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Transient mid-Cretaceous thermal uplift induced by lateral heating from passing oceanic lithosphere is often invoked as a mechanism for the formation of the Côte d'Ivoire–Ghana basement ridge in the Equatorial Atlantic. This heating event should have affected mid-Cretaceous sedimentary rocks along the ridge. However, organic maturity and clay mineral data on the thermal evolution of these rocks suggest that burial temperatures did not exceed 80 °C and that palaeo–geothermal gradients are not anomalous. Optical petrography and the stratigraphic pattern of temperature-sensitive parameters indicate that higher palaeotemperature estimates are related to admixtures of preheated, detrital organic and inorganic matter. Erosion brought the sediments to their present shallow burial depths. Lack of evidence for significant thermal alteration implies that either thermal exchange between oceanic and continental lithosphere along the Côte d'Ivoire–Ghana Transform Margin was negligible, or that lateral heating by oceanic lithosphere was not strong enough to affect the sedimentary cover of the basement ridge.  相似文献   
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In natural weathering systems, both the chemistry and the topography of mineral surfaces change as rocks and minerals equilibrate to surface conditions. Most geochemical research has focused on changes in solution chemistry over time; however, temporal changes in surface topography may also yield information about rates and mechanisms of dissolution. We use stochastic dissolution simulations of a regular 2-D lattice with reaction mechanisms defined in terms of nearest neighbor interactions to elucidate how the surface area and reactivity of a crystal evolve during dissolution. Despite the simplicity of the model, it reproduces key features observed or inferred for mineral dissolution. Our model results indicate that: (i) dissolving surfaces reach a steady-state conformation after sufficient dissolution time, (ii) linear defects cause surface area and dissolution rate to vary in concert with one another, (iii) sigmoidal and non-sigmoidal rate vs. free-energy of reaction (ΔGrxn) behavior can be rationalized in terms of the multiple steps occurring during dissolution, and (iv) surface roughness as a function of ΔGrxn is highly sensitive to the reaction mechanism. When simulated times to reach steady-state are compared to published time series rate data using suitable scaling, good agreement is found for silicate minerals while the model significantly over-predicts the duration of the transient for Fe and Al oxides. The implication of our simple model is that many aspects of mineral dissolution behavior, including approach to steady-state, sigmoidal vs. non-sigmoidal rate vs. ΔGrxn behavior, and development of rougher surfaces in conditions further from equilibrium can be explained by nearest neighbor interactions and simple Kossel-type models where reactivity of a surface is defined in terms of perfect surface, step, and kink sites.  相似文献   
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Killifish (Fundulus heteroclitus) from a highly contaminated site on the Elizabeth River are resistant to the acute toxicity and the cytochrome P4501A (CYP1A)-inducing activity of both the sediments from the site and chemically pure polycyclic aromatic hydrocarbons (PAHs). These effects are highly heritable for one generation, but heritable to a lesser degree by subsequent generations, in clean conditions in the laboratory. We show that offspring of this population of Elizabeth River killifish are also resistant to the teratogenicity and P4501A-inducing activity of PCB congener 126, a prototypical coplanar halogenated aromatic hydrocarbon (HAH). Furthermore, the pattern of greater resistance to acute toxicity and P4501A-inducing activity in the first generation and less in subsequent generations is also observed upon exposure to PCB-126.  相似文献   
6.
T Wagner  R Henrich 《Marine Geology》1994,120(3-4):335-364
Based on a multiparameter approach a combined litho- and organofacies concept was developed for glacial and interglacial sediment sections along an E-W transect through the central part of the Norwegian-Greenland Sea (NGS).

Modern and past surface water regimes are clearly displayed by specific litho- and organofacies patterns. Interglacial conditions reveal specific Atlantic water associated lithofacies (A and B3) in the eastern and central sector of the Norwegian-Greenland Sea (NGS). Corresponding interglacial organofacies in general are not well correlated to lithofacies due to strong diagenetic degradation of labile, e.g. autochthonous organic matter (OM). While in near-surface sediments a marine-dominated organofacies (I-1) is preserved under Atlantic water masses, this correlation is not evident for lower Holocene and Isotope Stage 5 deposits. However, during Isotopic Event 5.5.1 increased proportions of marine OM are recorded in a high accumulating core on the Vøring Plateau. Glaciomarine background lithofacies (B and C) indicate minor input of ice rafted debris (IRD) and seasonal variable sea-ice cover. Corresponding organofacies (II-1, non-oxidized and II-2, oxidized) are dominated by allochthonous OM. Most spectacular are glacial diamictons (Lithofacies E and F) evidencing short-term sediment pulses due to a sudden disintegration of far advanced tide water ice margins on the outer shelves. These diamictons bear specific organofacies (III-1 and III-2) with a clear predominance of terrigenous and reworked OM.

Some of the diamictons seem to occur contemporaneous with the so called “Heinrich-layers” H1 and H2, suggesting a common trigger-mechanism for the almost simultaneous disintegration of huge continental ice masses along the shelves of North America and the eastern margin of the NGS.

