Evaluation of Density Corrections to Methane Fluxes Measured by Open-Path Eddy Covariance over Contrasting Landscapes     

Samuel D. Chamberlain  Joseph Verfaillie  Elke Eichelmann  Kyle S. Hemes  Dennis D. Baldocchi 《Boundary-Layer Meteorology》2017,165(2):197-210

Corrections accounting for air density fluctuations due to heat and water vapour fluxes must be applied to the measurement of eddy-covariance fluxes when using open-path sensors. Experimental tests and ecosystem observations have demonstrated the important role density corrections play in accurately quantifying carbon dioxide \((\hbox {CO}_{2})\) fluxes, but less attention has been paid to evaluating these corrections for methane \((\hbox {CH}_{4})\) fluxes. We measured \(\hbox {CH}_{4}\) fluxes with open-path sensors over a suite of sites with contrasting \(\hbox {CH}_{4}\) emissions and energy partitioning, including a pavement airfield, two negligible-flux ecosystems (drained alfalfa and pasture), and two high-flux ecosystems (flooded wetland and rice). We found that density corrections successfully re-zeroed fluxes in negligible-flux sites; however, slight overcorrection was observed above pavement. The primary impact of density corrections varied over negligible- and high-flux ecosystems. For negligible-flux sites, corrections led to greater than 100% adjustment in daily budgets, while these adjustments were only 3–10% in high-flux ecosystems. The primary impact to high-flux ecosystems was a change in flux diel patterns, which may affect the evaluation of relationships between biophysical drivers and fluxes if correction bias exists. Additionally, accounting for density effects to high-frequency \(\hbox {CH}_{4}\) fluctuations led to large differences in observed \(\hbox {CH}_{4}\) flux cospectra above negligible-flux sites, demonstrating that similar adjustments should be made before interpreting \(\hbox {CH}_{4}\) cospectra for comparable ecosystems. These results give us confidence in \(\hbox {CH}_{4}\) fluxes measured by open-path sensors, and demonstrate that density corrections play an important role in adjusting flux budgets and diel patterns across a range of ecosystems.  相似文献   

Fluid Inclusion, Rare-Earth Element and Stable Isotope Study of Carbonate Minerals from the Pongkor Epithermal Gold–Silver Deposit, West Java, Indonesia     

I Wayan Warmada    Bernd Lehmann    Marolop Simandjuntak  Herian Sudarman Hemes 《Resource Geology》2007,57(2):124-135

The Pongkor gold–silver deposit is the largest low‐sulfidation epithermal precious metal deposit in Indonesia, and is of Pliocene age. The deposit consists of nine major subparallel quartz–adularia–carbonate veins with very low sulfide content. Vein infill records five paragenetic sequences, dominated by calcite in the early stage and quartz in the later stage of the hydrothermal evolution. Fluid inclusions in hydrothermal calcite and quartz of all stages indicate a temperature ranging from 180 to 220°C and a meteoric water origin (very low salinity close to 0 wt% NaCl equivalent). Carbon isotope data on calcite display a narrow range from ?6.5 to ?3.0‰δ¹³C. The oxygen isotope values have a wider range of +4.6 to +10.1‰δ¹⁸O. The broadly positive correlation of the δ¹³C versus δ¹⁸O plot suggests that the carbon species, which equilibrated during the formation of calcite, is dominated by H₂CO₃ not far from equilibrium with HCO₃^?. The abundance of rare earth and yttrium (REY) in carbonate samples is very low (>REY mostly <2 ppm). However, there is always a positive Eu anomaly, which indicates a deeper fluid reservoir at >250°C.  相似文献