Incorporation of Cr<Superscript>3+</Superscript> in dickite: a spectroscopic study     

E. Balan  T. Allard  G. Morin  G. Calas 《Physics and Chemistry of Minerals》2002,29(4):273-279

 We have investigated a well-ordered sample of natural Cr-bearing dickite from Nowa Ruda (Lower Silesia, Poland) using electron paramagnetic resonance (EPR) at X- and Q-band frequencies (9.42 and 33.97 GHz, respectively) and optical diffuse reflectance spectroscopy. The observation of the spin-forbidden transitions at 15500 and 14690 cm⁻¹ allows us to unambiguously identify the major contribution of octahedrally coordinated Cr³⁺ ions in the optical spectrum. The X- and Q-band EPR spectra show two superposed Cr³⁺ signals. The corresponding fine-structure parameters were determined at room temperature and 145 K. These results suggest the substitution of Cr³⁺ for Al³⁺ in equal proportions in the two unequivalent octahedral sites of the dickite structure. In kaolin group minerals, the distortion around Cr³⁺ ions (λ≈ 0.2–0.4) in Al sites is significantly less rhombic than that observed around Fe³⁺ ions (λ≈ 0.6–0.8). Received: 29 June 2001 / Accepted: 22 October 2001  相似文献   

A study of microearthquake seismicity and focal mechanisms within the Sea of Marmara (NW Turkey) using ocean bottom seismometers (OBSs)   总被引：1，自引：0，他引：1  

Toshinori Sato  Junzo Kasahara  Tuncay Taymaz  Masakazu Ito  Aya Kamimura  Tadaaki Hayakawa  Onur Tan 《Tectonophysics》2004,391(1-4):303

We have carried out seismological observations within the Sea of Marmara (NW Turkey) in order to investigate the seismicity induced after Gölcük–İzmit (Kocaeli) earthquake (M_w 7.4) of August 17, 1999, using ocean bottom seismometers (OBSs). High-resolution hypocenters and focal mechanisms of microearthquakes have been investigated during this Marmara Sea OBS project involving deployment of 10 OBSs within the Çınarcık (eastern Marmara Sea) and Central-Tekirdağ (western Marmara Sea) basins during April–July 2000. Little was known about microearthquake activity and their source mechanisms in the Marmara Sea. We have detected numerous microearthquakes within the main basins of the Sea of Marmara along the imaged strands of the North Anatolian Fault (NAF). We obtained more than 350 well-constrained hypocenters and nine composite focal mechanisms during 70 days of observation. Microseismicity mainly occurred along the Main Marmara Fault (MMF) in the Marmara Sea. There are a few events along the Southern Shelf. Seismic activity along the Main Marmara Fault is quite high, and focal depth distribution was shallower than 20 km along the western part of this fault, and shallower than 15 km along its eastern part. From high-resolution relative relocation studies of some of the microearthquake clusters, we suggest that the western Main Marmara Fault is subvertical and the eastern Main Marmara Fault dips to south at 45°. Composite focal mechanisms show a strike-slip regime on the western Main Marmara Fault and complex faulting (strike-slip and normal faulting) on the eastern Main Marmara Fault.  相似文献   

Enzymatic degradation of polyhydroxyalkanoate using lipase from <Emphasis Type="Italic">Bacillus subtilis</Emphasis>     

P. Kanmani  K. Kumaresan  J. Aravind  S. Karthikeyan  R. Balan 《International Journal of Environmental Science and Technology》2016,13(6):1541-1552