Application of a combined organo- and lithofacies concept provides essential information on spatial and temporal variations of water mass characteristics, the oceanic effects of ice sheet dynamics and circulation models.  相似文献   

7.
Late-Quaternary sections (about 1 Ma) from the Congo deep-sea fan (ODP Leg 175, site 1075) were used to reconstruct the terrigenous organic matter supply to the easternmost equatorial Atlantic Ocean. Variations in quantity and quality of the riverine organic matter reflect the interaction between the paleoclimatic development within the continental catchment area and the paleoceanographic conditions in the Congo river plume. To characterize the delivery of organic matter from terrigenous and marine sources, we used elemental and bulk carbon isotopic analyses, Rock-Eval pyrolysis, lignin chemistry, and organic petrology. High-amplitude fluctuations occurring about every 15-25 ka reveal a mainly precessional control on organic sedimentation. Results from Rock-Eval pyrolysis indicate a mixed kerogen type III/II, as would be anticipated in front of a major river. Fluctuations in Tmax from Rock-Eval pyrolysis demonstrate pronounced cyclic changes in the delivery of low- and high-mature organic matter. Contribution of the low-mature organic fraction was strongest during warm climates supporting enhanced marine production offshore of the Congo. Organic petrological observations confirm the existence of abundant terrigenous plant tissues, both non-oxidized (vitrinite) and oxidized (inertinite). Charcoal-like organic matter (fusinite) is attributed to periods of increased bush fires in the continental hinterland, and implies more arid climatic conditions. Results from ratios of specific phenolic lignin components suggest that terrigenous organic matter in Late-Quaternary sections of site 1075 mainly derives from non-woody angiosperm tissue, i.e., grasses and leaves. Correlation between the amount of specific lignin phenols and the bulk '13Corg signature fosters the conclusion that an appreciable amount of the terrigenous organic fraction derives from C4 plant matter. This may cause an underestimation of the terrigenous proportion of bulk organic matter when assessments are based on bulk carbon isotopic signatures alone.  相似文献   
8.
The Jason-1 sea state bias (SSB) is analyzed in depth from the first year of GDR products. Compared to previous missions, this work benefits from two aspects of the empirical determination of the SSB from the altimetric data themselves. First, from a methodological point of view, a nonparametric technique (NP) has been developed and largely tested on TOPEX/Poseidon 1, GFO and Envisat data. The NP estimator has proven to be a useful tool in the SSB estimation, and it is now mature enough to be used for a refined analysis. On the other hand, the SSB can be extracted from three different data sets (crossovers, collinear data, and residuals) with different characteristics. It is then possible to cross calibrate various estimations of the SSB models and to determine the most accurate one. A systematic comparison is made between these different estimates for the Jason-1 altimeter. The collinear and crossover data sets yield very similar estimates despite their difference of spatial and temporal distributions. These SSB models assure consistency with the TOPEX mission when comparing Jason-1 and TOPEX residuals during the tandem phase. Thanks to the present work, the impact of the short wavelengths filtering on the SSB estimation is evidenced. More generally, our understanding of potential errors affecting the sea surface height and their impact onto the SSB estimation is also improved.  相似文献   
9.
Seagrasses are an important coastal habitat worldwide and are indicative of environmental health at the critical land–sea interface. In many parts of the world, seagrasses are not well known, although they provide crucial functions and values to the world's oceans and to human populations dwelling along the coast. Established in 2001, SeagrassNet, a monitoring program for seagrasses worldwide, uses a standardized protocol for detecting change in seagrass habitat to capture both seagrass parameters and environmental variables. SeagrassNet is designed to statistically detect change over a relatively short time frame (1–2 years) through quarterly monitoring of permanent plots. Currently, SeagrassNet operates in 18 countries at 48 sites; at each site, a permanent transect is established and a team of people from the area collects data which is sent to the SeagrassNet database for analysis. We present five case studies based on SeagrassNet data from across the Americas (two sites in the USA, one in Belize, and two in Brazil) which have a common theme of seagrass decline; the study represents a first latitudinal comparison across a hemisphere using a common methodology. In two cases, rapid loss of seagrass was related to eutrophication, in two cases losses related to climate change, and in one case, the loss is attributed to a complex trophic interaction resulting from the presence of a marine protected area. SeagrassNet results provide documentation of seagrass change over time and allow us to make scientifically supported statements about the status of seagrass habitat and the extent of need for management action.  相似文献   
10.
Boron, chloride, sulfate, δD, δ18O, and 3H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-3H tracers (i.e., boron, chloride, sulfate, δD, and δ18O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ18O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
Résumé Les concentrations en bore, chlorure, sulfate, δD, δ18O, et 3H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ18O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ18O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ18O, y 3H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son 3H (por ejemplo, boro, cloruros, sulfatos δD, y δ18O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ18O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.
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