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One major difficulty in geology is high-resolution correlation among widely separated sections, especially in the Paleozoic where magnetostratigraphy polarity is not well established because rocks are often remagnetized, where critical biostratigraphic zonation may be poor or lacking, or where structural complexities make correlations very difficult. To address this problem, we have been using magnetostratigraphy susceptibility measurements. Here, we report our work from the Middle Devonian in Europe and North Africa. The Middle Devonian (Emsian–Eifelian) global boundary stratotype section and point (GSSP), located in the Eifel Hills, western Germany, was ratified by the International Subcommission on Stratigraphy in 1985, after careful evaluation of the biostratigraphy for this and many other sections. The boundary interval has been characterized using biostratigraphy, and the beginning of the Eifelian stage has been specifically defined by the first occurrence of the conodont Polygnathus costatus partitus. We have collected the Eifel Hills section for magnetic susceptibility (MS) measurement and here we establish it as the magnetostratotype for the Emsian–Eifelian stage boundary, by formally defining the magnetostratigraphy susceptibility for the section. We then collected, measured and compared the magnetostratotype to four other sections for which conodont biostratigraphy has been studied and where P. costatus partitus is present; two Emsian–Eifelian sections in Morocco and two sections in the Czech Republic (including the Emsian–Eifelian parastratotype). Finally, we have measured the MS for the El Puerto Creek section in the Cantabrian Mountains of Spain and identified the location of the Emsian–Eifelian boundary within the section based on MS comparison to the GSSP in conjunction with excellent biostratigraphic indicators, primarily brachiopods. While the conodont zonation in the El Puerto Creek section is poorly defined, we believe that the correspondence between the MS and biostratigraphy in the section allows the identification of the Emsian–Eifelian boundary. These results indicate that this method can be successfully applied to marine sequences where ambiguities in correlation exist.  相似文献   
2.
We report new data on the trace element concentrations of Mg, Cr, Mn, Co, Ni, Cu, Zn, Sr, Cd, Ba, La, Ce, Nd, Pb and U in USGS carbonate reference materials (MACS-1 and MACS-2) and compare solution ICP-MS and LA-ICP-MS trace element determinations on landfill calcites using calibration to different reference materials (MACS-1 and MACS-2 carbonate and NIST SRM 612 glass). Very good agreement (differences below 10% relative) was found between laser ablation and solution ICP-MS data for MACS-1 with higher concentrations of trace elements (values between 100 and 150 μg g−1), with the exception of Cu and Zn. Similarly good agreement was found for MACS-2 with lower trace element concentrations (units to tens of μg g−1), with the exception of Cr, Co and Zn. The MACS-1 reference material for calibration of LA-ICP-MS was found to be extremely useful for in situ determination of trace elements in real-world carbonate samples (landfill calcites), especially those present in calcite in higher concentrations (Mn, Sr, Ba; < 5% RSD). Less accurate determinations were generally obtained for trace elements present at low concentrations (∼ units of μg g−1). In addition, good agreement was observed between the instrument calibration to MACS and NIST SRM 612 glass for in situ measurements of trace elements in landfill calcites K-2, K-3 and K-4 (differences below 15% relative for most elements). Thus, the application of MACS carbonate reference materials is promising and points to the need for the development of new carbonate reference materials for laser ablation ICP-MS.  相似文献   
3.
This paper examines soil temperature (Ts) in two different plantation forests relative to an adjacent open land area in a tropical highland environment. To achieve the objectives, Ts in a Juniperus procera (JP) plantation, a Grevillea robusta (GR) plantation, and in the adjacent open land (OL) area were measured. One-way ANOVA and Pearson’s correlation were used for the data analysis. The result indicated that the mean daily Ts in the OL area at 10-cm depth of the soil was greater than the mean daily Ts recorded in the JP and GR plantations by 5 °C and 6 °C, respectively. The OL area Ts recorded at different soil depths (10 cm and 20 cm) was significantly different (p < 0.05). Rainfall (RF) and air temperature (Ta) of the study area have a direct relationship with the Ts in the plantation forests. The RF and Ta do not have a significant relationship with the Ts in the OL area at 10-cm soil depth. Overall, the study indicated that the Ts in the open land area was highly fluctuating monotonically, while it is relatively constant in the plantation forests.  相似文献   
4.