Polyhydroxyalkanoates (PHAs) are an important class of biodegradable polymers synthesized by a few bacteria under nutrient-limiting conditions. In this study, the lipase-catalysed degradation of PHA synthesized by Enterobacter sp. was monitored. For this, the lipase-encoding gene from Bacillus subtilis DI2 was PCR-amplified, cloned into a T vector system and sequenced. It was expressed in Escherichia coli DH5α cells, the recombinant enzyme was purified 24.25-fold, and its molecular weight was determined to be around 28 kDa. When PHA biodegradation studies were carried out with this enzyme, gel permeation chromatography showed 21.3 and 28.3 % molecular weight decrease and weight loss, respectively. Further, scanning electron micrographs revealed alterations in polymer surface morphology. Changes in molecular vibrations were noticed in the FTIR spectra. When the chemical shifts in NMR spectra were studied, a steep reduction in area under the peak at 1.57 ppm was observed. In the heating range of 30–930 °C employed during thermogravimetry analysis, the degraded sample showed a total of 45.82 % weight loss, as against 18.89 % for the native sample. The melting temperature (T _m) of the polymer was also brought down from 126.22 to 118.18 °C, as inferred from differential scanning calorimetry. Lipase-catalysed chain scission reactions could thus be used to generate low molecular weight functional biopolymers with wide-ranging pharmaceutical applications, such as in sustained drug release.  相似文献   

Constraints on unconsolidated pyroclastic flow sediments related REE enrichments originated from potassic-alkaline Gölcük stratovolcano: Darıdere-Direkli-Yakaören (DDY) table 4deposits,southwestern Anatolia of Turkey     

Budakoglu  Murat  Unluer  Ali Tugcan  Doner  Zeynep  Kocaturk  Huseyin  Kaya  Mustafa  Kumral  Mustafa  Kirikoglu  M. Sezai 《中国地球化学学报》2021,40(6):926-944

Acta Geochimica - In the last five decades, Rare Earth Elements (REE) are mostly produced from carbonatite complexes and alkaline magmatic environments. In this respect, pyroclastic flows produced...  相似文献   

Seasonal and solar cycle variations of night-time anomalous enhancements in total electron content     

N. Balan  P. B. Rao  K. N. Iyer 《Journal of Earth System Science》1986,95(3):409-416

Seasonal and solar cycle variations of the various characteristics of night-time anomalous enhancements in total electron content (TEC) of the ionosphere are presented for a low latitude station, Hawaii by considering TEC data for a full solar cycle. All the characteristics of the TEC enhancements have seasonal and solar cycle dependence. TEC enhancement characteristics such as frequency of occurrence, amplitude and duration are positively correlated with solar activity. The possible source mechanisms for the observed enhancements are also discussed.  相似文献   

Changes of oceanographic characteristics and the state of pollution in the Izmit bay following the earthquake of 1999     

Enis Morkoc  Legovic Tarzan  Oya Okay  Huseyin Tufekci  Vildan Tufekci  Leyla Tolun  Fatma Karakoc 《Environmental Geology》2007,53(1):103-112

The Izmit Bay is an elongated semi-enclosed bay in the Marmara Sea. It is being increasingly polluted by both domestic and industrial waste discharge since 1970’s. A monitoring program was conducted between 1999-2000 to document the state of pollution in the bay. This includes the effect of Marmara (Izmit) earthquake (magnitude 7.4) that occurred in August 1999. A stable two-layer ecosystem exists in the bay throughout the year due to continuous inflows of the saltier Mediterranean and brackish Black Sea waters to the Marmara basin. Therefore, the principal biochemical characteristics of the bay are governed by the two-layer flow system over the basin. Dissolved oxygen (DO) is generally at a saturated levels in the surface layer which is 10 to 15 m thick, but it is depleted to 60–70 μM in the lower layer, exhibiting a steep gradient in the sharp halocline. When the earthquake occurred, great loads of industrial wastes were released into the bay surface waters, which enhanced primary production in the upper layer and thus large export of particulate organic matter to lower layer and eventually to the bottom. Accordingly, DO was consumed and anoxic condition was established even in the upper layer/halocline interface, the halocline and bottom waters of the eastern and central bay. In this period, concurrent increases were observed in phosphate and ammonia contents at the halocline and in deep waters whilst the nitrate was almost consumed via denitrification processes in the anoxic water. Recently, the industrial C, N and P loads increased by as much as 8 fold within five years (1995–2000) whilst domestic inputs increased by 50%. Total organic matter discharged to the bay increased more than double within the last 15 years. Besides, most factories in the region release toxic wastes into the bay after only partial treatment.  相似文献   

