Leaching of lead metallurgical slags and pollutant mobility far from equilibrium conditions     

Nicolas Seignez  Arnaud Gauthier  David Bulteel  Denis Damidot  Jean-Luc Potdevin 《Applied Geochemistry》2008,23(12):3699-3711

Lead metallurgical slags are partially vitrified materials containing residual amounts of Zn, Pb, Cr, Cd and As. These hazardous materials are generally buried on heaps exposed to weathering. In this study, leaching behavior of lead blast furnace slags has been tested using pure water and open flow experiments. It appears that in such far from equilibrium and slightly acidic conditions, the main phase to be altered is the vitreous phase. As for lunar, basaltic and nuclear glasses, alkalis/proton exchanges prevail and lead to the formation of a non-protective altered layer enriched in Si, Fe and Al. The composition of the altered layer is quite constant except for Si whose concentration decreases towards the leachate interface. Owing to their sizes, micrometric Pb droplets are not always totally dissolved at the slag surface. Nevertheless, nanometric Pb droplets are instantaneously dissolved while a surrounding altered layer is formed. This leads to high Pb releases in open flow systems. Leachate chemistry and dissolution rates of the vitreous phase are closely comparable to previous leaching tests with basaltic and nuclear glasses in conditions far from equilibrium. Moreover, this study confirms that Fe is a stable element in such conditions.  相似文献   

Selenium distribution in the Rhône delta and the Gulf of Lions     

Dao Ming Guan  Jean-Marie Martin 《Marine Chemistry》1991,36(1-4)

Total dissolved selenium and selenium species have been measured in the Rhône river delta and the Gulf of Lions within the framework of the EROS-2000 project. The Rhône river concentration of total selenium averages 2.30 nM with important variations related to river discharge. During estuar-ine mixing, the concentrations of total dissolved selenium, selenite and selenate (calculated as the difference between total dissolved and selenite) decrease linearly with increasing salinity, without significant interconversion between selenium species. In the open Mediterranean waters of the Gulf of Lions the total dissolved selenium increases from 0.5 nM in the surface waters to 0.9 nM in the deep waters. Organic selenium has been observed in Mediterranean deep water, an observation which is different from those from the Atlantic and the Pacific Oceans. The distributions of total inorganic selenium (Σ5e), selenite and selenate are strongly related to phosphate and silicate concentrations as observed previously for the major oceans.  相似文献   

Prolonged Magmatic and Tectonic Development of the Caribbean Igneous Province Revealed by a Diving Submersible Survey     

Mauffret  Alain  Leroy  Sylvie  Vila  Jean-Marie  Hallot  Erwan  Mercier de Lépinay  Bernard  Duncan  Robert A. 《Marine Geophysical Researches》2001,22(1):17-45

Using the diving submersible survey NAUTICA we investigated the central part of the Caribbean large igneous province (CLIP) to observe and sample internal portions of this proposed oceanic plateau. Most of the samples are gabbroic and doleritic rocks; basalts are scarce. Radiometric dating by ⁴⁰Ar/³⁹Ar incremental heating experiments indicate that the intrusive rocks are Campanian in age (81–75 Ma). In some places these intrusive rocks underlie older Santonian (85–83 Ma) extrusive basaltic rocks, suggesting that the Campanian rocks represent a sill injection and an underplating episode. Results of the diving program supplemented by information from ODP and DSDP drilling sites document a 20 m.y. period (94–75 Ma) of igneous activity in the submerged portion of the Caribbean large igneous province (CLIP). In the northern part of the Beata Ridge late Campanian and/or post Campanian uplift is documented by prominent Maastrichtian (71–65 Ma) erosion and the establishment of a Paleocene-middle Eocene (65–49 Ma) carbonate platform. During and after the uplift an extensional period is indicated by seismic images and the subsidence (3 km depth) of the carbonate platform. Paleocene ages (55–56 Ma) determined on some volcanic samples are attributed to localised decompression mantle melting that accompanied the extension. We document a prolonged period of magmatic and tectonic events that do not fit with the current models of short-lived plateau formation during mantle plume initiation but shares many similarities with the constructional histories of other oceanic large igneous provinces.  相似文献   

