The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States     

Herbert L Windom  Ralph G Smith  Masaru Maeda 《Marine Chemistry》1985,17(1):43-56

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.  相似文献   

Partitioning of Ca and Al between forsterite and silicate melt in dynamic systems with implications for the origin of Ca,Al‐rich forsterites in primitive meteorites     

Andreas Pack  Herbert Palme 《Meteoritics & planetary science》2003,38(8):1263-1281

Abstract— We report the results of dynamic crystallization experiments that were specifically designed to study the dependence of Ca and Al partitioning between forsterite and melt in rapidly cooling Caand Al‐rich melts. The partitioning of Ca between olivine and silicate melt is found to be independent of the cooling rate within the range of 1.5 to 1000°C/hr and at CaO contents of up to 25 wt%. Within analytical uncertainty, our data plot on the equilibrium partitioning curve obtained by Libourel (1999). The partitioning behavior of Al at high cooling rates is more complex. Aluminum is much more heterogenously distributed in the olivine and the co‐existing melt than Ca. But, no systematic trend of Al partition coefficient with cooling rate is observed. We apply the results of the experiments to the formation of meteoritic forsterites with relatively high contents of Ca and Al. Although these forsterites are found frequently inside chondrules, the Ca contents of their host chondrules are far too low to crystallize these high Ca‐forsterites. This is also true for very rapid cooling of chondrule melts. The parental melt of these forsterites requires CaO contents above 20 wt%.  相似文献   

Coronal Holes and Icosahedral Symmetry     

Wolfram Neutsch  Herbert Kalisch  Horst Fichtner  S. Ranga Sreenivasan  Maurice Shevalier 《Astrophysics and Space Science》2003,288(3):391-408

The study of the expansion of the solar wind out of a system of coronal holes is continued. To this end, we consider the numerical integration of partial differential equations for problems with icosahedral symmetry, in general. First, employing Weyl theory, orbifold coordinates are introduced. Second, the icosahedral coordinates are discussed in detail. Third, following an analysis of the properties of these coordinates and the derivation of a few expressions useful for grid construction, various alternatives for the distribution of lattice points required for numerical integration are considered. A comparison of these numerical grids motivates the choice of a specific grid optimized for the numerical integration carried out in the accompanying paper by Kalish et al.(2002). This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Partitioning of Na between olivine and melt: An experimental study with application to the formation of meteoritic Na₂O-rich chondrule glass and refractory forsterite grains     

Alexander Borisov  Andreas Pack  Andreas Kropf  Herbert Palme 《Geochimica et cosmochimica acta》2008,72(22):5558-5573

We report experimentally determined 1 atm olivine/melt D_Na partitioning data for low f_O2, a variety of melt compositions and a temperature range of 1325-1522 °C. We demonstrated that high-current electron microprobe analyses (EPMA, I = 500 nA, 600 s on the peak) allow quantitative determination of Na₂O in olivine down to ∼10 μg/g. The mean olivine/melt D_Na from 12 experimental runs is 0.0031 ± 0.0007 (1σ). This is the recommended value for low pressures and a wide range of natural compositions.This result is applied to the problem of the origin of alkalis in chondrules and the formation of chondritic refractory forsterite grains. The data on Semarkona (LL3.0) chondrules show that Na₂O is primordial and was present during olivine crystallization. For refractory forsterite grains from Murchison (CM2), we demonstrate that high CaO contents are not a result of equilibration with Na₂O-rich melts, but require high activities of CaO during their formation.  相似文献   

Hydrometeorologische Ergebnisse aus Abflußmessungen im Bereich des Hintereisferners (Ötztaler Alpen) in den Jahren 1957 bis 1959     

