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The aim of this review is to examine the present knowledge about water structure close to an interface or confined in porous spaces. First, the structure of liquid water is briefly described. Though its understanding remains incomplete, it appears that it is largely dominated by the hydrogen bond network and its dynamical evolution. The presence of any ‘foreign’ substance in water perturbs such a structure by changing at least locally the hydrogen bond network. For this reason, the presence of a solid interface significantly modifies the structure of the first adsorbed layers. Whatever the support, it is now clearly evidenced that structural perturbations are limited to distances lower than 10–15 Å from the interface. The nature, energetic heterogeneity and hydrophilicility/hydrophobicity of the solid surface influence the arrangement of water molecules. This surface organisation must definitely be considered when studying adsorption phenomena at the solid–aqueous solution interface. The relevance of such problems to geosciences is illustrated by a few situations in which water structure plays a prominent role. To cite this article: L.J. Michot et al., C. R. Geoscience 334 (2002) 611–631.  相似文献   
2.
In July 2013, a wildfire severely affected the western part of the island of Mallorca (Spain). During the first three post‐fire hydrological years, when the window of disturbance tends to be more open, the hydrological and sediment delivery processes and dynamics were assessed in a representative catchment intensively shaped by terracing that covered 37% of its surface area. A nested approach was applied with two gauging stations (covering 1.2 km2 and 4.8 km2) built in September 2013 that took continuous measurements of rainfall, water and sediment yield. Average suspended sediment concentration (1503 mg L?1) and the maximum peak (33 618 mg L?1) were two orders of magnitude higher than those obtained in non‐burned terraced catchments of Mallorca. This factor may be related to changes in soils and the massive incorporation of ash into the suspended sediment flux during the most extreme post‐fire event; 50 mm of rainfall in 15 min, reaching an erosivity of 2886 MJ mm ha?1 h?1. Moreover, hysteretic counter‐clockwise loops were predominant (60%), probably related to the increased sensitivity of the landscape after wildfire perturbation. Though the study period was average in terms of total annual precipitation (even higher in intensities), minimal runoff (2%) and low sediment yield (6.3 t km?2 y?1) illustrated how the intrinsic characteristics of the catchment, i.e. calcareous soils, terraces and the application of post‐fire measures, limited the hydrosedimentary response despite the wildfire impact. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
3.
By nature minerals are heterogeneous materials for many of their properties. These properties also vary according to composition and structure fluctuations, compared to definitions. Technical minerals are used in applications where their performances depend on intrinsic properties and processing conditions. It is possible to base rankings on simple criteria, allowing estimating the abilities of minerals for each utilisation. The research of the corresponding mechanisms concerns the molecular level. These questions are discussed for kaolins, raw materials for baked clays, talqueous materials and montmorillonites. To cite this article: J. Yvon et al., C. R. Geoscience 334 (2002) 717–730.  相似文献   
4.
Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), Hallimond tube flotation and microelectrophoresis have been utilized to investigate the reactions in the adsorption-abstraction of K-amylxanthate on finely ground galena. The mineral was ground in a laboratory stainless steel rod mill under controlled conditions (pH 4.0 and 7.0) using HCl as a pH regulator. X-ray photoelectron spectroscopic (XPS) studies have been carried out in order to characterize the surface oxidation products after grinding (weak amounts of Sn and PbS2O3). The two-stage adsorption process discovered in previous studies was confirmed. For low concentrations or submonolayer capacity, the layer is formed with 1:1 monocoordinated lead xanthate and dixanthogen. For higher values of surface coverage, it is composed of lead xanthate (stoichiometric at pH 7 and non-stoichiometric at pH 4), amyldixanthogen and amylcarbonate disulphide. In the second stage mainly dixanthogen is formed. This stage corresponds to complete flotation and to a sharp decrease in zeta potentials.  相似文献   
5.
In aqueous medium, solid surfaces are in general electrically charged. The induced electrical and chemical properties govern numerous phenomena, such as colloidal stability or transport of pollutants. Numerous industrial processes make use of these properties. The understanding of the underlying mechanisms at molecular level is of high importance in order to predict and master the behaviour of dispersed matter in the environment and in industrial processes. The present paper shows the evolution of theories and experimental methods, their recent developments and applications. To cite this article: F. Thomas et al., C. R. Geoscience 334 (2002) 633–648.  相似文献   
6.
An understanding of the sources of variation in the use of erosion plots and of their feasibility to meet the objectives of each specific research project is key to improving future field designs, selecting data for modelling purposes and furthering knowledge of soil erosion processes. Our own field experiences from ongoing research on soil erosion processes since 1989, have allowed us to detect several methodological problems that cause measurement variability. Here several examples are presented concerning: (i) differences in long‐term soil erosion data between open and closed plots; (ii) differences in soil loss derived from replica soil erosion plots; and (iii) differences in soil loss data derived from plots at a range of spatial scales. Closed plots are not the most suitable method for long‐term monitoring of soil erosion rates due to the risk of exhaustion of available material within the plot. The difference in time after which exhaustion occurs depends on the surface soil characteristics, the climatological conditions and the size of the plots. We detected four and seven years as ‘time to exhaustion’. Different results are frequently obtained between pairs of replica plots. Differences up to a factor of nine have been detected in total soil loss between replica plots due to different spatial patterns of surface components. Different constraints appear depending on the spatial scale of measurement of soil loss. We obtained lower runoff percentages at coarser scales; however, larger sediment concentrations are observed at coarser scales (1·32 g l?1, catchment; 0·30 g l?1, 30 m2; 0·17 g l?1, 1 m2 scales). The smaller the plot, the larger the hydrological disconnection within the system, the lower the energy flows due to short distances and the quicker the response to runoff due to an artificial decrease of concentration times for continuous flow. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
7.
