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1.
We present a solid solution model, able to take into account short-range interactions up to the third nearest neighbor. This
model has been applied to illite/smectite mixed-layer clay minerals and tests the relative thermodynamic stability of each
illite/smectite stacking sequence. The non-ideal energy terms have been calculated, showing a strong decrease of the interaction
energy as the distance between elements grows. From ΔG
m calculations the model predicts the following succession in I/S stacking sequences as X
i
tends to 1:R1, R2 and then R3. This succession agrees well with some mineralogical observations in natural series.
Received: July 12, 1996 / Revised, accepted: March 21, 1997 相似文献
2.
Hydro-geochemistry of groundwater and surface water in Dschang town(West Cameroon): Alkali and alkaline-earth elements ascertain lithological and anthropogenic constraints 
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下载免费PDF全文 Yemeli Elida Joelle Temgoua Emile Kengni Lucas Ambrosi Jean-Paul Momo-nouazi Mathieu Silatsa-Tedou Francis Brice Wamba Franck Robean Tchakam-Kamtchueng Brice 《地下水科学与工程》2021,9(3):212-224
This study focuses on the sources of alkali and alkaline-earth elements based on the geochemistry of groundwater and surface water in Dschang concerning environmental and anthropogenic constraints. A comprehensive set of 50 samples from groundwater and surface water were analyzed by ICPMS and processed by spatial interpolation in a GIS environment. The results highlight a geochemical anomaly at the center of the densely inhabited area subject to a profusion of open dumps discharges. This anomaly with the highest spatial contents of Be(Cs, Rb, Mg) suggests an anthropogenic source that demarcates with the lowest alkali and alkaline-earth elements on the peripheral area of Dschang. Other findings include lithological constraints with volcanic rocks being the main source compared to granitoid.The study points out good correlations between Be, Cs, Rb and Mg spatial distributions and physicochemical parameters of waters(K, EC, TDS), and inversely with the lowest p H. p H is established as the most functioning physico-chemical constraint of alkali and alkaline-earth mobility in Dschang. The p H lowest values within the geochemical anomaly also highlight the impact of human activities on water acidity, which later enhance elements mobility and enrichment. Despite low elements contents relative to WHO standards, our findings point out an example of anthropogenic impact on water geochemistry linked to solid waste pollution; it also demonstrates significant anthropogenic changes of environmental physicochemical parameters of prime importance in the mobility and distribution of elements in the study area.Similar assessments should be extended in major towns in Cameroon. 相似文献
3.
Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in sediments from Hong Kong 总被引：4，自引：0，他引：4
Müller JF Gaus C Prange JA Päpke O Poon KF Lam MH Lam PK 《Marine pollution bulletin》2002,45(1-12):372-378
Concentrations of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in 14 sediment samples collected from four sites in the Mai Po Marshes Nature Reserve (within a RAMSAR Site) and from another six sites in Victoria Harbour and along the Hong Kong coastline. Elevated levels of PCDDs, and particularly OCDD, were detectable in all samples collected from the Mai Po Marshes and five of the six sites. In contrast to PCDDs, PCDFs were mainly found in sediment samples collected from industrial areas (Kwun Tong and To Kwa Wan) in Victoria Harbour. PCDD/F levels and congener profiles in the samples from the Mai Po Marshes Nature Reserve in particular show strong similarities to those reported in studies which have attributed similar elevated PCDD concentrations to nonanthropogenic PCDD sources. 相似文献
4.
Nowadays,the preservation of natural resources,the reuse,and the recycling of waste and by-products in the cement industry are gaining increasing attention in a sustainable development project.In this perspective,many studies focus on finding solutions in order to propose environmentally friendly materials.Nowadays the sediments represent a way to preserve the natural resources by their reuse as a secondary raw material in multiple applications(concrete,roads,landscaped mound,etc.).However,they commonly contain contaminants,organic matter(5%-30%),high water content(50%-200%),and relatively small particle size(Dmax≤300 mm).Therefore to improve the mechanical properties of this material as well as its physiochemical ones,specific methods of characterization and appropriate treatment techniques(calcination,chemical treatment,etc.)are required.This article presents a bibliographical review of the efficient use of sediments in cementitious matrix.It details experimental tests that must be performed to ensure the durability of sediment-based structure and assess their environmental impact under prescribed conditions. 相似文献
5.