Dr. Herbert Lang 《Theoretical and Applied Climatology》1966,14(3-4):280-302

Zusammenfassung Während der Internationalen Geophysikalischen Jahre 1957 bis 1959 wurde an einer Pegelmeßstelle bei 2287 m Höhe der Abfluß vom Hintereis- und Kesselwandferner registriert. Im vorliegenden Arbeitsbericht sollen spezifischen Merkmale des Abflusses aus dem zu 58% vergleitscherten Einzugsgebiet 26,6 km²) im Zusammenhang mit den meteorologischen Beidingungen dargestellt werden.Der Jahresabfluß betrug im Haushaltsjahr 1957/58 1848 mm und im Haushaltsjahr 1958/59 1770 mm; bedingt durch den stark negative massenhaushat der Gletscher was die Gletscherspende mit 24% bzw. 20% des Jahresabflusses außergewöhnlich hoch. Der winterabfluß (Oktober bis März) betrug nur 5% bzw. 10% des Jahresabflusses; die drei Sommermonate Juli bis September Lieferten dagegen 76% bzw. 72%. Der größte Monatsabfluß wurde im August 1958 mit 575 mm, im Juli 1959 mit 559 mm registriert.Die Häufigkeitsverteilung der Tagesabflußmengen für das Jahr 1957/58 ließ eine Andauer des Niedrigwassers mit Tages-Mittelwerten kleiner als 18,8 l/s km² (0,5 m³/s) von 217 Tagen (Oktober bis Mai, 59% des Jahres) erkennen. Größere Tagesabflüsse als 225 l/s km² (6,0 m³/s) kamen nur im Juli und August vor. Als Maximum wurden Abflußwerte bis zu 640 l/s km² Gletscherfläche im Tagesmittel erreicht, entsprechen 55m Abflußhöhe von den Schnee- und Eisflächen. Der exponentielle Abfall der Abflußganglinie vom Herbst zum Minimum im Frühjahr deutet an, daß es sich bei Winterwasser vorwiegend um das verzögerte Abfließen von in den Gletschern zurückgehaltenem Schmelzwasser aus der vorangegangenen Ablationsperiode handelt. Das Ansteigen der Wasserführung nach dem Beiginn der Schneeschmelze im Frühjahr erfolgt wegen des Wiedergefrierens von Schmelzwasser und wegen des Retentionsvermögens der Schneedecke mit einiger Verzörgerung.Die unperiodischen Schwankungen im Abflußgang stehen in engem Zusammenhang mit Wettervorgängen, wobei Schneeniederschlägen die Größte Bedeutung zukommt, weil die hohe Albedo einer Neuschneedecke die Ablation auf den Gletschern tagelang fast völlig unterbrechen kann. Aus zweistündigen Mittelwerten wurde für die Monate Juni bis September der mittlere Tagesgang der Wasserführung ermittelt. Die Ursache für das frühere Eintreten des taglichen Abflußmaximums im Spätsommer durfte verminderte Abflußverzögerung sein. Die Beziehung zwischen den Abflußwerten der Pegel Steg-Hospiz und Vent läßt einen Jahresgang erkennen.

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Summary During the International Geophysical Years 1957–1959 the run-off from Hintereisferner and Kesselwandferner was recorded by a stream gauge installed at an altitude of 2287 m. a. s. 1. The annual run-off in relation to mass budget and precipitation has already been reported in [10, 11]. In the present report characteristic features of run-off from a catchment area (26.6 km²) glaciated to 58 per cent shall be discussed with regard to the meteorological conditions.In the budget years 1957/58 and 1958/59 the yearly run-off was 1848 mm and 1770 mm, respectively. Owing to the strongly negative mass budget of the glaciers the glacier quota of 24 per cent and of 20 per cent, respectively, of the annual run-off was exceptionally high. Winter run-off (October to March) amounting to 5 per cent and to 10 per cent, respectively, of the yearly run-off was only small while July to September supplied 76 per cent and 72 per cent, respectively. The maximum monthly run-off was recorded in August 1958 with 575 mm, and in July 1959 with 559 mm.The frequency distribution of the daily run-off in 1957/58 showed a period of low run-off during 217 days (October to May, 59 per cent of the year) with daily means below 18.8 l/s km² (0.5 m³/s). Daily run-off exceeding 225 l/s km² (6.0 m³/s) occurred only in July and August. Daily means exceeding 338 l/s km² (9.0 m³/s) were recorded only three times in July. The maximum daily means of run-off were up to 640 l/s km² of glacier surface which corresponds to 55 mm of run-off from the snow and ice surfaces. The highest two hourly mean value was 950 l/s km² of the glacier surface. The exponential decrease of the run-off curve from fall to the minimum in spring indicates that winter water consists mainly of the delayed run-off of melt water stored in the glaciers during the preceding ablation period. Owing to the refreezing of the melt water and to the storage capacity of the snow cover run-off is somewhat delayed after the snow melt has set in.The aperiodic variations in the run-off are closely related to weather conditions. Snow falls are of primary importance as the high albedo of a fresh snow cover may interrupt ablation on glaciers almost completely for days. The mean daily variation of run-off was determined from two-hourly mean values for the period June to September. The early occurrence of the daily run-off. The relation between the run-off values recorded at the water gauges Steg-Hospiz and Vent indicates and annual variation.

