Thermodynamic and kinetic control on anaerobic oxidation of methane in marine sediments     

Nina J. Knab  Andrew W. Dale  Henrik Fossing 《Geochimica et cosmochimica acta》2008,72(15):3746-3757

The free energy yield of microbial respiration reactions in anaerobic marine sediments must be sufficient to be conserved as biologically usable energy in the form of ATP. Anaerobic oxidation of methane (AOM) coupled to sulfate reduction (SRR) has a very low standard free energy yield of ΔG^° = −33 kJ mol⁻¹, but the in situ energy yield strongly depends on the concentrations of substrates and products in the pore water of the sediment. In this work ΔG for the AOM-SRR process was calculated from the pore water concentrations of methane, sulfate, sulfide, and dissolved inorganic carbon (DIC) in sediment cores from different sites of the European continental margin in order to determine the influence of thermodynamic regulation on the activity and distribution of microorganisms mediating AOM-SRR. In the zone of methane and sulfate coexistence, the methane-sulfate transition zone (SMTZ), the energy yield was rarely less than −20 kJ mol⁻¹ and was mostly rather constant throughout this zone. The kinetic drive was highest at the lower part of the SMTZ, matching the occurrence of maximum AOM rates. The results show that the location of maximum AOM rates is determined by a combination of thermodynamic and kinetic drive, whereas the rate activity mainly depends on kinetic regulation.  相似文献   

Methane emission measurements in urban areas in Eastern Germany     

Joanne H. Shorter  J. Barry Mcmanus  Charles E. Kolb  Eugene J. Allwine  Brian K. Lamb  Byard W. Mosher  Robert C. Harriss  Uwe Partchatka  Horst Fischer  Geoffrey W. Harris  Paul J. Crutzen  Hans-Josef Karbach 《Journal of Atmospheric Chemistry》1996,24(2):121-140

We have investigated methane emissions from urban sources in the former East Germany using innovative measurement techniques including a mobile real-time methane instrument and tracer release experiments. Anthropogenic and biogenic sources were studied with the emphasis on methane emissions from gas system sources, including urban distribution facilities and a production plant. Methane fluxes from pressure regulating stations ranged from 0.006 to 24. l/min. Emissions from diffuse sources in urban areas were also measured with concentration maps and whole city flux experiments. The area fluxes of the two towns studied were 0.37 and 1.9 g/m²/s. The emissions from individual gas system stations and total town emissions of this study are comparable to results of similar sites examined in the United States.  相似文献   

Low-field magnetic susceptibility: a proxy method of estimating increased pollution of different environmental systems   总被引：18，自引：0，他引：18  

E. Petrovský  A. Kapička  N. Jordanova  M. Knab  V. Hoffmann 《Environmental Geology》2000,39(3-4):312-318

 A need for rapid and inexpensive (proxy) methods of outlining areas exposed to increased pollution by atmospheric particulates of industrial origin caused scientists in various fields to use and validate different non-traditional (or non-chemical) techniques. Among them, soil magnetometry seems to be a suitable tool, at least in some cases. This method is based on the knowledge that ferrimagnetic particles, namely magnetite, are produced from pyrite during combustion of fossil fuel. Besides the combustion processes, magnetic particles can also originate from road traffic, for example, or can be included in various waste-water outlets. Magnetite, Fe₃O₄, ranks among the main ferrimagnetic minerals and its identification in various ecosystems can contribute to fast and simple outlining of areas and sites exposed to higher pollution impact. Here the method of magnetic mapping of anthropogenic pollution will be introduced using a review of our recent case studies on different ecosystems in the Czech Republic and Germany. Received: 20 June 1998 · Accepted: 9 November 1998  相似文献   

Anaerobic oxidation of methane (AOM) in marine sediments from the Skagerrak (Denmark): I. Geochemical and microbiological analyses     

Nina J. Knab  Barry A. Cragg  R. John Parkes  Bo B. Jørgensen 《Geochimica et cosmochimica acta》2008,72(12):2868-2879

