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Gold mining activities in Apolobamba area, northwest of La Paz, Bolivia have created serious environmental concern and great risk to human health. The current methods used to extract gold are too primitive resulting in metal contamination of soil and water. The objectives of this study were to: (1) determine the degree of metal pollution, and (2) assess the risk to human health and environment in the Apolobamba area. Soil, water, sediment samples, and mine spills were collected and analyzed. Metals including Pb, Cu, Zn, Cd, and Hg concentrations were higher in surface soils than in subsurface soils indicating active atmospheric deposition of metals. Sediment samples had elevated levels of metals probably from mine spills discharged into the Sunchulli River. Surface soils in the Sunchulli community show the highest levels of Pb and Hg in all soil samples and may pose a risk to the health of the human population and environment.  相似文献   
2.
“Stone runs” is the Falklands vernacular term for openwork boulder accumulations, which include extensive blockstreams like the famous Darwin “stone-river” and associated features such as stone stripes. Since the early 20th century, they have been interpreted as the product of a suite of periglacial processes, including frost-wedging, gelifluction, frost heave, frost-sorting and snowmelt runoff. Following a literature review, the results of recent field investigations of the valley-floor blockstreams of East Falkland are presented. Access to the internal structure of these forms provides evidence for the existence of a three-fold profile, with clear vertical size gradation presenting striking similarities with an inverted weathering profile. Micromorphological analyses, SEM, XRD, thin sections and grain-size analyses lead to the hypothesis of an alternative model of stone run formation. It is suggested that the material forming the stone run profile lato sensu (including the superficial pavement) is not of periglacial origin, but derives directly from the stripping and accumulation downslope of a regolith, possibly Tertiary in age and formed under subtropical or temperate conditions. The valley-floor stone runs should, therefore, be considered as complex polygenetic landforms that may have formed according to a six-stage scenario, including in situ chemical weathering, regolith stripping by mass movements, soil formation, further regolith stripping, downslope accumulation and matrix washing-out (all phases possibly achieved by the Early Quaternary). Periglacial reworking of the stone run material would have operated at a “final” stage, i.e. during Quaternary cold stages, with boulder bioweathering and limonite-staining operating during the temperate intervals including the present one. The suggested antiquity of the Falklands blockstreams is in accordance with Caine's pioneer interpretation of Tasmania blockfields and with recent analyses and cosmogenic datings of blockfields from Scandinavia and North America.  相似文献   
3.
Anatolia has long been a major pottery production center of the ancient world, dating back 7000 cal yr B.P. The Early Iron Age Urartu Kingdom (800–600 B.C.) of eastern Anatolia is known for the production of high‐quality pottery, but little is known regarding firing technology and manufacture of these ceramics. Here we present a preliminary study of Urartu ceramic micromorphology and chemistry and suggest that the Urartus had good knowledge of local geology and intentionally used chemical fluxes (Pb, Rb, and Li) to attain desired firing temperatures. The sophisticated production of Urartu ceramics is comparable to later high‐quality Roman pottery (terra sigillata) procured from the same area. © 2010 Wiley Periodicals, Inc.  相似文献   
4.
Minerals such as iron oxides and clays provide high tinting strength and improve the adhesive properties of pigments. In this study, we investigated the mineral composition of pigments from samples of San rock art. We used X‐ray diffraction and scanning electron microscopy to determine the mineral composition and micromorphology of pigments. Results showed that the major minerals in pigments in San rock art are whewellite, quartz, gypsum, hematite, and various alumino‐silicate minerals. The red hue in the pigment is due to hematite; gypsum and clays provide the white coloration, whereas black might be due to amorphous manganese compounds. We believe that whewellite with globular habit was extracted from plant sap (e.g., aloe vera) and added to the pigment, perhaps as binder, extender, or whitener. Whewellite with needle‐shaped morphology was present in cracks that developed in pigments and indicated an early stage of deterioration of the rock art. We propose that conservationists should seriously evaluate any change in the environmental conditions at the art site (e.g., removal of vegetation to improve touristic view) because such changes might significantly increase thermal fluctuations in pigments and promote crack formation and hence the decay of the San rock art. © 2008 Wiley Periodicals, Inc.  相似文献   
5.
