Wollastonite at Nuliyam,Kerala, southern India: a reassessment of CO2-infiltration and charnockite formation at a classic locality     

Simon L. Harley  M. Santosh 《Contributions to Mineralogy and Petrology》1995,120(1):83-94

The occurrence of a charnockitised felsic gneiss adjacent to a marble/calc-silicate horizon at Nuliyam, southern India, has been cited in recent literature as a classic example of the dehydration of crustal rocks resulting from the advective infiltration of CO₂-rich fluids generated from a local carbonate source. Petrographic study of the Nuliyam calc-silicate, however, reveals it to consist of abundant wollastonite and scapolite and contain locally discordant veins rich in wollastonite. At the pressure—temperature conditions proposed for charnockite formation in recent studies, 5 kbar and 725°C, this wollastonite-bearing mineral assemblage was stable in the presence of a fluid phase only if X _CO2 was near 0.25 and could not have coexisted with the fluid causing biotite breakdown and charnockite development in adjacent rocks (X _CO2>0.85). The stable coexistence of wollastonite and scapolite prohibits the calc-silicate from being a source for fluid driving charnockitisation at the required P-T conditions. Textural observations such as the limited replacement of wollastonite by calcite+quartz symplectites and mosaics, are consistent with late fluid infiltration into the calc-silicate. The extensive isotopic, chemical and mineral abundance data of Jackson and Santosh (1992) are re-interpreted and integrated with these observations to develop a model involving the infiltration of an externally derived CO₂-rich fluid during high-temperature decompression. Increased charnockite development next to the calc-silicate has arisen because the calc-silicate acted as a relatively unreactive and impermeable barrier to fluid transport and caused fluid ponding beneath antiformal closures. The Nuliyam charnockite/calc-silicate locality is an example of a structural trap in a metamorphic setting rather than a site where charnockite formation can be attributed to local fluid sources.  相似文献   

Monazite behaviour and age significance in poly-metamorphic high-grade terrains: A case study from the western Musgrave Block, central Australia     

Nigel M. Kelly  Geoffrey L. Clarke  Simon L. Harley 《Lithos》2006,88(1-4):100-134

Integrated, in situ textural, chemical and electron microprobe age analysis of monazite grains in a migmatitic metapelitic gneiss from the western Musgrave Block, central Australia has identified evidence for multiple events of growth and recrystallisation during poly-metamorphism in the Mesoproterozoic. Garnet + sillimanite-bearing metapelite underwent partial melting and segregation to palaeosome and leucosome during metamorphism between 1330 and 1296 Ma, with monazite grains in leucosome recording crystallisation at 1300 Ma. Monazite breakdown during melting is inferred to have occurred in the palaeosome. During a subsequent granulite facies event at 1200 Ma, deformation and metamorphism of leucosome and palaeosome resulted in partial disturbance of ages and potential minor growth on 1300 Ma monazite in leucosome. Growth of new, high-Y (+HREE) monazite in palaeosome domains occurred during garnet breakdown in the presence of sillimanite to cordierite and spinel, as a result of post-peak isothermal decompression. Diffusive enrichment of resorbed garnet rims in Y + HREE suggests garnet breakdown occurred slower than volume diffusion of REE. Monazite in both palaeosome and leucosome were subsequently partially to penetratively recrystallised during a retrogression event that is suggested to have occurred at 1150–1130 Ma. The intensity of recrystallisation and disturbance of ages appears linked to proximity to retrogressed garnet porphyroblasts and their occurrence in the relatively reactive or ‘fertile’ local environments provided by the palaeosome/mesosome volumes, which caused localised changes in retrogressive fluids towards compositions more aggressive to monazite. Like reaction textures, it is apparent that domainal equilibrium and reaction may control or at least strongly influence monazite REE and U–Th–Pb chemistry and hence ages.  相似文献   

Two stages of zircon and monazite growth in anatectic leucogneiss: SHRIMP constraints on the duration and intensity of Pan-African metamorphism in Prydz Bay, East Antarctica   总被引：5，自引：0，他引：5  

I.C.W. Fitzsimons  P.D. Kinny  & S.L. Harley 《地学学报》1997,9(1):47-51

SHRIMP U–Pb data from two samples of foliated anatectic leucogneiss bracket the high-grade metamorphic history of metasediments from southern Prydz Bay, East Antarctica. Magmatic zircons in these two samples have mean crystallization ages of 535 ± 13 and 536 ± 35 Myr, and provide a good estimate for the timing of peak metamorphism and partial melting. Low-Th monazite grains in the same samples have mean ages of 528 ± 4 and 527 ± 11 Myr, which are within error of the zircon ages but may reflect a lower blocking temperature. High-Th monazite rims with younger mean ages of 518 ± 3 and 512 ± 13 Myr occur around low-Th cores in both samples, and were precipitated from hydrous fluids released during the crystallization of residual melts. These magmatic fluids were channelled along the retrograde foliation present in both samples. All mineral assemblages and fabrics preserved in the metasediments reflect intense Pan-African metamorphism and deformation, associated with high degrees of partial melting and significant vertical displacements of the crust. Continental reconstructions assuming limited Pan-African tectonism in East Antarctica should be reassessed in the light of these new data.  相似文献   