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Résumé Pendant les Années Géophysiques Internationales de 1957 à 1959 l'écoulement du Hintereisferner et du Kesselwandferner a été enregistré par un limnigraphe installé à une altitude 2287 m. Un rapport a déjà été présenté dans [10, 11] sur l'écoulement annuel en rapport avec le bilan hydrologique du bassin. Dans le présent rapoort il sera traité des caractères spécifiques de l'écoulement d'un bassin dont 58% sont recouverts par le glacier, les quels seront mis en rapport avec les conditions météorologiques.L'écoulement annuel au cours de l'année hydrologique 1957/58 a été de 1848 mm et dans l'année hydrologique 1958/59 de 1770 mm. L'eau libérée par la perte de substance glacière représente 24% pour 1957/58 et 20% pour 1958/59 de l'écoulement annuel. Les pourcentages extrêmement élevés doivent être attribués au bilan fortement négatif des glaciers. L'écoulement d'hiver (Octobre à Mars) représentant 5% pour l'année 1957/58 et 10% pour 1958/59 de l'écoulement annuel a été petit tandis que les trois mois d'été (Juillet–Septembre) fournissaient 76% (1957/58) et 72% (1958/59). L'écoulement mensuel le plus élevé a été enregistré en Aôut 1958 avec 575 mm, et, en Juillet 1959 avec 559 mm.La répartition des fréquences des écoulements journaliers pour l'année 1957/58 indique une période d'étiage de 217 jours (Octobre à Mai, 59% de l'année) avec valeurs journalières en dessous de 18.8 l/s km² (0.5 m³/s). Des écoulements dépassant 225 l/s km² (6.0 m³/s) n'ont été enregistrés qu'en Juillet et Aôut. Les moyennes journalières n'ont dépassé les 338 l/s km² (9.0 m³/s) que trois fois en Juillet. Les valeurs maximums des moyennes journalières d'écoulement se sont élevées à 640 l/s km² de la surface des glaciers, correspondant à 55 mm d'écoulement des surfaces de neige et de glace. La valeur maximum d'une moyenne de deux heures a été de 950 l/s km² de la surface des glaciers. La chute exponentielle de la courbe d'écoulement allant de l'automne au minimum enregistré au printemps indique que dans les cas d'étiage il s'agit de l'écoulement retardé des aux de fonte refenues dans les glaciers pendant la période d'ablation précédente. L'accroissement de l'écoulement après le comencement de la fonte de neige au printemps est retardé dans une certaine mesure par le regel des aux de fonte et la capacité de rétention de la couche de neige. Les variations apériodiques dans l'écoulement sont en relations étroites avec les conditions atmospheriques dont les chutes de neige sont de la plus grade importance car l'albédo élevé d'une couche de neige fraîche interrompt parfois et presque complétement l'ablation sur les glaciers pour des jours entiers.L'amplitude moyenne de la variation journalière de l'écoulement a été, pour les mois de Juin à Septembre, détérminée à la base des valeurs moyennes de deux heures. L'apparition précoce du maximum d'écoulement journalier en fin d'été est probablement due à la diminution du retardement de l'écoulement en cette période. La relation entre le valeurs d'écoulement des limnigraphes de Steg-Hospiz et de Vent met en évidence une variation annuelle.