Fragments of weathered granitic rocks from the Kunlun Shan, Qinghai Plateau (China) were investigated to elucidate the in?uence of biotic crusts on the breakdown of granitic rocks in an alpine environment. Scanning electron microscopy with energy dispersive system and X‐ray diffractometry were used to describe the nature and properties of mineral accumulations on the rock surface. Results showed that organic salts such as calcium oxalate and calcium formate are associated with Aspicilia caesiocinera (Nyl.ex Malbr.) Arnold, Caloplaca sp., Xanthoria elegans (Link) Th.Fr., and Lecidea plana (Lahm) Nyl. Secondary accumulations of 2 : 1 clays minerals are found in A. caesiocinera while oxides of manganese are associated with X. elegans. Coatings of goethite (iron oxides) are believed to form from biological activity associated with the presence of hyphae and rodlet structures on the ?akes. Calcium oxalate crystallizes into several morphologies such as druse, hexagonal plates, and lenticular containing between 20 and 48 per cent calcium by weight. Calcium formate and iron oxide (goethite) occur together in the form of ‘red’ desert varnish. Observed ‘black’ coatings contain as much as 37 per cent manganese and 22 per cent iron. Clay accumulations have plate‐like morphology and contain c. 2 : 1 silicon to aluminium contents. We argue that organic acids from the activities of biotic crusts contribute to the breakdown of granitic rocks. Fungi accelerate the breakdown of granitic rocks through the growth of fungal hyphae along the 001 cleavage planes in primary chloritic minerals. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
6.
Industrialization, urbanization, and agricultural practices are 3 of the most important sources of metal accumulations in soils. Concentrations of Cr, Mn, Ni, Cu, Pb, Zn and Cd were determined in surface soils collected under different land uses, including urban (UR), industrial (IN-1 and IN-2), agricultural (AG), abandoned unused (AB), and natural (NA) sites to examine the influence of anthropogenic activities on metals in soils formed in a typical Mediterranean environment. The highest concentrations of Cr, Cd, and Pb observed in the NW industrial area (IN-2) were 63.7, 3.34 and 2330 mg metal kg−1 soil, for each metal, respectively. The SW industrial area (IN-1) contained the highest Zn content at 135 mg kg−1. However, soils with the highest concentrations of Ni and Cu were located in AG sites at 30.9 and 64.9 mg kg−1 soil, respectively. Sampling locations with the highest concentrations of Mn were identified in AB sites. Using the concentrations of metals at the NA sites as the baseline levels, soils collected from all other land uses in the study area exhibited significantly higher total contents of Zn, Mn, Cr and Ni. Metal enrichment was attributed to fertilizer and pesticide applications, industrial activities, and metal deposition from a high volume of vehicular traffic (for Pb and Cd). High concentrations of Mn in some samples were attributed to parent materials. The study demonstrated that anthropogenic activities associated with various land uses contribute to metal accumulation in soils and indicated a need to closely monitor land management practices to reduce human and ecological risks from environmental pollution.  相似文献   
7.
In respect to the weathering of cave art exposed to the sun, cognizance has yet to be taken of the modified thermal conditions and the potential for endolithic biotic activity where the art is located on a light‐transmissive lithology. Where light penetrates rock, the light‐to‐heat transfer is not solely at the surface, and this leads to a thermal gradient that is different from where the paintings are located (and all transfer is at the surface). Light values of up to 200 W/m2 were recorded at 0.5 mm depth and up to 100 W/m2 at 1mm depth in the dry sandstone; rock moisture data showed that at this site the rock remained dry irrespective of atmospheric conditions. The light penetration means that there can be rapid and large subsurface thermal fluctuations contemporaneous with those at the rock surface, and that the thermal gradient is not as steep (approximately 1°C/mm in the surficial part of the rock) as where light‐to‐heat transfer is solely at the surface. Further, the presence of subsurface photosynthetically active radiation can (potentially) facilitate colonization by endolithic organisms. Here, as part of a study of the weathering of San rock art on sandstone in southern Africa, a first attempt is made to monitor the extent of light penetration and the resulting thermal conditions in the outer few millimeters of the sandstone. © 2009 Wiley Periodicals, Inc.  相似文献   
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