Active spreading and hydrothermalism in North Fiji Basin (SW Pacific). Results of Japanese French Cruise Kaiyo 87     

Jean-Marie Auzende  Eiichi Honza  Xavier Boespflug  Satendra Deo  Jean-Philippe Eissen  Jun Hashimoto  Philippe Huchon  Junichiro Ishibashi  Yo Iwabuchi  Philip Jarvis  Masato Joshima  Kiyoyuki Kisimoto  Yasuto Kuwahara  Yves Lafoy  Tsuyoshi Matsumoto  Jean-Pierre Maze  Kiyohiko Mitsuzawa  Hiroyasu Monma  Takeshi Naganuma  Yukihiro Nojiri  Suguru Ohta  Kiyoshi Otsuka  Yoshihisa Okuda  Hélène Ondreas  Akira Otsuki  Etienne Ruellan  Myriam Sibuet  Manabu Tanahashi  Takeo Tanaka  Tetsuro Urabe 《Marine Geophysical Researches》1990,12(4):269-283

The aim of the Japanese-French Kaiyo 87 cruise was the study of the spreading axis in the North Fiji Basin (SW Pacific). A Seabeam and geophysical survey allowed us to define the detailed structure of the active NS spreading axis between 16° and 22° S and its relationships with the left lateral motion of the North Fiji Fracture Zone. Between 21° S and 18°10′ S, the spreading axis trends NS. From 18°10 S to 16°40 S the orientation of the spreading axis changes from NS to 015°. North of 16°40′ S the spreading axis trends 160°. These two 015° and 160° branches converge with the left lateral North Fiji fracture zone around 16°40′ S to define an RRFZ triple junction. Water sampling, dredging and photo TV deep towing give new information concerning the hydrothermal activity along the spreading axis. The discovery of hydrothermal deposits associated with living communities confirms this activity.  相似文献   

Une approche innovante pour modéliser la biodégradation des composés organochlorés volatils en aquifères poreux     

Fabien Nex  Gerhard Schäfer  Jean-Marie Côme  Timothy M. Vogel 《Comptes Rendus Geoscience》2006,338(5):297-306

The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006).  相似文献   

Determination of Pb/Pb ages on zircon and monazite by laser-ablation ICPMS and application to a study of sedimentary provenance and metamorphism in southeastern Brazil     

N. Machado  G. Gauthier 《Geochimica et cosmochimica acta》1996,60(24):5063-5073

The recently developed method of laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) allows the determination of ²⁰⁷Pb/²⁰⁶Pb ages of single zircon grains. The main advantages of the method are minimal sample preparation, low cost, and high throughput. In this work we present an analytical routine for geochronological analyses of zircon and monazite by LA-ICPMS and its application to the Ribeira Belt of the Brazilian Orogen in southeastern Brazil. The ²⁰⁷Pb/²⁰⁶Pb ages of one hundred and thirty-seven detrital zircons from amphibolite facies quartzites from three lithotectonic domains in the central Ribeira Belt indicate that they are derived mainly from Paleoproterozoic crust of Transamazonian age (2.0−2.3 Ga). A small number of zircons originated in 2.6−2.9 Ga Archean crust. These results are coherent with 2.1−2.2 Ga and 2.6−3.0 Ga U---Pb ages previously obtained for basement gneisses. The viability of the method to date monazite is also assessed. Monazites from the same quartzite samples yield ages between 2.1 Ga and 0.57 Ga. indicating variable resetting of the U---Pb system during amphibolite facies metamorphism. In contrast, monazite from a basement migmatite and syn-metamorphic granitoids yields ages in the 500–700 Ma range, in general agreement with U-Pb ages of 590-565 Ma for the main metamorphic event.

