Geothermal palaeogradients and metamorphic zonation from the conodont colour alteration index (CAI)     

Susana García-López  Fernando Bastida  Jesús Aller  & Javier Sanz-López 《地学学报》2001,13(2):79-83

The conodont colour alteration index (CAI) is potentially valuable in thermal history investigations, but there are problems in its use. An approach is proposed herein to overcome the problem of establishing reliable geothermal palaeogradients in areas with burial metamorphism, based on knowledge of the stratigraphic succession thickness, the boundaries of chronostratigraphic units, and the age and duration of deformation episodes. Although also problematical that a correlation between CAI and Kübler index (KI) values does not exist, there are areas where CAI and KI values are notably consistent for the anchizone boundaries; however, anomalous correlations between CAI and KI values have also been found in some areas. A CAI anchizone (or ancaizone) is defined in order to enable CAI values to be used independently to establish a metamorphic zonation.  相似文献   

Diagenesis, palaeoclimate and tectono-sedimentary influences on clay mineralogy and stable isotopes from Upper Cretaceous marine successions of the Basque-Cantabrian Basin (N Spain)     

lvaro Jimnez Berrocoso  Maria Cruz Zuluaga  Javier Elorza 《Cretaceous Research》2008,29(3):386-404

Clay mineralogy and whole-rock stable isotopes (δ¹⁸O and δ¹³C) of Upper Cretaceous marly sediments on the Basque-Cantabrian Basin have been integrated to determine the main effects of diagenesis, palaeoclimate and tectono-sedimentary factors in sections belonging to deep- (Barrika) and platform-marine (Isla de Castro, Villamartín and Olazagutía) settings.The mean values for the clay assemblages and δ¹⁸O exhibit notable differences among the sections, partially explainable by the influence of diagenesis. The Barrika sediments, with more diagenetically advanced illite-smectite (I-S) mixed-layer (R1, 70% illite), authigenic chlorite, and low δ¹⁸O (−4.05‰ PDB), experienced higher diagenetic grade than Isla de Castro and Olazagutía, which have R0 I-S (20% illite) and heavier δ¹⁸O. Villamartín was also affected by higher diagenesis than Isla de Castro and Olazagutía, given the occurrence of R1 I-S (60% illite) and low δ¹⁸O (−4.11‰ PDB). However, the absence of other clays in Villamartín (e.g. authigenic chlorite) is indicative of less diagenetic grade than Barrika. These results show the useful integration of clay mineralogy and stable isotopes to detect different diagenetic grades in distinct marine successions of the same basin.Despite being influenced by diagenesis, the clay mineralogy partially preserves its inherited signature. This allows detection of major contents of I-S and mica, and minor kaolinite, interpreted as indicative of warm palaeoclimatic conditions. High kaolinite content in Villamartín and absence of kaolinite in Isla de Castro, though, are considered to be a product of neither diagenesis nor palaeoclimatic influences. Instead, tectono-sedimentary causes, related to unsuitable conditions for clay formation and transport from the local source areas, contributed to original clay differences. The inferred effects of diagenesis, palaeoclimate and tectono-sedimentary factors make this work important to show the potentially great variety of controls on the clay mineralogy of marine sections, which are often uncritically treated in studies concerning the Late Cretaceous.  相似文献   

Soil contamination from urban and industrial activity: example of the mining district of Linares (southern Spain)   总被引：1，自引：0，他引：1  

J. Martínez  J. F. Llamas  E. de Miguel  J. Rey  M. C. Hidalgo 《Environmental Geology》2008,54(4):669-677

The Linares region (southern Spain) has been subjected to two important sources of pollution: the intensive mining works and the urban-industrial activity. To obtain a geochemical characterisation of the soil, 31 trace elements were analysed and 669 soil samples were collected. By means of clustering analysis, we identified groups of elements and grid squares in which relations could be established concerning soil lithology, urban and industrial activities and the degree of pollution impact; in addition, we were able to characterise the geochemical background of the study area. The multivariate study led us to identify four factors. Particularly important was factor 2, which represented the elements associated with mineral paragenesis (Cu, Pb, As, Co, Mn, Zn, Sn, Ba). This factor also contains elements related with an urban-industrial activity, such as Pb, Cu, Zn, As and Ba. Furthermore, we identified factor 4, associating Ni, V and Cr, and which is related to the use of fuels.  相似文献   

Temporal variability of Pb fluxes and bioturbation in shelf sediments beneath the high primary production area off Concepción, central-southern Chile (36°S)     

