Experimental silicate mineral/melt partition coefficients for beryllium and the crustal Be cycle from migmatite to pegmatite   总被引：1，自引：0，他引：1  

Joseph M Evensen  David London 《Geochimica et cosmochimica acta》2002,66(12):2239-2265

Partition coefficients (D_Be^mineral/melt) for beryllium between hydrous granitic melt and alkali feldspars, plagioclase feldspars, quartz, dark mica, and white mica were determined by experiment at 200 MPa H₂O as a function of temperature (650-900°C), activity of Be in melt (trace levels to beryl saturation), bulk composition, and thermal run direction. At trace levels, Be is compatible in plagioclase of An₃₁ (1.84 at 700°C) and muscovite (1.35 at 700°C) but incompatible in biotite (0.39-0.54 from 650-800°C), alkali feldspar (0.38-0.19 from 680-850°C), quartz (0.24 at 800°C), and albite (0.10 at 750°C). The partition coefficients are different at saturation of the melt in beryl: lower in the case of plagioclase of An₃₁ (0.89 at 700°C), muscovite (0.87 at 700°C), biotite (0.18-0.08 from 675-800°C), alkali feldspar (0.18-0.14 from 680-700°C), and quartz (0.17-0.08 from 750-800°C), but higher in the case of albite (0.37 at 750°C).With other data sources, these new partition coefficients were utilized to track, first, the distribution of Be between aluminous quartzofeldspathic source rocks and their anatectic melts, and second, the dispersion or concentration of Be in melt through igneous crystal fractionation of different magma types (e.g., S-type, I-type) up to beryl-saturated granitic pegmatites and, finally, into their hydrothermal aureoles. Among the rock-forming minerals, cordierite, calcic oligoclase, and muscovite (in this order) control the fate of Be because of the compatibility of Be in these phases. In general, beryl-bearing pegmatites can arise only after extended crystal fractionation of large magma batches (to F, fraction of melt remaining, ≤0.05); granitic magmas that originate from cordierite-bearing protoliths or that contain large modal quantities of calcic oligoclase will not achieve beryl saturation at any point in their evolution.  相似文献   

Trace-element partitioning at conditions far from equilibrium: Ba and Cs distributions between alkali feldspar and undercooled hydrous granitic liquid at 200 MPa     

George B. Morgan  David London 《Contributions to Mineralogy and Petrology》2003,144(6):722-738

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Further studies of ozone and sunspots     

London  Julius  Oltmans  Samuel 《Pure and Applied Geophysics》1973,106(1):1302-1307

Pure and Applied Geophysics -  相似文献   

Experiments on the kinetics of partial melting of a leucogranite at 200 MPa H<Subscript>2</Subscript>O and 690–800°C: compositional variability of melts during the onset of H<Subscript>2</Subscript>O-saturated crustal anatexis     

Antonio?Acosta-VigilEmail author  David?London  George?B.?Morgan 《Contributions to Mineralogy and Petrology》2006,151(5):539-557

We have experimentally investigated the kinetics of melting of an aplitic leucogranite (quartz+sodic plagioclase of ≈Ab₉₀+K-feldspar+traces of biotite) at 690, 740, and 800°C, all at 200 MPa H₂O. Leucogranite cylinders, 3.5 mm in diameter and 7 mm in length, were run in the presence of excess H₂O using cold-seal pressure vessels for 11–2,925 h. At 690 and 740°C and any experimental time, and 800°C and short run times, silicate glass (melt at run conditions) occurs as interconnected films along most of the mineral boundaries and in fractures, with the predominant volume occurring along quartz/feldspars boundaries and quartz/plagioclase/K-feldspar triple junctions. Glass film thickness is roughly constant throughout a given experimental charge and increases with experimental temperature and run duration. The results indicate that H₂O-saturated partial melting of a quartzo-feldspathic protolith will produce an interconnected melt phase even at very low degrees (<5 vol%) of partial melting. Crystal grain boundaries are therefore completely occluded with melt films even at the lowest degrees of partial melting, resulting in a change in the mechanism of mass transport through the rock from advection of aqueous vapor to diffusion through silicate melt. At 690 and 740°C the compositions of glasses are homogeneous and (at both temperatures) close to, but not on, the H₂O-saturated 200 MPa haplogranite eutectic; glass compositions do not change with run duration. At 800°C glasses are heterogeneous and plot away from the minimum, although their molar ratios ASI (=mol Al₂O₃/CaO+Na₂O+K₂O) and Al/Na are constant throughout the entire charge at any experimental time. Glass compositions within individual 800°C experiments form linear trends in (wt%) normative quartz–albite–orthoclase space. The linear trends are oriented perpendicular to the 200 MPa H₂O haplogranite cotectic line, reflecting nearly constant albite/orthoclase ratio versus variable quartz/feldspar ratio, and have endpoints between the 800°C isotherms on the quartz and feldspar liquidus surfaces. With increasing experimental duration the trends migrate from the potassic side of the minimum toward the bulk rock composition located on the sodic side, due to more rapid (and complete) dissolution of K-feldspar relative to plagioclase. The results indicate that partial melting at or slightly above the solidus (690–740°C) is interface reaction-controlled, and produces disequilibrium melts of near-minimum composition that persist metastably for up to at least 3 months. Relict feldspars show no change in composition or texture, and equilibration between melt and feldspars might take from a few to tens of millions of years. Partial melting at temperatures well above the solidus (800°C) produces heterogeneous, disequilibrium liquids whose compositions are determined by the diffusive transport properties of the melt and local equilibrium with neighboring mineral phases. Feldspars recrystallize and change composition rapidly. Partial melting and equilibration between liquids and feldspars might take from a few to tens of years (H₂O-saturated conditions) at these temperatures well above the solidus.  相似文献   