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Die für diesen Bericht erforderliche weitere Bearbeitung der Abflußdaten und die Fertigstellung des Manuskriptes wurde dem Verfasser im Rahmen seiner Tätigkeit bei der Kommission für Glaziologie an der Bayerischen Akademie der Wissenschaften ermöglicht, wofür an dieser Stelle gedankt sei.  相似文献   

Holocene sedimentation of a wave-dominated barrierisland shoreline: Cape Lookout, North Carolina     

S.Duncan Heron Jr.  Thomas F. Moslow  William M. Berelson  John R. Herbert  George A. Steele III  Kenneth R. Susman   《Marine Geology》1984,60(1-4):413-434

The sedimentary record of 130 km of microtidal (0.9 m tidal range) high wave energy (1.5 m average wave height) barrier island shoreline of the Cape Lookout cuspate foreland has been evaluated through examination of 3136 m of subsurface samples from closely spaced drill holes. Holocene sedimentation and coastal evolution has been a function of five major depositional processes: (1) eustatic sea-level rise and barrier-shoreline transgression; (2) lateral tidal inlet migration and reworking of barrier island deposits; (3) shoreface sedimentation and local barrier progradation; (4) storm washover deposition with infilling of shallow lagoons; and (5) flood-tidal delta sedimentation in back-barrier environments.

Twenty-five radiocarbon dates of subsurface peat and shell material from the Cape Lookout area are the basis for a late Holocene sea-level curve. From 9000 to 4000 B.P. eustatic sea level rose rapidly, resulting in landward migration of both barrier limbs of the cuspate foreland. A decline in the rate of sea-level rise since 4000 B.P. resulted in relative shoreline stabilization and deposition of contrasting coastal sedimentary sequences. The higher energy, storm-dominated northeast barrier limb (Core and Portsmouth Banks) has migrated landward producing a transgressive sequence of coarse-grained, horizontally bedded washover sands overlying burrowed to laminated back-barrier and lagoonal silty sands. Locally, ephemeral tidal inlets have reworked the transgressive barrier sequence depositing fining-upward spit platform and channel-fill sequences of cross-bedded, pebble gravel to fine sand and shell. Shoreface sedimentation along a portion of the lower energy, northwest barrier limb (Bogue Banks) has resulted in shoreline progradation and deposition of a coarsening-up sequence of burrowed to cross-bedded and laminated, fine-grained shoreface and foreshore sands. In contrast, the adjacent barrier island (Shackleford Banks) consists almost totally of inlet-fill sediments deposited by lateral tidal inlet migration. Holocene sediments in the shallow lagoons behind the barriers are 5–8 m thick fining-up sequences of interbedded burrowed, rooted and laminated flood-tidal delta, salt marsh, and washover sands, silts and clays.

While barrier island sequences are generally 10 m in thickness, inlet-fill sequences may be as much as 25 m thick and comprise an average of 35% of the Holocene sedimentary deposits. Tidal inlet-fill, back-barrier (including flood-tidal delta) and shoreface deposits are the most highly preservable facies in the wave-dominated barrier-shoreline setting. In the Cape Lookout cuspate foreland, these three facies account for over 80% of the sedimentary deposits preserved beneath the barriers. Foreshore, spit platform and overwash facies account for the remaining 20%.  相似文献   

An experimental analysis of spatial competition in a dense infaunal community: The importance of relative effects     

W. Herbert Wilson  Jr 《Estuarine, Coastal and Shelf Science》1984,18(6)

A densely populated soft-sediment community was experimentally analysed for interspecific competition for space in laboratory experiments. No interspecific competitive interactions leading to a decrease in survivorship could be documented over a five-week period. The four most abundant species all coexisted in laboratory microcosms. The two tube-buiding species, the tanaid Leptochelia dubia and the polychaete Rhynchospio arenincola, could not exclude the mobile bivalve Transennella tantilla or the burrowing amphipod Paraphoxus spinosus. None of the species increases its emigration frequency when other species are present. Paraphoxus is found to be a browsing predator on Phynchospio but inflicts no detectable mortality. The coexistence of these species is permitted by virtue of the fact that none of the species can alter the soft-sediment habitat sufficiently to make the habitat unsuitable for the other species.  相似文献   