The LA-ICPMS ²⁰⁷Pb/²⁰⁶Pb ages are coherent and agree with expected results based on previous U---Pb geochronology, and show that the method has immediate applicability. At present, the most significant limitations of the method are the inability to yield reliable U/Pb values, analytical precision in the 1–10% range, and the requirement of grains larger than 80 gmm The method may be advantageous for provenance studies of Precambrian detrital sequences.  相似文献   

Particularités de la contamination crustale des phonolites : exemple du Velay oriental (Massif central)     

Jean-Marie Dautria  Jean-Michel Liotard  Danièle Briot 《Comptes Rendus Geoscience》2004,336(11):971-981

Sr and Nd isotopic compositions of one trachyte, eight phonolites and five basalts have been measured. The isotopic characteristics of the trachyte can be explained by a combined assimilation–fractional crystallization process within an upper crustal magmatic chamber. Some phonolites display isotopic signatures identical to basalts, suggesting that they have been protected against any crustal assimilation during their formation. Some others have low Sr contents, whereas they are enriched in radiogenic Sr (0.70451<⁸⁷Sr/⁸⁶Sr_i<0.71192), and display basaltic ¹⁴³Nd/¹⁴⁴Nd ratios. Both observations could be explained by very strong alkali feldspar fractionation and by subsequent very low assimilation of surrounding rocks (between 0.3 and 4%) during intrusion. To cite this article: J.-M. Dautria et al., C. R. Geoscience 336 (2004).  相似文献   

On core surface flows inferred from satellite magnetic data     

Céline Eymin  Gauthier Hulot 《Physics of the Earth and Planetary Interiors》2005,152(3):200-220

Satellite-data allows the magnetic field produced by the dynamo within the Earth’s core to be imaged with much more accuracy than previously possible with only ground-based data. Changes in this magnetic field can in turn be used to make some inferences about the core surface flow responsible for them. In this paper, we investigate the improvement brought to core flow computation by new satellite-data based core magnetic field models. It is shown that the main limitation now encountered is no longer the (now high) accuracy of those models, but the “non-modelled secular variation” produced by interaction of the non-resolvable small scales of the core flow with the core field, and by interaction of the (partly) resolvable large scales of the core flow with the small scales of the core field unfortunately masked by the crustal field. We show how this non-modelled secular variation can be taken into account to recover the largest scales of the core flow in a consistent way. We also investigate the uncertainties this introduces in core flows computed with the help of the frozen-flux and tangentially geostrophic assumptions. It turns out that flows with much more medium and small scales than previously thought are needed to explain the satellite-data-based core magnetic field models. It also turns out that a significant fraction of this flow unfortunately happens to be non-recoverable (being either “non-resolvable” because too small-scale, or “invisible”, because in the kernel of the inverse method) even though it produces the detectable “non-modelled secular variation”. Applying this to the Magsat (1980) to Ørsted (2000) field changes leads us to conclude that a flow involving at least strong retrograde vortices below the Atlantic Hemisphere, some less-resolved prograde vortices below the Pacific Hemisphere, and some poorly resolved (and partly non-resolvable) polar vortices, is needed to explain the 1980-2000 satellite-era average secular variation. The characteristics of the fraction of the secular variation left unexplained by this flow are also discussed.  相似文献   

Mise au point d'un milieu de culture pour l'étude de l'altération de silicates en présence de Pseudomonas aeruginosa     

Georges Aouad  Valérie Geoffroy  Jean-Marie Meyer  Jean-Louis Crovisier  Denis Damidot  Peter Stille 《Comptes Rendus Geoscience》2005,337(15):1340-1347

The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).  相似文献   

On the effect of boundary conditions on the Canadian Regional Climate Model: use of process tendencies     

Kamel Chikhar  Pierre Gauthier 《Climate Dynamics》2015,45(9-10):2515-2526

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