Geodynamic Evolution of East Antarctica – A Key to East–West Gondwana Connection, Satish-Kumar, M., Motoyoshi, Y., Osanai, Y., Hiroi, Y. & Shiraishi, K., (Eds.), Special Publication Geological Society of London, vol. 308, (456 pp.).     

Geodynamic Evolution of East Antarctica &#x; A Key to East&#x;West Gondwana Connection  Satish-Kumar  M.  Motoyoshi  Y.  Osanai  Y.  Hiroi  Y. &#x; Shiraishi  K.  Special Publication Geological Society of London  vol. 《Gondwana Research》2009,16(2):362

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Resistive wave breaking in the Earth's outer core     

Steven D. London 《地球物理与天体物理流体动力学》2013,107(5):397-411

The equations for an electrically conducting fluid in cylindrical coordinates are linearized assuming that the inertial terms in the momentum equation can be ignored (small Rossby number), and that the ratio of the Elsasser number and magnetic Reynolds number is one. After these assumptions, the governing equations are linearized about an ambient solution which vanishes at the the equator. Upon assuming large Elsasser and magnetic Reynolds number, the solutions to the linearized equations are approximated by wave trains having very short wave length (relative to the core radius) but which vary slowly (on a scale of the core radius). The period of the waves is much longer than a day but much shorter than the period of the slow hydromagnetic oscillations. These waves are found to be trapped in a region about the equator and away from the axis of rotation. The waves break at a latitudinal wave region boundary, in the sense that the waves become exponentially large in a boundary layer, having as an exponent some positive power of the large azimuthal wave number. This behavior is amplified as the Elsasser number becomes smaller while still remaining relatively large. Waves in more Earth-like parameter regimes are discussed briefly.  相似文献   

Boron in granitic magmas: stability of tourmaline in equilibrium with biotite and cordierite     

Michael B. Wolf  David London 《Contributions to Mineralogy and Petrology》1997,130(1):12-30

Experiments at 750 °C, 200 MPa_(H2O), a _(H2O)=1, and fO₂∼Ni-NiO established that the equilibrium among tourmaline, biotite, cordierite, and melt (± spinel, aluminosilicate, or corundum) occurs with ∼2 wt% B₂O₃ in strongly peraluminous melt with an aluminosity, measured by the parameter ASI, of >1.2. The experiments demonstrate the relationship of tourmaline stability to the activity product of the tourmaline components boron and aluminum, which are inversely related to one another. Tourmaline is unstable in metaluminous to mildly peraluminous melts (ASI <1.2) at 750 °C regardless of their boron content. For a given aluminosity, addition of components such as F requires a greater boron content of melt at this equilibrium. The stability of tourmaline increases with decreasing temperatures below 750 °C. At the inception of melting, tourmaline breaks down incongruently to assemblages containing crystalline AFM silicates (biotite, cordierite, garnet, sillimanite), aluminates (spinel, corundum), and B-enriched but Fe-Mg-poor melt. Granitic melts are likely to be undersaturated in tourmaline from the start of their crystallization, and their initial boron contents will be limited by the abundance of tourmaline in their source rocks. Quartzofeldspathic (gneissic, metapelitic) rocks that reached conditions of the granulite facies and still contain (prograde) tourmaline are rare, and probably have never yielded a partial melt. Most leucogranitic magmas will initially crystallize biotite, cordierite, or garnet, but not tourmaline. With crystallization, the Fe-Mg content of melt decreases, and the B₂O₃ content increases until the tourmaline-biotite and/or tourmaline-cordierite (or garnet) equilibria are attained. The B₂O₃ content of melt is buffered as long as these equilibria continue to operate, but low initial Fe-Mg contents of the magmas limit the quantity of boron that can be consumed by these reactions to <1 wt% B₂O₃. Normally, leucogranitic magmas contain insufficient Fe and Mg to conserve all boron as tourmaline and thus lose a large fraction of magmatic boron to wallrocks. Leucogranites and pegmatites with tourmaline as an early and only AFM silicate mineral probably contained >2 wt% B₂O₃ in their bulk magmas. Received: 6 August 1996 / Accepted: 21 July 1997  相似文献   

The use of satellite observations for atmospheric radiation studies     

Julius London 《Theoretical and Applied Climatology》1962,12(1):64-77

Summary The problem of satellite observation of infrared radiation is studied in terms of geometric and spectral variation of atmospheric radiation. As an aid in interpretation of satellite observations, the anisotropy of out-going radiation at the top of the atmosphere and at the satellite level is computed for different atmospheric models and spectral regions to characterize radiation from the lower, middle, and high troposphere. It is shown that limb darkening is an extremely sharp property of the atmosphere as viewed from an orbiting satellite.