Joelle E. Langford Robert A. Schincariol Ranjeet M. Nagare William L. Quinton Aaron A. Mohammed 《Ground water》2020,58(2):258-268
Permafrost covers approximately 24% of the Northern Hemisphere, and much of it is degrading, which causes infrastructure failures and ecosystem transitions. Understanding groundwater and heat flow processes in permafrost environments is challenging due to spatially and temporarily varying hydraulic connections between water above and below the near-surface discontinuous frozen zone. To characterize the transitional period of permafrost degradation, a three-dimensional model of a permafrost plateau that includes the supra-permafrost zone and surrounding wetlands was developed. The model is based on the Scotty Creek basin in the Northwest Territories, Canada. FEFLOW groundwater flow and heat transport modeling software is used in conjunction with the piFreeze plug-in, to account for phase changes between ice and water. The Simultaneous Heat and Water (SHAW) flow model is used to calculate ground temperatures and surface water balance, which are then used as FEFLOW boundary conditions. As simulating actual permafrost evolution would require hundreds of years of climate variations over an evolving landscape, whose geomorphic features are unknown, methodologies for developing permafrost initial conditions for transient simulations were investigated. It was found that a model initialized with a transient spin-up methodology, that includes an unfrozen layer between the permafrost table and ground surface, yields better results than with steady-state permafrost initial conditions. This study also demonstrates the critical role that variations in land surface and permafrost table microtopography, along with talik development, play in permafrost degradation. Modeling permafrost dynamics will allow for the testing of remedial measures to stabilize permafrost in high value infrastructure environments. 相似文献
6.
Nejib Abidi Joëlle Duplay Amane Jada Raymonde Baltenweck Emna Errais Khadija Semhi Malika Trabelsi-Ayadi 《Arabian Journal of Geosciences》2017,10(16):373
Clays, particularly kaolinite, are promising adsorbents for the treatment of textile effluents, but there is a need of better understanding the mechanisms of adsorption, especially in the case of anionic dyes. Thus, the removal of RR120 anionic dye was investigated using Tunisian raw clay (TBK) composed of kaolinite and illite, and a standard kaolinite (KGa-2), and conducting batch experiments by varying different parameters (contact time, ionic strength, concentration, temperature). We investigated the clays’ surface charges by electrophoretic mobility measures and the dye-clay interactions during adsorption, by the streaming-induced potentials (SIP). The results showed that KGa-2 has higher adsorption capacity for RR120 dye than TBK clay, moreover enhanced by increasing the ionic strength and/or lowering the pH of the aqueous. The SIP results showed an increase of negative charges for both clays, reflecting the adsorption of the anionic dye on the positive charges of the amphoteric surfaces of the clays. The SIP magnitudes indicated a higher adsorption rate for KGa-2 in accordance with the kinetic study. The Sips model that described the best adsorption isotherms indicates lateral interactions of the dye molecules, stronger in the case of KGa-2 than TBK. Also, the dye molecules form a thinner layer on KGa-2 surfaces. In addition, the dye molecule’s structure was not altered, as verified by mass spectrometry. The adsorption process was feasible and spontaneous and favored at ambient temperature. Thus, kaolinite-rich clays are effective in the removal of anionic dyes in aqueous solution and potential good adsorbents in wastewater treatment. 相似文献
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8.
