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Lead concentrations and isotopic composition have been measured in bone and teeth of small cetaceans belonging to three species (Delphinus delphis, Phocoena phocoena and Stenella coeruleoalba), to evaluate the toxicological risk and to determine sources of lead in the European waters. Lead concentrations, far lower than threshold value inducing toxic effects in human, were higher in teeth than in bones, but highly correlated between the two tissues (r=0.92, p<0.001). Large variations of 206Pb/207Pb values in bone tissue showed that cetaceans must be submitted to various atmospheric influences. No geographical differences appeared which is consistent with studies on their distribution indicating seasonal movements between Brittany waters and the Bay of Biscay. The negative correlation between 206Pb/207Pb ratios and age of the individuals reflected the decrease in the production of alkyl lead in Europe, i.e., the increasing use of unleaded gasoline.  相似文献   
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Conventional water treatments when downsized to cover the demands of small and scattered populations are costly and ineffective. In fact, many small towns cannot afford the high average treatment costs nor provide the skill and complex management requirements. Even when these facilities are available, waste water might not be properly treated. Land application system treatments (LAST) have been shown to be preferable on the basis of their technical effectiveness and financial viability. The recently approved Spanish regulations (RDL 1620/2007, pp 50369–50661) represent an opportunity for the implementation of well-designed LASTs. This paper presents an assessment methodology for the design of LASTs by combining technical, financial and location criteria. The method is applied to the design of LASTs to cover the water disposal demand of twelve municipalities located within the protected natural landscape, and surrounding areas of ‘El Rebollar’, Salamanca, Spain.  相似文献   
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In this paper, the two computer codes TOUGH2 and RDCA (for “rock discontinuous cellular automaton”) are integrated for coupled hydromechanical analysis of multiphase fluid flow and discontinuous mechanical behavior in heterogeneous rock. TOUGH2 is a well-established code for geohydrological analysis involving multiphase, multicomponent fluid flow and heat transport; RDCA is a numerical model developed for simulating the nonlinear and discontinuous geomechanical behavior of rock. The RDCA incorporates the discontinuity of a fracture independently of the mesh, such that the fracture can be arbitrarily located within an element, while the fluid pressure calculated by TOUGH2 can be conveniently applied to fracture surfaces. We verify and demonstrate the coupled TOUGH–RDCA simulator by modeling a number of simulation examples related to coupled multiphase flow and geomechanical processes associated with the deep geological storage of carbon dioxide—including modeling of ground surface uplift, stress-dependent permeability, and the coupled multiphase flow and geomechanical behavior of fractures intersecting the caprock.  相似文献   
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An upgraded version of the Eta model   总被引:2,自引:0,他引:2  
Upgrades implemented over a number of years in an open source version of the Eta model, posted at the CPTEC web site http://etamodel.cptec.inpe.br/, are summarized and examples of benefits are shown. The version originates from the NCEP’s Workstation Eta code posted on the NCEP web site http://www.emc.ncep.noaa.gov/mmb/wrkstn_eta, which differs from the NCEP’s latest operational Eta by having the WRF-NMM nonhydrostatic option included. Most of the upgrades made resulted from attention paid to less than satisfactory performance noted in several Eta results, and identification of the reasons for the problem. Others came from simple expectation that including a feature that is physically justified but is missing in the code should help. The most notable of the upgrades are the introduction of the so-called sloping steps, or discretized shaved cells topography; piecewise-linear finite-volume vertical advection of dynamic variables; vapor and hydrometeor loading in the hydrostatic equation, and changes aimed at refining the convection schemes available in the Eta. Several other modifications have to do with the calculation of exchange coefficients, conservation in the vertical diffusion, and diagnostic calculation of 10-m winds. Several examples showing improved performance resulting from the dynamics changes are given. One includes a case of unrealistically low temperatures in several mountain basins generated by a centered vertical advection difference scheme’s unphysical advection from below ground, removed by its replacement with a finite-volume scheme. Another is that of increased katabatic winds in the Terra Nova Bay Antarctica region. Successful forecast of the severe downslope zonda wind case in the lee of the highest peaks of the Andes is also shown, and some of the recent successful verification results of the use of the upgraded model are pointed out. The code is used at numerous places, and along with setup information it is available for outside users at the CPTEC Eta web site given above.  相似文献   
7.
