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Astrid Holzheid Marina V. Charykova Vladimir G. Krivovichev Brendan Ledwig Elena L. Fokina Ksenia L. Poroshina Natalia V. Platonova Vladislav V. Gurzhiy 《Chemie der Erde / Geochemistry》2018,78(2):228-240
Any progress in our understanding of low-temperature mineral assemblages and of quantitative physico-chemical modeling of stability conditions of mineral phases, especially those containing toxic elements like selenium, strongly depends on the knowledge of structural and thermodynamic properties of coexisting mineral phases. Interrelation of crystal chemistry/structure and thermodynamic properties of selenium-containing minerals is not systematically studied so far and thus any essential generalization might be difficult, inaccurate or even impossible and erroneous. Disagreement even exists regarding the crystal chemistry of some natural and synthetic selenium-containing phases. Hence, a systematic study was performed by synthesizing ferric selenite hydrates and subsequent thermal analysis to examine the thermal stability of synthetic analogues of the natural hydrous ferric selenite mandarinoite and its dehydration and dissociation to unravel controversial issues regarding the crystal chemistry. Dehydration of synthesized analogues of mandarinoite starts at 56–87?°C and ends at 226–237?°C. The dehydration happens in two stages and two possible schemes of dehydration exist: (a) mandarinoite loses three molecules of water in the first stage of the dehydration (up to 180?°C) and the remaining two molecules of water will be lost in the second stage (>180?°C) or (b) four molecules of water will be lost in the first stage up to 180?°C and the last molecule of water will be lost at a temperature above 180?°C. Based on XRD measurements and thermal analyses we were able to deduce Fe2(SeO3)3·(6-x)H2O (x?=?0.0–1.0) as formula of the hydrous ferric selenite mandarinoite. The total amount of water apparently affects the crystallinity, and possibly the stability of crystals: the less the x value, the higher crystallinity could be expected. 相似文献
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俯冲带是壳-幔物质循环的重要场所,硬玉岩可以记录这一循环过程。文中总结了俄罗斯极地乌拉尔硬玉岩的研究进展。硬玉岩呈脉状或透镜状产在蛇纹石化的方辉橄榄岩中,主要由硬玉和绿辉石组成。根据结构和颜色,硬玉可识别出两个世代。硬玉韵律环带发育,含有H2O和CH4流体包裹体,显示从流体中结晶的特征。硬玉岩中的锆石为热液锆石,锆石稀土元素中LaN/YbN=0.001~0.01,LuN/GdN=10~83,Ce/Ce*=2.8~72,显示正异常,δEu=0.53~1.02,类似于岩浆锆石。锆石的176Hf/177Hf=0.282 708~0.283 017,εHf(t)=+6~+17,类似于N-MORB的Hf同位素组成,锆石δ18O组成为5.03‰~6.04‰,平均δ18O为(5.45±0.11)‰,类似于岩浆热液和地幔的氧同位素组成。这可能反映了锆石是被俯冲带流体从途经火成岩中捕获的或者形成锆石的流体与寄主岩(方辉橄榄岩)达到了平衡。硬玉岩稀土元素配分模式近平坦或轻稀土元素略显富集,LaN/YbN比值为0.82~2.42,δEu为1.2~1.6,显示正异常,这与寄主岩稀土元素配分模式相似。富集Sr、Ba、Zr、Hf,Nb为负异常,与岛弧岩浆特征类似。(87Sr/86Sr)t为0.703 400~0.703 519(t=368 Ma),变化较小,与古海水差别明显;εNd(t)值为+0.77~+5.61,变化较大,与寄主岩(方辉橄榄岩)的Nd同位素组成类似,但不同于海水及沉积物的Nd同位素组成,表明硬玉岩的物质来源与寄主岩有明显继承关系,海水与沉积物的贡献不是主要的。矿物学和岩石学证据支持极地乌拉尔的硬玉岩主要是俯冲带流体与橄榄岩相互作用后并在其中结晶的产物。 相似文献
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Only a few historical assessments of the zooplankton biomass in the Arctic Ocean exist are difficult to compare due to methodological differences including incomplete sampling of the water column. We present assessments of the zooplankton biomass for 66 locations scattered over the Eurasian and Makarov Basins of the Arctic Ocean and analyze regional variability and factors affecting the biomass distribution. The study is based on material from several summer expeditions of RV Polarstern (1993–1998) that was collected and processed using consistent methods, i.e. stratified sampling of the entire water column from the bottom to the surface with very similar gear and standardized calculation of biomass. Total zooplankton biomass varied strongly from 1.9 to 23.9 g DW m−2 dry mass. Regional variability was mainly related to the circulation pattern, but local food availability was also important. A belt of elevated biomass along the Eurasian continental margin was associated with the advection of Atlantic pelagic populations within the Arctic Ocean Boundary Current along the Siberian shelves and returning branches along mid-ocean ridges. Biomass was highest in the core of the Atlantic inflow and remained rather stable along the continental margins, but species composition