Surface hydrological behaviour is important in drylands because it affects the distribution of soil moisture and vegetation and the hydrological functioning of slopes and catchments. Microplot scale run‐off can be relatively easily measured, i.e. by rainfall simulations. However, slope or catchment run‐off cannot be deduced from microplots, requiring long‐time monitoring, because run‐off coefficients decrease with increasing drainage area. Therefore, to determine the slope length covered by run‐off (run‐off length) is crucial to connect scales. Biological soil crusts (BSCs) are good model systems, and their hydrology at slope scale is insufficiently known. This study provides run‐off lengths from BSCs, by field factorial experiments using rainfall simulation, including two BSC types, three rain types, three antecedent soil moistures and four plot lengths. Data were analysed by generalized linear modelling, including vascular plant cover as covariates. Results were the following: (i) the real contributing area is almost always much smaller than the topographical contributing area; (ii) the BSC type is key to controlling run‐off; run‐off length reached 3 m on cyanobacterial crust, but hardly over 1 m on lichen crust; this pattern remained through rain type or soil moisture; (iii) run‐off decreased with BSC development because soil sealing disappears; porosity, biomass and roughness increase and some changes occur in the uppermost soil layer; and (iv) run‐off flow increased with both rain type and soil moisture but run‐off coefficient only with soil moisture (as larger rains increased both run‐off and infiltration); vascular plant cover had a slight effect on run‐off because it was low and random. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
8.
This introductory paper aims at presenting the series of articles in this special issue of Comptes Rendus Geoscience devoted to the study and use of natural minerals. The research methodology that can be applied to the investigation of surface phenomena related to adsorption, exchange and retention onto the surface of natural minerals and divided solids is presented. A special focus is given to the retention of surfactant molecules, in view of their considerable importance in numerous industrial fields, such as, for instance, mineral flotation and enhanced oil recovery. Throughout this introductory paper, the relevance of this research approach to the field of geosciences is stressed by listing various applications where it can provide conclusive answers, especially for environmentally related issues. To cite this article: J.-M. Cases, C. R. Geoscience 334 (2002) 585–596.  相似文献   
9.
The adsorption of surfactants from aqueous solution is a phenomenon of major importance in applications ranging from ore flotation and paint technology to enhanced oil recovery. As this paper will illustrate, the process is very complex and of high scientific interest; its results can be extended to the retention of organic compounds (humic and fulvic acids, pollutants...) on solids in the biosphere. For a good understanding of the mechanisms involved in surfactants adsorption at the hydrophilic solid–aqueous solution interface, thermodynamic models have to take into account: (i) the physical chemistry of the surfactant in aqueous solution for choosing the appropriate reference phase, (ii) the surface heterogeneity of the adsorbing solid, (iii) the intensity of normal adsorbate–adsorbent bonds responsible for adsorption, (iv) the intensity of lateral bonds that favour the formation of surface aggregates through cooperative process and finally, (v) suitable theoretical models to describe adsorption phenomena. Once this has been achieved, two systems can be discussed: systems characterised by strong normal adsorbate–adsorbent bonds, currently used in ore flotation, which lead, in the case of heterogeneous surfaces, to the formation of lamellar aggregates at monolayer concentration and bilayer formation for higher concentrations. Systems characterised by weak normal adsorbate–adsorbent bonds, currently used in enhanced oil recovery and hydrocarbon (bio)remediation, which correspond to: (i) formation of globular micelles at the solid surface near the CMC when the temperature is higher than the Krafft point, (ii) formation of bilayered lamellar aggregates in the opposite case, (iii) three-dimensional condensation on substrate (T<TKrafft) if the ionic surfactant interacts with cations in the bulk. To cite this article: J.-M. Cases et al., C. R. Geoscience 334 (2002) 675–688.  相似文献   
10.
The precise study of adsorption mechanisms at solid–liquid interfaces requires a good analysis of the surface heterogeneity of the studied solids. For that purpose, molecular probe technique is one of the most powerful, especially at solid–gas interfaces. Indeed, low-pressure gas adsorption coupled to modelling of derivative adsorption isotherms as a function of logarithm of pressure allows to study qualitatively and quantitatively the effect of surface heterogeneity on the energy distribution of adsorption centres. The present review points out the interests of that approach to determine the shape of particles, the presence of high-energy adsorption sites and the surface polarity. Results comparing adsorption at solid–gas and solid–liquid interfaces are also mentioned. To cite this article: F. Villiéras et al., C. R. Geoscience 334 (2002) 597–609.  相似文献   
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