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Piper (1944) diagram has been the basis for several important interpretations of the hydrogeochemical data. As seen in this diagram, most natural waters contain relatively few dissolved constituents, with cations (metals or bases) and anions (acid radicles) in chemical equilibrium with one another. Apart from the facies representation, the composition of the mixed sample can be identified in terms of the composition of the parental solution. To bring out this advantage of the Piper diagram, a study was conducted in the Kalpakkam region of Tamilnadu, South India. By taking the geology and water table into consideration, two sample locations were selected as parent solution and third one as the mixture sample. All three samples were analyzed for calcium (Ca), magnesium (Mg), sodium (Na), potassium (K), chloride (Cl), sulphate (SO4) and phosphate (PO4) by Ion Chromatograph (Metrohm IC 861). HCO3 was determined by volumetric titration. The Piper diagram shows that parent solutions clustered towards Na-Mg-Ca-HCO3-Cl and Na-HCO3 facies, and the mixing sample belongs to Na-Mg-HCO3 facies. Phreeqc interac-tive (Ver 2.8) along with the original composition of the mixture sample was used to correlate the mixing proportion identified by the Piper diagram.  相似文献   
2.
The chemical composition of 29 bore well water samples throughout the Kalpakkam region, South India, was determined to identify the major hydrogeochemical processes and the suitability of groundwater for domestic and irrigation purposes. The hydrochemical data were analyzed with reference to World Health Organization (WHO) standards and their hydrochemical facies were determined. The Piper plot shows that most of the groundwater samples fall in the field of mixed calcium–sodium–bicarbonate type followed by sodium–chloride, calcium–bicarbonate and mixed calcium–magnesium–chloride water types. The concentration of total dissolved solids exceeds the desirable limit in about 14% of samples; alkalinity values exceed the desirable limit in about 34% of the samples. The concentration of sulphate is well within the desirable limit at all the locations. The dominance of various heavy metals in the groundwater followed the sequence: Zn > Fe > Mn > Cu > Ni > Pb > Cr > Cd. Among the metal ions, the concentration of chromium and cadmium are within the permissible limit. Data are plotted on the US Salinity Laboratory diagram, which illustrates that most of the samples fall in the field of high salinity and low sodium hazard, which can be used to irrigate salt tolerant and semi-tolerant crops under favorable drainage conditions. Based on the analytical results, chemical indices like sodium adsorption ratio and residual sodium carbonate were calculated which show that most of the samples are good for irrigation.  相似文献   
3.
Excess fluoride in groundwater affects the human health and results in dental and skeletal fluorosis. Higher concentration of fluoride was noted in hard rock terrain of the south India, in the Krishnagiri district of Tamilnadu. The region has a complex geology ranging from ultra basic to acid igneous rocks, charnockite and gneissic rocks. Thirty-four groundwater samples were collected from this study area and analysed for major cations and anions along with fluoride. The order of dominance of cations is Na+?>?Mg2+?>?Ca2+?>?K+ and the anions in the following order HCO3 ??>?Cl??>?NO3 ??>?SO4 2?. It is found that nearly 58 % of the samples have more fluoride ranging from 1 to 3 mg/L. It is also noted that high fluoride waters correspond to magnesium water types. This is due to the release of fluoride from the magnesium-bearing minerals like, biotite, hornblende, etc., or weathering of apatite/hydroxyapatites found in charnockites.  相似文献   
4.
Fluoride (F?) is an indispensable element for the human’s skeletal and dental health at prescribed levels and becomes lethal at higher levels. Spatial–temporal variability of F? and its geochemical control/association with other dissolved ions in groundwater in the Dindigul district of Tamilnadu (India) were conducted to describe the geochemical dynamics of F in response to seasonal variability. High concentrations of fluoride (≥1.5 mg L?1) were observed in the northern region of the district. High levels of F? were observed in non-monsoon periods and low levels in monsoon, because of dilution by precipitation. Bicarbonate was well correlated with F? which explains that both ions were derived from the weathering. While F? has a very weak correlation with silica, this implies that the silicate weathering does not supply F? to the groundwater system. The F? pollution in Dindigul groundwaters is mainly driven by two factors: (1) the geogenic weathering inputs, the geology of this area mainly comprises fluoride bearing minerals (e.g. hornblende biotite gneiss and charnockite); (2) the anthropogenic inputs (agri-fertilizers and tannery waste). Further, F? in the study area is mainly attributed to geogenic sources during pre and postmonsoons and anthropogenic sources in monsoon periods.  相似文献   
5.
The accurate information through water quality analysis, scientific study on F ? distribution in groundwater and geochemical knowledge with spatial information on geology and climate are necessary to understand the source/cause, type and level of F ? contamination. The Dindigul district is a hard-rock terrain and marked as one of the fluoride-rich area in Tamilnadu due to occurrence of various rock types including fluoride-bearing minerals. The F ? content of groundwater can thus originate from the dissolution of fluoride-bearing minerals in the bed rock. Eighty-six representative groundwater samples from Dindigul district was collected during two different seasons. Samples were analysed for F ?, other major cations and anions. The study area is chiefly composed of hornblende biotite gneiss and charnockite, apart from this untreated tannery effluents also let from many places in the study area. Geographical Information System technique was adopted to study the sources of F ?, and it was found that F ? in the study is mainly attributed to geogenic source.  相似文献   
6.
The chemistry of the rainwater indirectly reflects the composition of the ions in the atmosphere. The study of the rainwater gains its own importance as it forms the basis for the agricultural, domestic and drinking water. Twelve rainwater samples were collected along the southeastern coast of India during southwest monsoon. The samples were analyzed for the major anions (Cl?, SO4 2?, PO4 3? and HCO3 ?) and cations (Na+, K+, Ca2+ and Mg2+). The majority of the samples reflect acidic pH. The general dominance of the cations is in the order of Na+ > Ca2+ > K+ > Mg2+ and that of anions is HCO3 ? > Cl? > SO4 2? > PO4 3?. The water is classified as calcium bicarbonate to sodium bicarbonate type. The decrease of pH value also increases the pCO2. In order to study the impact of acidic and alkaline species on rainwater, correlation coefficients were determined for establishing the relationship between different ions. Good correlation was established between cations, and sulfate has no correlation with other ions and pH. Factor analysis reveals that land use pattern, marine source and methanogenesis from the tidal influenced mangroves play a major role in determining the rainwater chemistry of the region.  相似文献   
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