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One unsolved problem of Archean metallogeny of the Russian part of the Fennoscandian Shield is related to the period of formation of orogenic gold deposits, the age of which was previously considered Early Proterozoic. Comprehensive studies identified the complex evolution of ores from the Novye Peski deposit and the first Neoarchean Sm–Nd isochron isotopic age (2583 ± 16 Ma) of the formation of orogenic gold of the Karelian Craton. A significant positive εNd(t) value of +4.7 of gold-bearing metasomatites probably points to the link between the ore-forming fluid and the deep mantle source.

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This paper describes the creation of two new reference samples of black shale, SCHS-1 and SLg-1, collected in the Bodaibo Region of Irkutsk District (Siberia, Russia). These samples have been developed as State Standard Samples to meet the requirements of Russia's Normative Documents, so that they can be recognised by the Russian State Certification Agency and included on the State Register of certified reference materials. SCHS-1 was produced from shale of the Khomolkho suite; SLg-1 represents the average composition of the Sukhoy Log gold deposit (within Au mineralisation). The homogeneity was assessed by applying the concept of potential inhomogeneity, and the inhomogeneity uncertainties (σinhom) for the indicator elements that were estimated experimentally by silicate XRF analysis. It was found that a majority of the indicator elements was characterised by σinhomp < 1/8 (Δp is the permissible certification uncertainty), and so σinhom was neglected for the indicator elements and all other elements that were included in their respective group. The value of σinhom calculated for Fe (σinhom,Fep > 1 /8) was taken into consideration for the noble metals and their associated elements (e.g., Ag, As, Au, etc.). More than fifty laboratories (thirty-seven from Russia) were involved in the interlaboratory experiment (ILE) to analyse these reference samples. The data obtained from the ILE allowed SCHS-1 and SLg-1 to be certified for, fifty-one and forty-three elements, respectively, as State Standard Samples.  相似文献   
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