Downscaling of South America present climate driven by 4-member HadCM3 runs   总被引:5,自引:2,他引:3  
The objective of this work is to evaluate climate simulations over South America using the regional Eta Model driven by four members of an ensemble of the UK Met Office Hadley Centre HadCM3 global model. The Eta Model has been modified with the purpose of performing long-term decadal integrations and has shown to reproduce “present climate”—the period 1961–1990—reasonably well when forced by HadCM3. The global model lateral conditions with a resolution of 2.5° latitude?×?3.75° longitude were provided at a frequency of 6?h. Each member of the global model ensemble has a different climate sensitivity, and the four members were selected to span the range of uncertainty encompassed by the ensemble. The Eta Model nested in the HadCM3 global model was configured with 40-km horizontal resolution and 38 layers in the vertical. No large-scale internal nudging was applied. Results are shown for austral summer and winter at present climate defined as 1961–90. The upper and low-level circulation patterns produced by the Eta-CPTEC/HadCM3 experiment set-up show good agreement with reanalysis data and the mean precipitation and temperature with CRU observation data. The spread in the downscaled mean precipitation and temperature is small when compared against model errors. On the other hand, the benefits in using an ensemble is clear in the improved representation of the seasonal cycle by the ensemble mean over any one realization. El Ni?o and La Ni?a years were identified in the HadCM3 member runs based on the NOAA Climate Prediction Center criterion of sea surface temperature anomalies in the Ni?o 3.4 area. The frequency of the El Ni?o and La Ni?a events in the studied period is underestimated by HadCM3. The precipitation and temperature anomalies typical of these events are reproduced by most of the Eta-CPTEC/HadCM3 ensemble, although small displacements of the positions of the anomalies occur. This experiment configuration is the first step on the implementation of Eta-CPTEC/HadCM3 upcoming experiments on climate change studies that are discussed in a companion paper.  相似文献   
8.
Fixed wavelength fluorescence (FF) for detection of polyaromatic hydrocarbon (PAH) metabolites in fish bile has been studied, and is presented through a laboratory and a field experiment. The method, which can be regarded as a biomarker of exposure to PAH, has proved to be a simple, rapid and cost effective method for monitoring PAH contamination.  相似文献   
9.
Physically based and spatially distributed modelling of catchment hydrology involves the estimation of block or whole-hillslope permeabilities. Invariably these estimates are derived by calibration against rainfall–runoff response. Rarely are these estimates rigorously compared with parameter measurements made at the small scale. This study uses a parametrically simple model, TOPMODEL, and an uncertainty framework to derive permeability at the catchment scale. The utility of expert knowledge of the internal catchment dynamics (i.e. extent of saturated area) in constraining parameter uncertainty is demonstrated. Model-derived estimates are then compared with core-based measurements of permeability appropriately up-scaled. The observed differences between the permeability estimates derived by the two methods might be attributed to the role of intermediate scale features (natural soil pipes). An alternative method of determining block permeabilities at the intermediate or hillslope scale is described. This method uses pulse-wave tests and explicitly incorporates the resultant effects of phenomena such as soil piping and kinematic wave migration. The study aims to highlight issues associated with parameterizing or validating distributed models, rather than to provide a definitive solution. The fact that the permeability distribution within the Borneo study catchment is comparatively simple, assists the comparisons. The field data were collected in terrain covered by equatorial rainforest. Combined field measurement and modelling programmes are rare within such environments. © 1998 John Wiley & Sons, Ltd.  相似文献   
10.
The characteristic biology and wide distribution of hagfish species makes them relevant for use in pollution biomonitoring at great water depths, particularly in regions where deep-water oil production may take place. The exposure of fish to petrogenic contaminants can normally be detected from the level of polycyclic aromatic hydrocarbon (PAH) metabolites in bile fluid. Some of these metabolites are strong fluorophores, allowing analytical detection by means of simple fluorometric techniques such as fixed wavelength fluorescence (FF) and synchronous fluorescence scanning (SFS). In the present study bile from Atlantic hagfish (Myxine glutinosa) collected in pristine areas (Barents Sea and southwestern Norway) displayed strong bile fluorescence levels, suggesting the presence of PAH contaminants. However, gas-chromatography-mass spectrometry (GC-MS) analyses ruled out PAHs as the origin for this fluorescence signal. Rather, the bile of Myxine contains components resulting in unusually strong background fluorescence interfering at the wavelength pairs used for detection of PAH metabolites. Possible background for the observed matrix interference and implications for detection of PAH metabolites in hagfish is discussed.  相似文献   
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