The organic rich sediments of the Skagerrak contain high quantities of shallow gas of mostly biogenic origin that is transported to the sediment surface by diffusion. The sulfate methane transition zone (SMTZ), where anaerobic oxidation of methane (AOM) and sulfate reduction occur, functions as a methane barrier for this upward diffusing methane.To investigate the regulation of AOM and sulfate reduction rates (SRR) and the controls on the efficiency of methane consumption, pore water concentrations, and microbial rates of AOM, sulfate reduction and methanogenesis were determined in three gravity cores collected along the slope of the Norwegian Trench in the Skagerrak. SRR occurred in two distinct peaks, at the sediment surface and the SMTZ, the latter often exceeding the peak AOM rates that occurred at the bottom of the SMTZ. Highest rates of both AOM and SRR were observed in a core from a pockmark, where advective methane transport occurred, generating high methane and sulfate fluxes. But even at this site with a shallow SMTZ, the entire flux of methane was oxidized below the sediment surface. AOM, SRR and methanogenesis seem to be closely associated and strongly regulated by sulfate concentrations, which were, in turn, regulated by the methane flux. Rate measurements of SRR, AOM and methanogenesis revealed a tight coupling of these processes. Bicarbonate-based methanogenesis occurred at moderate sulfate concentrations (>5 mM) above the AOM zone but seemed to be inhibited in the depth where AOM occurred. The unbalanced stoichiometry of AOM and SRR in the SMTZ was more pronounced in rate measurements than in methane and sulfate fluxes, and seemed more likely be related to enhanced SRR in this zone than an underestimation of methane fluxes.  相似文献   

The distribution of trace elements in carbonaceous chondrites     

Hans-Josef Knab 《Geochimica et cosmochimica acta》1981,45(9):1563-1572

12 carbonaceous chondrites, amongst them representatives of nearly all known petrologic types were analyzed for twenty trace elements by spark source mass spectrography combined with the isotope dilution method. Data on different element groups (refractory, moderately volatile and volatile) show that the distribution of the trace elements in the carbonaceous chondrites, with the exception of Renazzo, can be well explained by Anders' two-component model. This is also valid for the highly metamorphosed CV5 chondrite Karoonda.Furthermore, it is observed that the $\text{Zr}\text{Hf}$-ratios in the carbonaceous chondrites increase with increasing petrologic type which is interpreted as the result of mixing two components with different $\text{Zr}\text{Hf}$-ratios  相似文献   

Parameterizations of cloud feedback in a radiative-convective model     

Hans-Josef Jung  Wilfrid Bach 《Pure and Applied Geophysics》1985,123(4):610-623

The effect of cloud feedback on the response of a radiative-convective model to a change in cloud model parameters, atmospheric CO₂ concentration, and solar constant has been studied using two different parameterization schemes. The method for simulating the vertical distribution of both cloud cover and cloud optical thickness, which depends on the relative humidity and on the saturation mixing ratio of water vapor, respectively, is the same in both approaches, but the schemes differ with respect to modeling the water vapor profile. In scheme I atmospheric water vapor is coupled to surface parameters, while in scheme II an explicit balance equation for water vapor in the individual atmospheric layers is used. For both models the combined effect of feedbacks due to variations in lapse rate, cloud cover, and cloud optical thickness results in different relationships between changes in surface temperature, planetary temperature, and cloud cover. Specifically, for a CO₂ doubling and a 2% increase in solar constant, in both models the surface warming is reduced by cloud feedback, in contrast to no feedback, with the greater reduction in scheme I as compared to that of scheme II.  相似文献   

Surveying the anthropogenic impact of the Moldau river sediments and nearby soils using magnetic susceptibility     

M. Knab  V. Hoffmann  E. Petrovský  A. Kapička  N. Jordanova  E. Appel 《Environmental Geology》2006,49(4):527-535

Measuring magnetic susceptibility is a method which is used to estimate the amount of magnetic particles in soils, sediments or dusts. Changes in magnetic susceptibility can be due to various reasons: input from different sources of sediments, e.g. from different soils or rocks, atmospheric fallout of anthropogenic dusts containing magnetic particles produced by fossil fuel combustion, steel production or road traffic. In the case of river sediments, input from the catchment is of primary significance. The main aim of this investigation was to test the potential of magnetic susceptibility screening in identifying the effect and significance of anthropogenic activities in an area with complex geological conditions. We investigated the magnetic susceptibility of riverbed sediments of the largest river of the Czech Republic, the Moldau river. Besides that, the magnetic signal of nearby topsoils as well as of outcropping bedrocks in the vicinity of the river was examined. In the upper 300 km of the river, the magnetic enhancement of the river sediments can be linked to anthropogenic activities. Positive correlations were found in the river sediments between the contents of Cu and Zn and magnetic susceptibility, while Fe, Mn and Ni did not show a correlation with magnetic susceptibility. However, the major geogenic magnetic anomaly in the area around the Slapy dam has made it impossible to unambiguously interpret the magnetic signal in terms of anthropogenic impact in the last 80 km downstream.  相似文献