrite (n= 9), −4.0 and −5.7‰ for two samples of sphalerite-chalcopyrite intergrowth, and −3.4‰ for a single chalcopyrite separate.
The total spread in the isotopic composition of sulfides from Vai Lili and Hine Hina is more than 20‰ over a distance of less
than 30 km. The δ34S values of sulfides at Hine Hina are the lowest values so far reported for volcanic-hosted polymetallic massive sulfides
from the modern seafloor. Barite from the Hine Hina field also has unusually light sulfur with δ34S values of +16.1 to +16.7‰ (n= 5). Isotopic compositions of the sulfides at Hine Hina indicate a dramatic decrease in δ34S from ordinary magmatic values and, in the absence of biogenic sulfur and/or boiling, imply a unique 34S-depleted source of probable magmatic origin. Sulfide-barite mineralization in the Hine Hina area is associated with a distinctive
alteration assemblage consisting of cristobalite, pyrophyllite, kaolinite, opal-CT, talc, pyrite, native sulfur, and alunite.
Similar styles of alteration are typically known from high-sulfidation epithermal systems on land. Alunite-bearing, advanced
argillic alteration in the Hine Hina field confirms the role of acidic, volatile-rich fluids, and a δ34S value of +10.4‰ for the sulfur in the alunite is consistent with established kinetic isotope effects which accompany the
disproportionation of magmatic SO2 into H2S and H2SO4. The Hine Hina field occurs near the propagating tip of the Valu Fa back-arc spreading center (i.e., dominated by dike injections
and seafloor eruptions) and therefore may have experienced the largest contribution of magmatic volatiles of the three fields.
The sulfur isotopic ratios of the hydrothermal precipitates and the presence of a distinctive epithermal-like argillic alteration
in the Hine Hina field suggest a direct contribution of magmatic vapor to the hydrothermal system and support the concept
that magmatic volatiles may be an important component of some volcanogenic massive sulfide-forming hydrothermal systems.
Received: 16 January 1997 / Accepted: 28 October 1997 相似文献
7.
Hannington Mark D. Kjarsgaard Ingrid M. Galley Alan G. Taylor Bruce 《Mineralium Deposita》2003,38(4):423-442
Mineralium Deposita - The massive sulfide deposits of the Kristineberg area, Sweden, occur within a 2- to 3-km-thick succession of felsic volcaniclastic rocks belonging to the Skellefte Group. The... 相似文献
8.
Thomas Monecke Sven Petersen Mark D. Hannington Marco Anzidei Alessandra Esposito Guido Giordano Dieter Garbe-Sch?nberg Nico Augustin Bernd Melchert Mike Hocking 《Bulletin of Volcanology》2012,74(9):1937-1944
Explosions of hot water, steam, and gas are common periodic events of subaerial geothermal systems. These highly destructive events may cause loss of life and substantial damage to infrastructure, especially in densely populated areas and where geothermal systems are actively exploited for energy. We report on the occurrence of a large number of explosion craters associated with the offshore venting of gas and thermal waters at the volcanic island of Panarea, Italy, demonstrating that violent explosions similar to those observed on land also are common in the shallow submarine environment. With diameters ranging from 5 to over 100?m, the observed circular seafloor depressions record a history of major gas explosions caused by frequent perturbation of the submarine geothermal system over the past 10,000?years. Estimates of the total gas flux indicate that the Panarea geothermal system released over 70?Mt of CO2 over this period of time, suggesting that CO2 venting at submerged arc volcanoes contributes significantly to the global atmospheric budget of this greenhouse gas. The findings at Panarea highlight that shallow submarine gas explosions represent a previously unrecognized volcanic hazard around populated volcanic islands that needs to be taken into account in the development of risk management strategies. 相似文献
9.
D. Müller L. Franz S. Petersen P. M. Herzig M. D. Hannington 《Mineralogy and Petrology》2003,79(3-4):259-283
Summary Grab samples from the submarine Conical Seamount, located about 10km south of the giant Ladolam gold deposit, Lihir Island, reveal the highest gold concentrations yet reported from the modern seafloor. Lavas from Conical Seamount are characterized by high K2O contents, high K2O/Na2O ratios, and high Ce/Yb ratios, which are typical of high-K igneous rocks from oceanic (island) arc-settings. The primitive character of the rocks from Conical Seamount implies a magmatic evolution related to a single eruptive phase, which contrasts with the more evolved rocks forming Lihir Island. Geochemical as well as mineral chemical data suggest that the melts from both Conical Seamount and Lihir Island originate from the same magma source. In common with the samples from Lihir Island, elevated oxygen fugacities of 0.7–2.5log units above the FMQ buffer are recorded from the Conical Seamount lavas.There are distinct differences between the mineralization styles at Conical Seamount and at the Ladolam gold deposit, Lihir Island. While early-stage pyritic stockwork mineralization at Conical Seamount is hosted by clay-silica altered basaltic rocks with local alunite±kaolinite alteration, main-stage Au-mineralization occurs in sericite-alkali feldspar altered polymetallic sulfide-bearing siliceous veins. By contrast, early-stage pyritic stockwork mineralization at Ladolam is restricted to biotite–magnetite ± silica-altered monzodiorite, while the main-stage bulk-tonnage mineralization occurs as auriferous pyrite-bearing hydrothermal breccias which, in places, are cut by quartz–chalcedony–illite–adularia–pyrite±marcasite veins containing isolated bonanza gold grades. 相似文献
10.
Giovanni Spagnoli Mark Hannington Katharina Bairlein Andreas Hördt Marion Jegen Sven Petersen Tea Laurila 《Geo-Marine Letters》2016,36(3):235-245
Seafloor massive sulfide (SMS) deposits are increasingly seen as important marine metal resources for the future. A growing number of industrialized nations are involved in the surveying and sampling of such deposits by drilling. Drill ships are expensive and their availability can be limited; seabed drill rigs are a cost-effective alternative and more suitable for obtaining cores for resource evaluation. In order to achieve the objectives of resource evaluations, details are required of the geological, mineralogical, and physical properties of the polymetallic deposits and their host rocks. Electrical properties of the deposits and their ore minerals are distinct from their unmineralized host rocks. Therefore, the use of electrical methods to detect SMS while drilling and recovering drill cores could decrease the costs and accelerate offshore operations by limiting the amount of drilling in unmineralized material. This paper presents new data regarding the electrical properties of SMS cores that can be used in that assessment. Frequency-dependent complex electrical resistivity in the frequency range between 0.002 and 100 Hz was examined in order to potentially discriminate between different types of fresh rocks, alteration and mineralization. Forty mini-cores of SMS and unmineralized host rocks were tested in the laboratory, originating from different tectonic settings such as the intermediate-spreading ridges of the Galapagos and Axial Seamount, and the Pacmanus back-arc basin. The results indicate that there is a clear potential to distinguish between mineralized and non-mineralized samples, with some evidence that even different types of mineralization can be discriminated. This could be achieved using resistivity magnitude alone with appropriate rig-mounted electrical sensors. Exploiting the frequency-dependent behavior of resistivity might amplify the differences and further improve the rock characterization. 相似文献