Geochemistry of suspended matter from the Baltic Sea 2. Results of bulk trace metal analysis by AAS     

Lutz Brügmann  Paul C. Bernard  Rene van Grieken 《Marine Chemistry》1992,38(3-4)

In 1984, on a transect covering the whole Baltic Sea and parts of the adjacent North Sea, 160 water samples were taken and analysed for their concentrations of particulate and dissolved metals. In addition, the suspended materials were investigated for their elemental bulk composition.The particulate fractions represented from about 5% (Cd, Cu and Ni) to 50% (Fe and Pb) of the total (particulate plus dissolved) concentrations. For some elements (Ba, Cd, Cu, Pb and Zn), the particulate matter from the surface microlayer was enriched with respect to those suspended materials taken from 0.2 m depth. This could reflect the atmospheric input of metal-rich aerosols. In anoxic deep waters, maximum contents of Zn (6400 μg g⁻¹), Cu (1330 μg g⁻¹) and Cd (12 μg g⁻¹) were observed in the particulate matter, indicating sulphidic forms. On the other hand, under oxic conditions the distribution coefficients (K_d) decreased with the water depth (Cd, Fe and Pb).Relative to global background levels, the particulate matter contained metal “excesses” amounting to more than 90% of the total contents (Cd, Mn, Pb and Zn). Automated electron probe X-ray microanalysis (EPXMA) revealed that the elemental composition of sediments is mainly governed by post-depositional processes of early diagenesis and is only weakly related to the composition of suspended matter in the overlying water body. For instance, in relation to surface mud sediments of the central Baltic net-sedimentation basins, Zn, Cd, Cu and Mn had 30–100% higher levels in the suspended materials. The general pattern of metal contents of particulate matter taken from 10 m depth on a transect between the Bothnian Bay and the North Sea were—possibly as a result of anthropogenic inputs—rather similar for Pb, Zn and Cu. For Fe and Mn, the distribution patterns along the transect were probably governed by the natural loading characteristics and by the biogeochemistry of those elements.  相似文献   

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon     

Lutz Nasdala  Wolfgang Hofmeister  Nicholas Norberg  James M. Martinson  Fernando Corfu  Wolfgang Dörr  Sandra L. Kamo  Allen K. Kennedy  Andreas Kronz  Peter W. Reiners  Dirk Frei  Jan Kosler  Yusheng Wan  Jens Götze  Tobias Häger  Alfred Kröner  John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   

New paleomagnetic results from the Aegean extensional province     

Haubold  Herbert  Scholger  Robert  Kondopoulou  Despina  Mauritsch  Hermann J. 《Geologie en Mijnbouw》1997,76(1-2):45-55

Various Oligocene formations from NE Greece (ignimbrites from the Medousa area, rhyolites from Zagradenia, granodiorites from Elatia) show discordant paleomagnetic signatures, in each case indicating small cw (clockwise) rotation and also inclination flattening. Marls from Pithion were partly remagnetized in a present-day field. Samples that contain ancient magnetization components also indicate small cw rotation and inclination flattening. However, the magnetization of andesites from Peplos reflects a considerably larger rotation, likely owing to local tectonics. In the context of previous work in the area, these results are used to propose a subdivision of NE Greece into four structural zones of distinctive rotational behaviour (from east to west): sites in zone 1, east of the Kavala-Xanthi-Komotini fault (KXK), show various cw and ccw (counterclockwise) rotation angles owing to complex kinematics resulting from the interaction of the KXK and the north-Anatolian fault zone. However, zone 2, between the KXK and the Strymon valley, is structurally homogeneous ( 10° cw rotation). The paleomagnetic signature of the Vertiskos massif (zone 3) implies a larger (> 30°) cw rotation, whereas sites in the Vardar basin (zone 4) contain a paleomagnetic signature similar to that of zone 2. This suggests a motion of the Vertiscos massif, a meta-ophiolitic nappe, relative to underlying strata. Indeed, zones 2 and 4 may be parts of the same structural unit which underlies this nappe.  相似文献