changed, pointing to different adaptation levels to local conditions by advected species. Biomass gradually decreased towards the shelves and basins and was lowest in the centers of the basins north of 85°N. In the slope region, three Calanus species (C. hyperboreus, C. glacialis, C. finmarchicus) and Metridia longa contributed most to the biomass, chaetognaths (Eukrohnia hamata) were also important. In the basins, C. hyperboreus was dominant, copepods made up to 97% of total biomass. Vertical distribution was similar at all stations with biomass maxima in the upper 50 m layer except for stations near Fram Strait and northern Kara Sea, the gateways of Atlantic water to the Arctic Ocean, where maxima where between 25 and 100 m. As there was only very little interannual variability of temperature and current velocity in the regions of the Atlantic inflow we suggest that the majority of our samples, collected in 1993 and 1995, represents the phase of the 1990s warm event in the Nordic Seas. 相似文献
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Teresa Oberc-Dziedzic Ryszard Kryza Ksenia Mochnacka Alexander Larionov 《International Journal of Earth Sciences》2010,99(1):27-46
Approximately 500-Ma-old orthogneisses are widespread in the eastern part of the Variscan belt and are commonly interpreted
to have intruded mica-schist series of assumed Neoproterozoic age. New SHRIMP zircon ages of quartzofeldspathic metavolcanogenic
rocks of the mica schist series in the eastern part of the Karkonosze-Izera Massif (SW Poland) indicate that they are late
Cambrian/early Ordovician rather than Neoproterozoic in age, based on the zircon age spectra distributed mainly between ca.
500 and 660 Ma (with a few Proterozoic inherited minimum ages of ca. 970 and 1,825 Ma). Younger zircon dates, dispersed between
ca. 412 and 464 Ma, are interpreted as a result of Pb-loss likely caused by subsequent metamorphism. Consequently, the felsic
metavolcanogenic rocks appear to be roughly contemporaneous with the intrusion of ca. 500-Ma-old orthogneiss protoliths (with
the pooled concordia age of 487 ± 8 Ma interpreted as the best approximation of the protolith intrusive age). Field relationships,
petrological and geochemical features of the felsic and mafic rocks studied support a model in which the accompanying mica
schist series are not the original country rocks to the ca. 500 Ma granite intrusions, and indicate that their recent close
proximity is the result of tectonic juxtaposition. However, both the mica schists enclosing the bimodal metavolcanic rocks,
and the orthogneisses, are interpreted to represent a Cambro-Ordovician passive continental margin sequence being part of
the Saxothuringian domain. They are tectonically overlain to the east by HP/T metamorphic units, comprising MORB-type metaigneous
rocks, and delineating a tectonic suture separating the Saxothuringian block in the west from an assumed continental block
(Tepla-Barrandian) to the south-east. 相似文献
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Riphean basins of the central and western Siberian Platform 总被引：1，自引：0，他引：1
Sergey V. FrolovGrigorii G. Akhmanov Elena V. KozlovaOleg V. Krylov Ksenia A. SitarYuriy I. Galushkin 《Marine and Petroleum Geology》2011,28(4):906-920
The Siberian Platform is unique by its volume of Meso-Neoproterozoic sedimentary deposits. For about one billion years (∼1650-650 Ma) several sedimentary basins were developed here, resulting in the formation of several kilometers thickness of sedimentary cover. The Riphean (Mesoproterozoic-Lower Neoproterozoic) rocks are exposed mainly along platform peripheries. The most complete sections are represented by several megacycles. Each megacycle contains terrigenous series at the base and carbonate formations in the upper part. Several isolated and anisochronous basins were created during the Riphean on the territory of East Siberia. Some of them were intracratonic, others were developed on passive margins. Neoproterozoic orogeny along the platform boundaries resulted in re-organization of the Siberian basins, with extensive faulting, uplifting and erosion of the territories.In eastern Siberia, Riphean series contain large hydrocarbon accumulations. The reservoirs were formed mainly