Forward Modeling with Forced Neural Networks for Gravity Anomaly Profıle     

Onur Osman  A. Muhittin Albora  Osman Nuri Ucan 《Mathematical Geosciences》2007,39(6):593

In this paper, we introduce a new method called Forced Neural Network (FNN) to find the parameters of the object in geophysical section respect to gravity anomaly assuming the prismatic model. The aim of the geological modeling is to find the shape and location of underground structure, which cause the anomalies, in 2D cross section. At the first stage, we use one neuron to model the system and apply back propagation algorithm to find out the density difference. At the second level, quantization is applied to the density differences and mean square error of the system is computed. This process goes on until the mean square error of the system is small enough. First, we use FNN to two synthetic data, and then the Sivas–Gürün basin map in Turkey is chosen as a real data application. Anomaly values of the cross section, which is taken from the gravity anomaly map of Sivas–Gürün basin, are very close to those obtained from the proposed method.  相似文献   

整数模糊度参数的快速检索算法   总被引：1，自引：0，他引：1  

葛茂荣  Huseyin Baki Iz  陈永奇 《测绘学报》1998,27(2):99-104

ＧＰＳ快速定位中,由于模糊度参数之间的强相关性,模糊度参数置信区间定义的检索区域比相应的置信椭球大得多。本文通过模糊度参数向量的正交变换,定义出包含模糊度参数置信椭球的最小正交多面体,借助在其中构造的均匀正交网格点,找出置信椭球中的所有整数模糊度参数向量。该方法显著地减少了整数模糊度参数的检索范围,提高了计算效率。  相似文献   

Newly discovered mud volcanoes in the Coastal Belt of Makran,Pakistan—tectonic implications   总被引：1，自引：1，他引：0  

Akhtar M. Kassi  Shuhab D. Khan  Huseyin Bayraktar  Aimal K. Kasi 《Arabian Journal of Geosciences》2014,7(11):4899-4909

The Makran accretionary wedge has a much larger number of mud volcanoes then those reported earlier. Using high-resolution satellite images, over 70 active mud volcanoes were identified. These mud volcanoes occur within a well-defined zone; we call it the Makran zone of active mud volcanoes (MZAMV), which is parallel to the regional trend of the accretionary wedge. Mud volcanoes within the zone occur as clusters, which form linear belts parallel to the regional thrusts associated with anticlines. The MZAMV zone also includes the offshore mud volcanoes occurring in the shallow shelf area, including the recurrently emerging mud islands. Several occurrences of thick deposits of old mud volcanoes (Pleistocene or even older) are also present within this zone, which also display recognizable features that are characteristic of the fossil mud volcanoes. We propose that the MZAMV developed and evolved in response to the continued compression within the Makran accretionary wedge, which in turn, is a response of the subduction process. Mud diapirism has been an ongoing phenomena since Pleistocene or even earlier. The events of enhanced mud extrusion in mud volcanoes and/or emergence of island(s) have relevance with seismic phenomena and, therefore, may be closely monitored.  相似文献   

Discovering a pull-apart basin using InSAR in Bursa,Turkey     

Hakan S. Kutoglu  Huseyin Kemaldere  Tomonori Deguchı  Mustafa Berber 《Natural Hazards》2014,71(1):871-880

The city of Bursa in Turkey is surrounded by major and secondary fault branches which splay from the North Anatolian Fault. Nonetheless, as their traces were not exactly known in the alluvial land of the Bursa basin, until this study, they were not plotted in the official active fault map of Turkey. In this study, the Bursa basin was observed by InSAR technology, and the subsidence which is consistent with the pull-apart basin geometry was detected in the basin. This finding was discussed in the local platforms in Turkey. Then, the city of Bursa was included into the priority provinces for the urban reconstruction under the risk of an earthquake, and the official active fault map of the region was revised by General Directorate of Mineral Research and Exploration of Turkey.  相似文献