Experimental determination of REE partition coefficients between zircon,garnet and melt: a key to understanding high‐T crustal processes          下载免费PDF全文

R. J. M. Taylor  S. L. Harley  R. W. Hinton  S. Elphick  C. Clark  N. M. Kelly 《Journal of Metamorphic Geology》2015,33(3):231-248

The partitioning of rare earth elements (REE) between zircon, garnet and silicate melt was determined using synthetic compositions designed to represent partial melts formed in the lower crust during anatexis. The experiments, performed using internally heated gas pressure vessels at 7 kbar and 900–1000 °C, represent equilibrium partitioning of the middle to heavy REE between zircon and garnet during high‐grade metamorphism in the mid to lower crust. The D_REE (zircon/garnet) values show a clear partitioning signature close to unity from Gd to Lu. Because the light REE have low concentrations in both minerals, values are calculated from strain modelling of the middle to heavy REE experimental data; these results show that zircon is favoured over garnet by up to two orders of magnitude. The resulting general concave‐up shape to the partitioning pattern across the REE reflects the preferential incorporation of middle REE into garnet, with D_Gd (zircon/garnet) ranging from 0.7 to 1.1, D_Ho (zircon/garnet) from 0.4 to 0.7 and D_Lu (zircon/garnet) from 0.6 to 1.3. There is no significant temperature dependence in the zircon–garnet REE partitioning at 7 kbar and 900–1000 °C, suggesting that these values can be applied to the interpretation of zircon–garnet equilibrium and timing relationships in the ultrahigh‐T metamorphism of low‐Ca pelitic and aluminous granulites.  相似文献   

Late Pleistocene baldcypress (Taxodium distichum) forest deposit on the continental shelf of the northern Gulf of Mexico     

Kristine L. Delong  Suyapa Gonzalez  Jeffrey B. Obelcz  Jonathan T. Truong  Samuel J. Bentley Sr  Kehui Xu  Carl A. Reese  Grant L. Harley  Alicia Caporaso  Zhixiong Shen  Beth A. Middleton 《Boreas: An International Journal of Quaternary Research》2021,50(3):871-892

Approximately 13 km south of Gulf Shores, Alabama (United States), divers found in situ baldcypress (Taxodium distichum) stumps 18 m below the ocean surface. These trees could have only lived when sea level fell during the Pleistocene subaerially exposing the tectonically stable continental shelf. Here we investigate the geophysical properties along with microfossil and stratigraphical analyses of sediment cores to understand the factors that lead to this wood’s preservation. The stumps are exposed in an elongated depression (~100 m long, ~1 m deep) nested in a trough of the northwest–southeast trending Holocene sand ridges and troughs with 2–5 m vertical relief and ~0.5 km wavelength. Radiocarbon ages of the wood were infinite thus optically stimulated luminescence (OSL) dating was used to constrain the site’s age. Below the Holocene sands (~0.1–4 m thick), separated by a regional erosional unconformity, are Late Pleistocene mud-peat (72±8 ka OSL), mud-sand (63±5, 73±6 ka OSL), and palaeosol (56±5 ka OSL) facies that grade laterally from west to east, respectively. Foraminiferal analysis reveals the location of the terrestrial-marine transitional layer above the Pleistocene facies in an interbedded sand and mud facies (3940±30 (1σ) ¹⁴C a BP), which is part of a lower shoreface or marine-dominated estuarine environment. The occurrence of palaeosol and swamp facies of broadly similar ages and elevation suggests the glacial landscape possessed topographic relief that allowed wood, mud and peats to be preserved for ~50 ka of subaerial exposure before transitioning to the modern marine environment. We hypothesize that rapid sea-level rise occurring ~60 or ~40 ka ago provided opportunities for local flood-plain aggradation to bury the swamp thus preserving the stumps and that other sites may exist in the northern Gulf of Mexico shelf.  相似文献   

Large sand waves on the Atlantic Outer Continental Shelf around Wilmington Canyon,off Eastern United States     

Harley J. Knebel  David W. Folger 《Marine Geology》1976,22(1):M7-M15

New seismic-reflection data show that large sand waves near the head of Wilmington Canyon on the Atlantic Outer Continental Shelf have a spacing of 100–650 m and a relief of 2–9 m. The bedforms trend northwest and are asymmetrical, the steeper slopes being toward the south or west. Vibracore sediments indicate that the waves apparently have formed on a substrate of relict nearshore sediments. Although the age of the original bedforms is unknown, the asymmetry is consistent with the dominant westerly to southerly drift in this area which has been determined by other methods; the asymmetry, therefore, is probably modern. Observations in the sand-wave area from a submersible during August 1975, revealed weak bottom currents, sediment bioturbation, unrippled microtopography, and lack of scour. Thus, the asymmetry may be maintained by periodic water motion, possibly associated with storms or perhaps with flow in the canyon head.  相似文献   

