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Transformation of arsenic compounds in modern intertidal sediments of Iriomote Island, Japan 总被引:1,自引:0,他引:1
The arsenic accumulation process in intertidal sediments of Iriomote Island, Japan, is analyzed as a naturally balanced arsenic-fixation system. Major and minor element chemistry is analyzed by X-ray fluorescence photometry, mineralogy is investigated by X-ray diffractometry, and four arsenic compounds are characterized by hydrogen-generated atomic absorption photometry. It is found that arsenic is accumulated by iron hydroxides/oxides precipitated following the decomposition of humic acids in the shallower sediment, and is subsequently incorporated into iron sulfide minerals at depth. The arsenic is immobile during incorporation into arsenic-bearing phases, suggesting that arsenic is unlikely to be released into the porewater under natural conditions in early diagenesis. The formation and decomposition of arsenic-bearing organic compounds appear to be associated with the formation and decomposition of arsenic in oxyhydroxides/oxides, suggesting that microbial activity may play an important role in controlling the behavior of arsenic and arsenic-bearing phases in the sediment column. 相似文献
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The chemical composition of lake water in Laguna Amarga, a small, shallow, saline lake near the Torres del Paine National Park (at 51°S), Chilean Patagonia, was studied in January, 1993. The water was strongly alkaline (pH 9.4) conductivity was 71.4 mS cm–1, and salinity was 77 g L–1. The major ions were sodium and sulphate. 相似文献
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Development of a New Method of Extraction of Interstitial Water from Low‐Porosity Consolidated Sediments Recovered During Super‐Deep Drilling Projects 下载免费PDF全文
Tomohiro Toki Harue Masuda Harunur Rashid Sebastian Hammerschmidt Ryuichi Shinjo 《Geostandards and Geoanalytical Research》2016,40(2):291-300
During the Integrated Ocean Drilling Program (IODP) Expedition 338, several methods were tested for the extraction of interstitial water in consolidated, low‐porosity deep‐sea sediments from Site C0002 in the Kumano Basin. On the basis of those tests, we propose a modified ground rock interstitial normative determination (GRIND) method of extraction of interstitial water. In separate runs of the new method, sediment samples were ground in a ball mill with either ultrapure water or a solution of HNO3. The interstitial water was then extracted with a conventional squeezer. Sufficient solution was extracted by this method to analyse most major and a few minor components of interstitial water that were comparable to those previously reported for samples extracted by the conventional squeezing method. The new method requires much smaller amounts of sediment than that of the conventional method and will be useful for analysis of samples recovered during super‐deep drilling programmes. 相似文献
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Xiao-Dong Li Cong-Qiang Liu Masuda Harue Si-Liang Li Xiao-Long Liu 《Applied Geochemistry》2010,25(12):1924-1936
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峨眉山地区大气漂尘化学组成研究 总被引:2,自引:0,他引:2
为了揭示峨眉山大气漂尘的化学特征,研究小组分别在1998,1999,2000年使用小型大气采样器进行采样,并测得样品中含有水溶性化学成分(Na^ ,K^ ,Mg^2 ,Ca^2 ,SO4^2-,NO3^-,NH4^ 和Cl^-)和酸溶性化学成分(Pb和Zn)。这一地区三年的大气成分与1990年的相似,而且峨眉山的Na^ ,Cl^-,SO4^2-,NO3^-,Ca^2 ,NH4^ ,Pb和Zn浓度分别比日本山形县鹤岗的要高出4-15,3-19,3-5,3-6,13-23,4-7,11-28和10-23倍之多。 相似文献
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Rates of urea supply from the decomposition and the excretion of zooplankton were determined for samples collected in Suruga
Bay. Five species of Zooplankton were incubated in filtered seawater at 20‡C for 276 hrs after being forced to die in a refrigerator.
More than 77.6 % of body nitrogen of the Zooplankton was liberated, except forEuphausia similis, which showed a lower decomposition rate of 53.0 %. In the liberated nitrogen. 4.8 to 9.8 % was determined as urea.
Incubation experiments of two species of zooplankton at 13‡C during 12 hrs, showed that the organisms excreted 0.86 and 0.73Μg-at. N indi.−1 d−1 as total soluble nitrogen. Urea accounted for 8.3 and 6.8 % of the excreted total soluble nitrogen. 相似文献
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Naoya Miyoshi Hisao Satoh Yoshiaki Yamaguchi Harue Masuda 《Geostandards and Geoanalytical Research》2003,27(1):91-98
Five synthetic silica glasses have been prepared for microprobe determination of trace aluminium in quartz. The glasses were synthesized from tetraethoxysilane (TEOS) into which between 0 and 1431 μg g-1 aluminium had been doped. The aluminium concentrations of the glasses were independently determined by ICP-AES analysis. X-ray wavelength shift in the Al Kα peak was minimised relative to unknown quartz samples when these glasses were used for calibration. A set of these five glasses yielded a linear calibration line, and are available for trace aluminium analysis of quartz in routine microprobe systems. 相似文献