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Zusammenfassung Das Problem der Satellitenbeobachtungen der infraroten Strahlung wird in seiner Beziehung zu den geometrischen und spektralen ?nderungen der atmosph?rischen Strahlung untersucht. Die Anisotropie der ausgehenden Strahlung an der Obergrenze der Atmosph?re und in Satellitenh?he wird für verschiedene Atmosph?renmodelle und Spektralbereiche berechnet, um die Strahlung der niederen, mittleren und hohen Troposph?re zu charakterisieren und um die Deutung von Satellitenbeobachtungen zu erleichtern. Es wird gezeigt, da? die Randverdunklung ein besonders deutliches Kennzeichen der Atmosph?re ist, wie sie von einem kreisenden Satelliten gesehen wird.

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Résumé Le problème de l'observation, par satellite, des radiations infra-rouges est envisagé en fonction de la géométrie et des variations spectrales du champ de radiations atmosphériques. En vue de faciliter l'interprétation des observations obtenues au moyen de satellites, l'anisotropie du champ de radiations émergeantes est calculée à la limite supérieure de l'atmosphère et au niveau du satellite pour différents modèles atmosphériques et pour des régions spectrales caractérisant le champ de radiations de la basse, de la moyenne et de la haute troposphère. Nous démontrons que l'assombrissement du bord devrait être une propriété très caractéristique de notre atmosphère comme elle est observée d'un satellite artificiel.

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With 4 Figures

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It is a pleasure to dedicate this paper toDr. W. M?rikofer on the occasion of his 70th birthday and in recognition of his basic contributions to observations of atmospheric radiation.  相似文献   

Behavior and effects of phosphorus in the system Na2O−K2O−Al2O3−SiO2−P2O5−H2O at 200 MPa(H2O)   总被引：1，自引：1，他引：1  

David London  George B. Morgan VI  Harold A. Babb  Jennifer L. Loomis 《Contributions to Mineralogy and Petrology》1993,113(4):450-465

The addition of phosphorus to H₂O-saturated and initially subaluminous haplogranitic (Qz–Ab–Or) compositions at 200 MPa(H₂O) promotes expansion of the liquidus field of quartz, a marked decrease of the solidus temperature, increased solubility limits of H₂O in melt at low phosphorus concentrations, and fractionation of melt out of the haplogranite plane (projected along an Or₂₈ isopleth) toward a peralkaline, silica-poor but quartz-saturated minimum composition. The partition coefficient for P₂O₅ between aqueous vapor and melt with an ASI (aluminum saturation index, mol Al/[mol Na+K])=1 is negligible (0.06), and consequently so are the effects of phosphorus on other melt-vapor relations involving major components. Phosphorus becomes more soluble in vapor, however, as the concentration of a NaPO₃ component increases via the fractionation of melt by crystallization of quartz and feldspar. The experimental results here corroborate existing concepts regarding the interaction of phosphorus with alkali aluminosilicate melt: phosphorus has an affinity for alkalis and Al, but not Si. Phosphorus is incorporated into alkali feldspars by the exchange component AlPSi_-2. For subaluminous compositions (ASI=1), the distribution coefficient of phosphorus between alkali feldspar and melt, D[P]Af/m, is 0.3. This value increases to D[P]Af/m=1.0 at a melt ASI value of 1.3. The increase in D[P]Af/m with ASI is expected from the fact that excess Al promotes the AlPSi_-2 exchange. With this experimental data, the P₂O₅ content of feldspars and whole rocks can reveal important facets of crystallization and phosphorus geochemistry in subaluminous to peraluminous granitic systems.  相似文献   

冀东迁西三屯营地区早太古宙三组片麻岩的岩石地球化学及其成因   总被引：1，自引：0，他引：1  

刘武旭  杨振升  D.Powell  M.F.Thirlwall  C.L.R.Friend 《地质论评》1993,39(3)

冀东迁西三屯营地区的高级变质杂岩,主要由早太古宙的三组片麻岩所组成。岩石地球化学研究表明,较早期的三屯营片麻岩为钙碱性石英闪长质岩石,除U和Th外,它不亏损不相容元素。较晚期的小关庄片麻岩和秋花峪片麻岩,分别为钙碱性石英闪长质和钙碱性英云闪长—奥长花岗质岩石,二者均发生了不相容元素的亏损。三屯营地区的岩石亏损与未亏损是源岩浆所具有的特征,可能是初始地壳形成时上地幔不均匀造成的。  相似文献