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GERNOT ARP CHRISTIAN OSTERTAG‐HENNING SELÇÜK YÜCEKENT JOACHIM REITNER VOLKER THIEL 《Sedimentology》2008,55(5):1227-1251
Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe2+ and Mn2+ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO3 precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO3 precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ13C in conjunction with evaporite pseudomorphs showing extremely low δ13CCarb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition. 相似文献
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Abstract— To contribute to the understanding of the impact history of asteroids, we performed a high-resolution 40Ar-39Ar study of ten moderately to highly shocked chondrites, which we selected according to the shock classification given by Stöffler et al. (1991). Two recent shocked chondrite falls and two highly shocked eucrites completed our sample suite. When possible, we separated impact melt from host rock for separate analysis. In total, we studied 28 samples from 14 meteorites. In some cases, atmospheric Ar that we associate with terrestrial weathering was identified and corrected for. The ages we obtained range between ～100 Ma and ～4.1 Ga and are clearly distinct from primordial ages that correspond to solar system formation. We reproduced the previously reported cluster of L-chondrite ages, ～500 Ma. The most prominent result of our study is that, in the case of chondrites, melts generally are older than host rocks or melt-embedded unmolten rocks. To solve this apparent paradox, we propose that the melt-forming event, which was the most severe shock episode in the history of these meteorites, has not been the only occasion affecting their K-Ar systems. At least one later impact metamorphism must have occured. The response of the K-Ar clock to this second event was more severe in the host rock than in the previously (in the first event) generated melt veins and pockets because of different Ar retention rates. Hence, impact metamorphism on meteorite parent bodies indeed was a multistage process extending in time over billions of years. 相似文献
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JOACHIM REGNÉLL 《Boreas: An International Journal of Quaternary Research》1992,21(4):373-377
Dating pollen concentrated from sediment samples is a way to improve lake-sediment chronology. The predominantly terrestrial origin of pollen assemblages minimizes, for example, the reservoir effect inherent in bulk sediment samples, especially from hard-water lakes. Pollen can be concentrated for dating by a combination of sieving and chemical treatment (Brown et al . 1989). This study illustrates the difficulty in applying a single, standard procedure, and demonstrates the need for flexibility depending on lake sediment characteristics and the particular pollen flora. Samples taken at the Ulmus decline were prepared and AMS-dated following different steps of the pollen concentration procedure. The results showed that both sieving and chemical treatment were needed to obtain an age close to the expected age for the Ulmus decline. The pollen concentrate dated c . 1000 years younger than a bulk date from the same level, but is close to the expected age based on correlation with dates for the Ulmus decline from Sphagnum peat sequences in north-western Europe. A compilation of bulk dates at the Ulmus decline implies that pollen concentrates would be a better material for dating than bulk samples for many lake sediments, not only for those from hard-water lakes. 相似文献
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Micritization of crinoids by diagenetic dissolution 总被引：2，自引：0，他引：2
JOACHIM NEUGEBAUER 《Sedimentology》1978,25(2):267-283
Bands within the Chalk of Kansas made up of masses of Uintacrinus socialis show an unusual preservation of crinoid ossicles: in contrast to their normal preservation in full relief as single large calcite crystals the ossicles are compressed and transformed to micrite. The micrite originated by a process different from the well-known micritization by algal and fungal borings and subsequent cementation of the borings: it is the outcome of partial dissolution. Dissolution proceeded inside the sediment and preferentially attacked the echinoderms as the most soluble calcareous component of the chalk sediment. Later, the remains of the Uintacrinus crystals preferentially attracted syntaxial cement so that the layer changed to a hard band of limestone within the soft chalk. In addition to a second process of micritization the preservation of Uintacrinus demonstrates (1) that the magnesium content of magnesian calcites survives the earliest stages of diagenesis within chalk, and (2) that a diagenetic comminution of large crystals (in an optical sense) to smaller ones is possible. Provided the ossicles of echinoderms are true single crystals (the knowledge in this field is summarized), this is an example of the often discussed ‘crystal diminution’. 相似文献