Praxedes Muñoz  Javier Sellanes  Carina Lange  Maritza Palma 《Progress in Oceanography》2007,75(3):586-602

We estimated monthly fluxes of ²¹⁰Pb in shelf sediments beneath a high productivity area off central-southern Chile (36°S) during 1 year (September 2002-August 2003). Sediment cores were obtained using a multiple corer and were analyzed mainly for ²¹⁰Pb, total pigments, and macrofauna abundance. The ²¹⁰Pb inventories and fluxes were estimated for surface sediments (0-5 cm) and bioturbation coefficients were inferred using chlorophyll-a (reactive) profiles. In general, ²¹⁰Pb content was inversely correlated with phytodetritus fluxes. High photosynthetic pigment contents in surface sediments were consistently associated with lower ²¹⁰Pb contents. Macrofaunal activity responded to oxygen and organic matter supplies at the sediment surface, generally concentrated in the first centimeters, but particularly so during months of high organic matter fluxes and deficient bottom water oxygen conditions. At this study site, several processes involved in the ²¹⁰Pb surface distribution make it difficult to accurately estimate ages at the surface. We postulate that the organic fluxes promote changes in the faunal activity, which, in combination with sediment resuspension and water circulation over the shelf, produce seasonal variations in the ²¹⁰Pb inventories.  相似文献   

Cd, Pb, Cu, Ni and Co distribution in the German Bight     

L. Mart  H.W. Nürnberg   《Marine Chemistry》1986,18(2-4)

Cd, Pb and Cu concentrations, dissolved and total, have been determined in the German Bight. In 1975, 1977, 1978, 1980 and 1983 water samples were collected at 215 sampling stations. In the 1983 mission samples were also analysed for Ni and Co. The samples were filtered and acidified immediately after collection. Analysis was performed by voltammetry.The analytical data indicate that a net portion of the Cd, the Weser being a distinct source for it, will cross the estuarine zone. Open sea Cd levels in the German Bight are about a factor 10 higher than North Atlantic values. Pb, being transported mainly with the suspended particulate phase (up to 99.5%), is better eliminated by sedimentation in the estuaries. Ni and Cu occur mainly in the dissolved phase. Pollution by Co is distinct in the Elbe, but the output is rapidly diluted to background contents below 10 ng kg⁻¹. An interpretation of the results from the different years yields a rather steady state situation in the German Bight.  相似文献   

The Levant Slumps and the Phoenician Structures: collapse features along the continental margin of the southeastern Mediterranean Sea     

Yossi Mart  William Ryan 《Marine Geophysical Researches》2007,28(4):297-307

Two distinct series of slumps deform the upper part of the sedimentary sequence along the continental margin of the Levant. One series is found along the base of the continental slope, where it overlies the disrupted eastern edge of the Messinian evaporites. The second series of slumps transects the continental margin from the shelf break to the Levant Basin. It seemed that the two series were triggered by two unrelated, though contemporaneous, processes. The shore-parallel slumps were initiated by basinwards flow of the Messinian salt, that carried along the overlying Plio-Quaternary sediments. Seawater that percolated along the detachment faults dissolved the underlying salt to form distinctly disrupted structures. The slope-normal slumps are located on top of large canyons that cut into the pre-Messinian sedimentary rocks. A layer of salt is found in the canyons, and the Plio-Quaternary sediments were deposited on that layer. The slumps are bounded by large, NW-trending faults where post-Messinian faulted offset was measured. We presume that the flow of the salt in the canyons also drives the slope-normal slumps. Thus thin-skinned halokynetic processes generated the composite post-Tortonian structural patterns of the Levant margin. The Phoenician Structures are a prime example of the collapse of a distal continental margin due to the dissolution of a massive salt layer.  相似文献   

Faults at the proximal continental shelf off Atlit,central Israel,and their neotectonic significance     

Yossi Mart 《Geo-Marine Letters》1996,16(2):41-48

A seismic reflection survey was conducted in the proximal shelf off Atlit, western Mt. Carmel, Israel, to clarify the regional neotectonic regime. The Atlit promontory is built of late Pleistocene eolianite ridge, truncated by faults at its northern extension. The seismic survey encountered two series of faults, trending N—S and NW—SE, offsetting the upper strata by 1–5 m. Faulted escarpments of the N—S faults are barely covered by sediments, suggesting that they are tectonically active. The escarpments of the NW—SE faults are rarely exposed, suggesting their late Pleistocene age. A submerged undamaged Neolithic well near a major NW trending fault indicates that the structural stability of these faults during the last 8000 years can be presumed.  相似文献   