Relatively rich conodont faunas from sections in the Prague Synform (Barrandian area, Czech Republic) include a number of indexes and other important guide conodonts that can be correlated with other regions, especially with Nevada and the Spanish Central Pyrenees. The collation and detailed correlation of conodont data from the Lochkovian in two parallel sections in the Požáry quarries, together with biostratigraphic control of additional data from several (incomplete) sections with changing facies development, is the basis for a new detailed regional biozonal scale for the Lochkovian in the Prague Synform. The new subdivision follows, with modification, the global threefold conodont subdivision of the Lochkovian. Data from the Prague Synform enable further detailed subdivision of the lower, middle and upper Lochkovian into small‐scale units. The conodont distribution shows a large proportional discrepancy between the late Lochkovian elsewhere; the conodont record in the latest Lochkovian in the Prague Synform area, which appears to be rather restricted and requires further discussion. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
5.
Occurrences and distribution of extremely scarce eognathodontids do not facilitate reliable correlation across the European regions. The correlation of the traditional early Pragian of the Prague Synform (a part of the classical Barrandian area) and the Spanish Central Pyrenees (section Segre 1) is based on conodont taxa of the Icriodus steinachensis and the Pelekysgnathus serratus stocks. This correlation has the potential to be extended to other peri‐Gondwanan regions where this scarcity of eognathodontid faunas exists as well. Application of the morphotype subdivision in I. steinachensis enables approximation of the beginning of the Pragian in the Pyrenees. It is based on the entry of I. steinachensis beta morphotype; it enters together with early eognathodontid taxa in the Barrandian sections. These correlations show that routine application of certain zonal concepts can lead to misleading conclusions. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
6.
The Lugiin Gol nepheline syenite intrusion, Mongolia, hosts a range of carbonatite dikes mineralized in rare-earth elements(REE). Both carbonatites and nepheline syenite-fluorite-calcite veinlets are host to a previously unreported macroscale texture involving pseudo-graphic intergrowths of fluorite and calcite. The inclusions within calcite occur as either pure fluorite, with associated REE minerals within the surrounding calcite, or as mixed calcite-fluorite inclusions, with associated zirconosilicate minerals. Consideration of the nature of the texture, and the proportions of fluorite and calcite present(~29 and 71 mol%,respectively), indicates that these textures most likely formed either through the immiscible separation of carbonate and fluoride melts, or from cotectic crystallization of a carbonatefluoride melt. Laser ablation ICP-MS analyses show the pure fluorite inclusions to be depleted in REE relative to the calcite. A model is proposed, in which a carbonate-fluoride melt phase enriched in Zr and the REE, separated from a phonolitic melt, and then either unmixed or underwent cotectic crystallization to generate an REE-rich carbonate melt and an REE-poor fluoride phase. The separation of the fluoride phase(either solid or melt) may have contributed to the enrichment of the carbonate melt in REE, and ultimately its saturation with REE minerals. Previous data have suggested that carbonate melts separated from silicate melts are relatively depleted in the REE, and thus melt immiscibility cannot result in the formation of REE-enriched carbonatites. The observations presented here provide a mechanism by which this could occur, as under either model the textures imply initial separation of a mixed carbonate-fluoride melt from a silicate magma. The separation of an REEenriched carbonate-fluoride melt from phonolitic magma is a hitherto unrecognized mechanism for REE-enrichment in carbonatites, and may play an important role in the formation of shallow magmatic REE deposits.  相似文献   
7.
Mineral dust and other constituents of Devonian atmospheric aerosols together with certain amounts of aquatic suspensions of riverine detrital origin, colloidal particle dispersions and seawater solutes were embedded in ~95–98% (or purer) limestones on a consistently subsiding isolated carbonate platform where they formed very complex impurity systems. Very low Th/U values, relative abundance of Fe but a slight excess of K typically characterize these ultrafine impurities which are mineralogically dominated by smectite–illite and mica (sericite) together with goethite. In vertical section, these impurities are arranged like incremental series of light and dense bands. The combined method of natural gamma-ray spectrometric and magnetic susceptibility measurements (GRS–MS) together with background of major and trace element analyses provided first systematic insights into fine-scale variability of these impurities in a pile of pure carbonate platform beds, mostly in inner platform Amphipora limestone facies. These carbonates were deposited close to sea level but far from river mouths, and they represented a certain sort of a relatively “independent” medium that was primarily sensitive to climatically (and by rare events) controlled input of atmospheric dust. A remarkable similarity of MS stratigraphic patterns that reflect the quantity and quality of embedded impurities in very distant and paleogeographically separated Devonian basins might be seen as supporting this viewpoint. A long composite stratigraphic section of the Moravian Karst ranges from mid-Eifelian to end-Frasnian levels and yields a number of time characterizing GRS–MS variations that can potentially serve as templates for high-resolution stratigraphic correlations over long distances.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献   
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