due to fracturing and leaching of carbonate strata (e.g. vugular carbonates of the pre-Vendian weathering crust). The Upper Proterozoic deposits are overlain by thick clayey-carbonate and saliferous-carbonate series of the Upper Vendian and Cambrian, isolating them from the upper sedimentary cover. The Riphean basins contained thick, organic rich, clayey and clayey carbonate. In some of them a hydrocarbon generation maximum took place at the end of the Riphean. The pre-Vendian erosion has removed a significant volume of Riphean sediments. During this time a majority of already formed hydrocarbon accumulations have been lost or degraded. Remaining Riphean series have generated hydrocarbons during the Paleozoic.Despite its complex history, the Riphean is still considered highly prospective, with source rocks developing at multiple levels and reservoirs occurring in both carbonate and clastic rocks. Discoveries of new oil-and-gas fields in East Siberia are likely, but will depend on integration of detailed seismic data and a large volume of core data for the correct prognosis of Riphean reservoir distribution. 相似文献
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Ksenia Tlatova Andrey Tlatov Alexei Pevtsov Kalevi Mursula Valeria Vasil’eva Elina Heikkinen Luca Bertello Alexander Pevtsov Ilpo Virtanen Nina Karachik 《Solar physics》2018,293(8):118
We use recently digitized sunspot drawings from Mount Wilson Observatory to investigate the latitudinal dependence of tilt angles of active regions and its change with solar cycle. The drawings cover the period from 1917 to present and contain information as regards polarity and strength of magnetic field in sunspots. We identified clusters of sunspots of same polarity, and used these clusters to form “bipole pairs”. The orientation of these bipole pairs was used to measure their tilts. We find that the latitudinal profile of tilts does not monotonically increase with latitude as most previous studies assumed, but instead, it shows a clear maximum at about 25?–?30 degree latitudes. Functional dependence of tilt (\(\gamma\)) on latitude (\(\varphi\)) was found to be \(\gamma= (0.20\pm0.08) \sin(2.80 \varphi) + (-0.00\pm0.06)\). We also find that latitudinal dependence of tilts varies from one solar cycle to another, but larger tilts do not seem to result in stronger solar cycles. Finally, we find the presence of a systematic offset in tilt of active regions (non-zero tilts at the equator), with odd cycles exhibiting negative offset and even cycles showing the positive offset. 相似文献
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Hans-Jürgen Hirche Ksenia Kosobokova 《Deep Sea Research Part II: Topical Studies in Oceanography》2007,54(23-26):2729
The distribution of Calanus finmarchicus was studied on a transect across the central Greenland Sea, and on five transects from the Eurasian shelves across the Atlantic Inflow in the Arctic Ocean. Stage composition was used as an indicator for successful growth; gonad maturity and egg production were taken as indicators for reproductive activity. On the Arctic Ocean transects, these parameters were measured simultaneously from the sibling species Calanus glacialis. Response of egg production rate to different temperatures at optimal food conditions was very similar between both species in the laboratory. C. finmarchicus was present at all stations studied, but young developmental stages were only present close to the regions of submergence of Atlantic water under the Polar water. This together with a decreasing abundance and biomass from west to east along the Atlantic Inflow in the Arctic Ocean and reproductive failure indicates that C. finmarchicus is expatriated in the Arctic Ocean. We hypothesize that the late availability of food in the Arctic Ocean, rather than low temperature per se, limits reproductive success. Better reproductive success in the very low temperature regions of the Return Atlantic Current and the marginal ice zone in the Greenland Sea supports this hypothesis. The possibility for a replacement of C. glacialis by C. finmarchicus and consequences for the ecosystem after increasing warming of the Arctic are discussed. 相似文献
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