Alkaline phosphatase activity and its relationship to inorganic phosphorus in the transition zone of the North-western African upwelling system     

Marta Sebastin  Javier Arístegui  María F. Montero  Jose Escanez  F. Xavier Niell 《Progress in Oceanography》2004,62(2-4):131

The enzymatic activity of alkaline phosphatase (APA) was studied in the transition zone between the African upwelling system and the open ocean waters of the Canary Islands region. This region is recurrently dominated by the presence of upwelling filaments that may transport nutrient-enriched waters out into the open ocean before nutrients become exhausted by plankton. Turnover rates by APA were generally low in the whole region, but detectable in all the measurements carried out. On average, turnover rates were higher in the upwelling stations, and APA in those waters seemed to be mainly generated by heterotrophic bacteria to supply easily assimilable organic C. APA outside the upwelling area showed an inverse hyperbolic relationship with increasing phosphate, suggesting the presence of both constitutive and Pi-inducible APA. In these offshore waters, a threshold of 0.1 μM of phosphate could be defined for the regulatory function of Pi on APA. Thus, APA in nutrient-poor waters seemed to be induced to compensate for Pi-deficiency. Turnover rates in the filaments showed basal (probably constitutive) levels, whereas they increased in the surrounding waters, where phosphate concentration presumably did not satisfy plankton P-demands. The fertilising effect of the filaments and associated cyclonic eddies extended to at least 175 km offshore, where basal alkaline phosphatase activities were still found. The magnitude of this effect depends probably on the intensity of upwelling events and the degree of recirculation of filament water back to the coastal jet.  相似文献   

A comparative mineralogical study of gas-related sediments of the Gulf of Cádiz     

C. Martín-Puertas  M. P. Mata  M. C. Fernández-Puga  V. Díaz del Río  J. T. Vázquez  L. Somoza 《Geo-Marine Letters》2007,27(2-4):223-235

The Gulf of Cádiz area has been extensively surveyed in recent years and several gas-related fluid escape seafloor structures have been identified. In this study, gravity cores, collected during the ANASTASYA/00 and ANASTASYA/01 cruises, on mud volcanoes, hemipelagic sediments and dredged material from diapiric structures, have been studied. A comparative mineralogical analysis by XRD and SEM of samples from different areas has been performed in order to determine whether there is a characteristic mineralogy related to these fluid escape structures, and also to determine the origin of the mud matrix and constrain the depth of the parent units. The mineralogical analysis reflects the different origins of the different units described in the cores: hemipelagic material of the slope, clays that underlie the mud volcanoes and are discharged at the sea bottom surface, and authigenic and diagenetic minerals possibly involved in the anaerobic oxidation of methane in the mud volcano sediments.  相似文献   

Distribution and transport of organic matter along a filament-eddy system in the Canaries – NW Africa coastal transition zone region     

Mercedes García-Muoz  Javier Arístegui  María F. Montero  Eric D. Barton 《Progress in Oceanography》2004,62(2-4):115

The distribution and transport of chlorophyll a (Chla), particulate (POC) and dissolved (DOC) organic carbon, and the respiratory ETS activity of the microplankton community were studied along a filament-eddy system located in the transition zone between the NW Africa upwelling and Canary Islands waters. Two independent filaments (F1 and F2) stemming from the coastal jet, between Cape Juby and Cape Bojador, merged about 100 km offshore, turning southward and onshore forced by the circulation of a recurrent oceanic cyclonic eddy. In general, the coastal upwelling waters presented higher Chla, but lower POC, DOC and ETS activity than filament waters. However, differences in organic carbon distribution and respiratory activity were observed among stations from the two filaments. The bio-chemical fields were strongly influenced by a complex sub-mesoscale hydrography resulting from the interaction of cyclonic and anticyclonic island eddies with the filaments. The combined F1 + F2 filament system transported 97.1 kg s⁻¹ of excess (non-refractory) total organic carbon (e-TOC), a value comparable to other published estimates from upwelling filaments in the NE Atlantic. About 90% of e-TOC was exported as DOC, since eddy re-circulation precluded the offshore transport of POC. Assuming that the calculated transport of e-TOC is representative of the annual average, the yearly offshore transport (3.1 x 10⁹ kg C) would represent about 25% of the upwelling primary production of the region of study.  相似文献