William J. Sydeman Michelle M. Hester Julie A. Thayer Franklin Gress Paige Martin Joelle Buffa 《Progress in Oceanography》2001,49(1-4)
We studied the effects of low-frequency climate change on the reproductive performance of 11 species of marine bird in the southern California Current system, 1969–1997. Reproductive performance of Brown Pelican (Pelecanus occidentalis) and Double-crested Cormorant (Phalacrocrax auritus) in southern California demonstrated an increase in the 1970s and early 1980s, attributable to recovery from organochlorine contamination (primarily DDE). Brandt's Cormorant (Phalacrocorax penicillatus) in central California was the only species to demonstrate a secular increase in performance through time, a pattern that remains unexplained. Ashy Storm-petrel (Oceanodroma homochroa) and Pelagic Cormorant (Phalacrocorax pelagicus) demonstrated curvilinear patterns of change, with decreasing reproductive performance in the past decade. All other species including Western Gull (Larus occidentalis), Pigeon Guillemot (Cepphus columba), Xantus's Murrelet (Synthiloboramphus hypoleucus), Common Murre (Uria aalge), Cassin's Auklet (Ptychoramphus aleuticus) and Rhinoceros Auklet (Cerorhinca monocerata) showed diminishing reproductive performance through time. Patterns of change for the murre and auklets were not significant, presumably because of a lack of reproductive variation for these species, which display a conservative breeding effort (i.e. single-egg clutches). Changes in the birds' abilities to provision young and maintain chick survival during May–July each year appeared most closely related to overall changes in reproductive performance. Dietary change indicated a decline in use of juvenile rockfish (Sebastes spp.) by marine birds in central California. There was also significant interannual variability in consumption of juvenile rockfish and the euphausiid Thysanoessa spinifera. Patterns of change in marine bird reproductive performance were generally concordant between southern and central California after considering the period of recovery for Brown Pelican and Double-crested Cormorant. The decline in reproductive performance and changes in diet composition do not appear directly related to the polarity reversal of the Pacific Decadal Oscillation in 1976/1977. Instead, reproductive performance and dietary characteristics indicate substantial change in the late 1980s, suggesting another regime-shift at that time. 相似文献
9.
David Devreker Sami Souissi Juan Carlos Molinero Delphine Beyrend-Dur Fernando Gomez Joelle Forget-Leray 《Estuarine, Coastal and Shelf Science》2010
Annual variability in abundance and population structure of the copepod Eurytemora affinis was studied in the maximum turbidity zone of the Seine Estuary in 2005. An Eulerian sampling strategy was applied monthly from March to July and from September to December. Chlorophyll a and suspended particulate matter (SPM) concentration, copepod abundance and stage distribution, and phytoplankton abundance were measured in sub-surface and near-bottom water during the ebb phase. Total E. affinis abundance was at a maximum in March and April (>200 × 103 ind. m−3), and decreased from May to September (<25 × 103 ind. m−3). This decrease corresponds to annual increases in temperature, salinity, chlorophyll a concentration and phytoplankton abundance, which was dominated by large diatoms, and decreases in SPM and river discharge. The phenology observed in 2005 was almost two months earlier compared to previous studies in the 1990s, when E. affinis reached maximum abundance in May and June. The low proportion of nauplii (<50%) in the population and high abundance of ovigerous females suggests that low recruitment is probably related to anomalously low temperatures in late winter (<5 °C). Whatever the horizontal position of the population in the estuary, adult and late copepodid stages are distributed in higher salinity than naupliar stages. Overall E. affinis population abundance was driven by parameters that characterize water masses at the tidal scale and by river discharge and chlorophyll a at the annual scale. By integrating the tidal effect, the high-frequency sampling protocol used appears to be optimal for investigating annual variability of planktonic communities in megatidal estuaries. 相似文献
10.
A Tripole Index for the Interdecadal Pacific Oscillation 总被引：1，自引：0，他引：1
Benjamin J. Henley Joelle Gergis David J. Karoly Scott Power John Kennedy Chris K. Folland 《Climate Dynamics》2015,44(11-12):3077-3100