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The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓmax2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.  相似文献   
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Electron velocity distribution functions (VDF) observed in the low speed solar wind flow are generally characterized by ‘core’ and ‘halo’ electrons. In the high speed solar wind, a third population of ‘strahl’ electrons is generally observed. New collisional models based on the solution of the Fokker-Planck equation can be used to determine the importance of the different electron populations as a function of the radial distance. Typical electron velocity distribution functions observed at 1 AU from the Sun are used as boundary conditions for the high speed solar wind and for the low speed solar wind. Taking into account the effects of external forces and Coulomb collisions with a background plasma, suprathermal tails are found to be present in the electron VDF at low altitudes in the corona when they exist at large radial distances. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
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We show how the Yarkovsky effect can be understood as a heat engine. The output of the engine, manifested in the rate of change in semimajor axis of the body, has a maximum at an intermediate heat capacity, depending on the rotation rate of the body. This maximum arises because the work output depends on the product of the solar heat absorbed by the body and transported from its morning to evening side (this am-pm heat flux increases with heat capacity) and the Carnot efficiency (which declines with heat capacity).  相似文献   
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This paper considers the problem of estimatingm, the number of components in a finite mixture of distributions from a parametric family. A step-up procedure using the bootstrap method is proposed. Some properties of the procedure are illustrated with simulation studies. An example of the method, applied to orientation of beach clasts, is given.  相似文献   
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Topographic features affect the scattering properties of planetary surfaces by casting shadows and altering the local incidence and emission angles. Measurements of this phenomenon were obtained on the Cornell goniometer for both high and low albedo surfaces. For the low albedo surface, the decrease in reflected radiation due to topography increases sharply with increasing phase angle, whereas for the high albedo sample the effects are approximately constant between phase angles of 30 and 70°. The observations are in good agreement with a theoretical model in the case of the dark surface. However, for the high albedo surface the model overestimates the effects by about a factor of 2, since it does not include the partial illumination of shadows by multiple scattering. For both high and low albedo surfaces, the effects of topography do not become significant until a phase angle of 30–40°.  相似文献   
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