Photosynthesis-irradiance relationships for three species of submersed macrophytes in the tidal freshwater Hudson River     

Michael T. Harley  Stuart Findlay 《Estuaries and Coasts》1994,17(1):200-205

Net photosynthesis under a range of natural light intensities was determined for three common macrophytes of the tidal freshwater Hudson River:Vallisneria americana Michx.,Potamogeton perfoliatus L., andMyriophyllum spicatum L. Light-saturated net photosynthetic rates did not differ among species, nor were there differences among species in the light intensity at which respiration balanced photosynthesis. The initial slope (α) of the photosynthesis-irradiance (P-I) curve was greater forV. americana than the other two species. As a result, maximum photosynthetic rates were reached inV. americana at significantly lower irradiances than those required to saturate photosynthesis inP. perfoliatus andM. spicatum. This characteristic would give this species a competitive advantage under conditions in which growth is limited by light availability. Macrophyte biomass distribution showed no clear correlation with depth.V. americana was the most abundant of the three species, both in frequency of occurrence and absolute biomass. The low irradiance required for the saturation of photosynthesis inV. americana may contribute to its predominance in the turbid Hudson River.  相似文献   

The distribution of H2O–CO2 between cordierite and granitic melt under fluid-saturated conditions at 5 kbar and 900 °C     

Pauline Thompson  Simon L. Harley  Damian P. Carrington 《Contributions to Mineralogy and Petrology》2001,142(1):107-118

  相似文献   

Partial melting and phase relations in high-grade metapelites: an experimental petrogenetic grid in the KFMASH system   总被引：31，自引：0，他引：31  

D. P. Carrington  S. L. Harley 《Contributions to Mineralogy and Petrology》1995,120(3-4):270-291

Petrogenetic grids are a powerful tool for understanding metamorphic terrains and many theoretical grids have been suggested for the process of granulite formation in metapelitic rocks, via fluid-absent biotite melting reactions. However, application of these grids has been difficult due to the lack of suitable experimental constraints. We present here an experimentally determined and tightly constrained petrogenetic grid for KFMASH system metapelites which extends from 840–1000°C and 5.0–12.5 kbar. Sixty four experiments on three KFMASH, mineral-mix, bulk compositions (X _Mg=0.62, 0.74, 0.86) provide phase composition and assemblage data from which a grid can be derived and constrained. Reversal experiments and consideration of the phase composition data show the experiments to be close to equilibrium. The KFMASH univariant fluid-absent biotite melting reactions occur between 850 and 870°C at 5 kbar and between 900 and 915°C at 10 kbar. These reactions are connected to equilibria beyond the stability of biotite to develop a fixed framework within which the phase assemblage evolution of metapelitic rocks can be interpreted. The effect of minor components on phase equilibria is evaluated using the experimentally determined grid as a simple-system reference. The temperature at which melting occurs in metapelites is strongly controlled by the concentrations of titanium and fluorine in biotite. Pressure-temperature pseudosections presented for each of the experimental compositions show both the univariant and divariant reactions available to a particular bulk composition, clearly illustrating the possible evolution of the phase assemblage. The pseudosections also constrain the stability limits of  相似文献   

Reaction textures in scapolite–wollastonite–grossular calc-silicate rock from the Kerala Khondalite Belt, Southern India: evidence for high-temperature metamorphism and initial cooling     

M. Satish-Kumar  Simon L. Harley 《Lithos》1998,44(3-4):83-99

Scapolite–wollastonite–grossular bearing calc-silicate rocks from the Vellanad area in the Kerala Khondalite Belt (KKB) of Southern India preserve a number of reaction textures which help to deduce their P–T–fluid history. Textures include calcite+plagioclase±quartz symplectites after scapolite, grossular+quartz coronas between wollastonite and plagioclase, grossular coronas between wollastonite and plagioclase+calcite that replace former scapolite, and grossular blebs replacing anorthite+calcite+quartz pseudomorphs of scapolite. Garnet coronas are also observed between clinopyroxene and wollastonite or scapolite or plagioclase. The reactions, apart from those involving clinopyroxene, can be modelled in the simple CaO–Al₂O₃–SiO₂–CO₂ system and interpreted using partial reaction grids constructed for the activities of end-members in the analysed phases. The reaction topologies produced are good approximations for the peak as well as retrograde mineral assemblages and reaction textures. For the compositions of the phases present in this study, the medium pressure calc-silicate assemblages are defined by the stable pseudo-invariant points [Qtz], [Mei] and [Grs]. The textural features interpreted using these activity-corrected grids indicate a phase of isobaric cooling from about 835°C to 750°C at 6 kbar in the Vellanad area. This is inconsistent with earlier studies on other lithologies from the KKB, most of which imply a post-peak P–T path involving near-isothermal decompression. However, as the temperatures obtained for the KKB from the calc-silicates are higher than those previously deduced from metapelites and garnet–orthopyroxene assemblages, the phase of near-isobaric cooling reported here is inferred to have proceeded prior to the onset of the decompression documented from studies of other rock types.  相似文献