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1.
Elevated As concentrations in groundwater in the eastern United States have been recognized predominantly in the accretionary geologic terranes of northern New England. A retrospective examination of more than 18,000 existing groundwater samples from the Pennsylvania Department of Environmental Protection (PA DEP) Drinking Water and Sampling Information System database indicates that elevated groundwater As concentrations occur throughout the northern half of the Piedmont Province of Pennsylvania. Chemical analyses of 53 samples collected in 2005 from drinking water wells in this area all had detectable As, and 23% of these samples contained elevated (>133 nmol/L or >10 μg/L) concentrations of As. Elevated concentrations of As in the groundwater samples were most common in the Mesozoic sedimentary strata composed of sandstone and red mudstone with interbedded gray shale, and gray to black siltstone and shale. Arsenic was typically not elevated in groundwater of diabase intrusions of the Newark Basin or in crystalline and calcareous aquifers to the north of the Newark Basin. Geochemical parameters such as pH and oxidation–reduction potential can indicate mobility mechanisms of As in some regions. In this area, measured groundwater conditions were predominantly oxidizing (Eh > +50 mV), and more than 85% of samples contained arsenate as the dominant As species. Variations in pH were strongly correlated to the As concentration, with highest As concentrations observed at pH values greater than 6.4. The original source of As is most likely the black and gray shales that contain some arsenian pyrite with groundwater concentrations likely to be controlled by adsorption/desorption reactions with Fe oxides in the red mudstone aquifer materials. 相似文献
2.
Karen L. Hunter Dewayne A. Fox Lori M. Brown Kenneth W. Able 《Estuaries and Coasts》2006,29(3):487-498
Modification of brackish marshes by nonindigenousPhragmites australis has occurred across a broad geographical area in eastern North America. Among its effects on marsh processes,Phragmites may be increasingly unfavorable to marsh surface fishes as its invasion progresses within an estuary. We assessed the effect
of thePhragmites invasion on resident marsh surface fishes by examining the population response ofFundulus heteroclitus (mummichog, 5–48 mm TL) andF. luciae (spotfin killifish, 5–41 mm TL) to four distinct invasion stages in three estuaries of the U.S. mid Atlantic region (New
Jersey, Delaware, and Maryland). We documented precipitous declines in mean catch per unit effort ofF. heteroclitus in pit traps from natural marsh (51.6), through initial (33.8), early (12.3), and late invasion stages (2.4) across all sites.
A similar pattern was documented forF. luciae, with mean catch per unit effort in pit traps declining from natural marsh (48.9), through initial (39.1), early (9.3), and
late invasion stages (2.7). Population structure of both species also changed somewhat across invasion stages such that we
collected a narrower size range of individuals of both species from late invasion stages. Patterns suggest that as thePhragmites invasion progresses, there is a decline in habitat function for larval and juvenileF. heteroclitus and an increased risk of extirpation ofF. luciae from brackish marshes along the east coast of the U.S. 相似文献
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Electromagnetic induction by the equatorial electrojet 总被引:1,自引:0,他引:1
R. G. Rastogi 《Geophysical Journal International》2004,158(1):16-31
5.
ABSTRACTRain-on-snow (ROS) has the potential to produce devastating floods by enhancing runoff from snowmelt. Although a common phenomenon across the eastern United States, little research has focused on ROS in this region. This study used a gridded observational snow dataset from 1960–2009 to establish a comprehensive seasonal climatology of ROS for this region. Additionally, different rain and snow thresholds were compared while considering temporal trends in ROS occurrence at four grid cells representing individual locations. Results show most ROS events occur in MAM (March-April-May). ROS events identified with rainfall >1 cm are more frequent near the east coast and events identified with >1 cm snow loss are more common in higher latitudes and/or elevations. Decreasing trends in DJF (December-January-February) ROS events were identified near the coastal areas, with increasing trends in the northern portion of the domain. Significant decreasing trends in MAM ROS are likewise present on a regional scale. Factors playing a role in snowpack depth and rainfall, such as movement of storm tracks in this region, should be considered with future work to discern mechanisms causing the changes in ROS frequency. 相似文献
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Anticipating the scale invariance of rock fracturing processes, we applied Keilis-Borok’s algorithm M8, originally designed
for identifying times of increased probability (TIPS) of occurrence of strong earthquakes (M < 8.0), retrospectively to Koyna
earthquakes which occurred in the region after the impoundment of the Shivaji Sagar reservoir in 1962. The algorithm which
enables diagnosis of TIPS from the 7th year onwards after the commencement of the earliest available data set showed that
the 5.3 magnitude earthquake of 20 September 1980 indeed occurred within a time of increased probability. This result, apart
from its potential application to recognizing future TIPS in the region, points to selfsimilarity between the premonitory
patterns of natural and induced earthquakes and to scale-invariant nature of their processes. Further, a typical precursory
rise in seismicity followed by a relative quiescence was also found to precede all the three larger earthquakes of the sequence. 相似文献
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Petrographic and SEM observations on 478 samples of six quartzose sandstones provide a data base that can be used to evaluate the role of intergranular pressure solution (IPS) in sandstone diagenesis and to constrain predictive models of the pressure solution process. SEM examination of grain contacts that have experienced pressure solution suggests that IPS occurs at the interior portions of contacts where the greatest stress is concentrated and that granulation of quartz grains at points of contact may contribute to the process. The chemical compaction fabrics that result from IPS suggest that the process is most commonly induced by effective lithostatic stress and that the resulting strain is uniaxial.Numerous geological variables influence IPS. Grain size exerts a fundamental influence, with finer grained samples experiencing more IPS than coarser grained samples. On both local and regional scales, IPS is inhibited by poor sorting, an abundance of ductile grains, the presence of “shallow” cement, slow rates of shallow burial, and overpressured conditions. In contrast, IPS is enhanced by the presence of illite grain coatings, increased maximum burial depth, rapid rates of shallow burial, longer times spent at great depths, higher temperatures, and high volumes and rates of fluid flow.Silica budgets indicate that some of the analyzed sandstones approximate mass balance whereas others have exported silica. Calculations of fluid flow requirements indicate that advanced stages of IPS are favored by high volume, high velocity fluid flow. Such flow can occur as a result of uplift of basin margins, which is typical of foreland and intractonic basins. 相似文献