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ZHANG Xingliang Joachim REITNER 《《地质学报》英文版》2006,80(5):636-642
The Ediacaran Dickinsonia is well-known for being the only fossil to be assigned to many phyla, ranging from lichens, Cnidaria, Piatyheiminthes, Annelida, and a phylum of its own to a nonmetazoan kingdom. A new specimen from the Ediacaran fine-grained sandstone on the Winter Coast of the White Sea in northern Russia, which has an age of -555 million years ago, preserved convincing internal anatomies of definite animals, comparable with meridionai canals of extant ctenophores （comb jellies）. Additionally, we reconsidered Dickinsonia as a biradiaily symmetrical animal rather than a bilateral one as previously thought. The animal nature of Dickinsonia is, thus, well established and its affinities are most probably allied to ctenophores. This research is not only removing Dickinsonia from Vendobionta, but also bringing the fossil record of ctenophores forward to 20 million years before the Cambrian ＂explosion＂. 相似文献
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Abstract: The Shibantan Member (Dengying Formation, South China) represents one of only two carbonate settings with Ediacara-type organisms and offers a rare opportunity to study the biogeochemistry of these ecosystems. To evaluate possibilities and limitations for future biomarker studies on fossil-bearing outcrop samples of the Shibantan Member, we analysed the spatial distribution of hydrocarbons in extractable organic matter (i.e. bitumen) on a millimetre scale. Our study demonstrates that the sample and most likely also other rocks from the same setting are contaminated with petroleum-derived compounds that bear the potential for erroneous interpretations in palaeo-reconstructions. The contamination was revealed by distribution patterns and amounts of extractable n-alkanes and acyclic isoprenoids. The contamination is linked to the external weathering surfaces but also to cracks within the rock, and the extent most likely depends on concentration gradients between these contamination sources. Here we show that contamination can successfully be distinguished from syngenetic signals obtained from non-extractable organic matter (i.e. kerogen) using catalytic hydropyrolysis (HyPy). However, we observed that decalcification is necessary to achieve sufficient yields of kerogen-bound hydrocarbons and to avoid artificial alteration of the biomarker signals due to matrix effects. 相似文献
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Pervasive early- to late-stage dolomitization of Lower Ordovician Ellenburger Group carbonates in the deep Permian Basin of west Texas and southeastern New Mexico is recorded in core samples having present-day burial depths of 1.5–7.0 km. Seven dolomite-rock textures are recognized and classified according to crystal-size distribution and crystal-boundary shape. Unimodal and polymodal planar-s (subhedral) mosaic dolomite is the most widespread type, and it replaced allochems and matrix or occurs as void-filling cement. Planar-e (euhedral) dolomite crystals line pore spaces and/or fractures, or form mosaics of medium to coarse euhedral crystals. This kind of occurrence relates to significant intercrystalline porosity. Non-planar-a (anhedral) dolomite replaced a precursor limestone/dolostone only in zones that are characterized by original high porosity and permeability. Non-planar dolomite cement (saddle dolomite) is the latest generation and is responsible for occlusion of fractures and pore space. Dolomitization is closely associated with the development of secondary porosity; dolomitization pre-and post-dates dissolution and corrosion and no secondary porosity generation is present in the associated limestones. The most common porosity types are non-fabric selective moldic and vuggy porosity and intercrystalline porosity. Up to 12% effective porosity is recorded in the deep (6477 m) Delaware basin. These porous zones are characterized by late-diagenetic coarse-crystalline dolomite, whereas the non-porous intervals are composed of dense mosaics of early-diagenetic dolomites. The distribution of dolomite rock textures indicates that porous zones were preserved as limestone until late in the diagenetic history, and were then subjected to late-stage dolomitization in a deep burial environment, resulting in coarse-crystalline porous dolomites. In addition to karst horizons at the top of the Ellenburger Group, exploration for Ellenburger Group reservoirs should consider the presence of such porous zones within other Ellenburger Group dolomites. 相似文献