Advances in lithium analysis in solids by means of laser-induced breakdown spectroscopy: an exploratory study     

Cécile Fabre  Marie-Christine BoironJean Dubessy  Aliouka ChabironBernard Charoy  Tomas Martin Crespo 《Geochimica et cosmochimica acta》2002,66(8):1401-1407

Lithium is an important geochemical tracer for fluids or solids. However, because the electron microprobe cannot detect Li, variations of Li abundance at the micrometric scale are most often estimated from bulk analyses. In this study, the Li intense emission line at 670.706 nm in optical emission spectroscopy was used to perfect the analysis of Li at the micrometric scale by means of laser-induced breakdown spectroscopy (LIBS). To estimate lithium content for different geological materials, LIBS calibration of the emission line at 670.706 nm was achieved by use of synthetic glasses and natural minerals. The detection limit for this method is ∼5 ppm Li. Three applications to geological materials show the potential of LIBS for lithium determination, namely for Li-bearing minerals, melt inclusions, quartz, and associated fluid inclusions.For spodumene and petalite from granite pegmatite dikes (Portugal), the Li₂O concentrations are 7.6 ± 1.6 wt% and 6.3 ± 1.3 wt%, respectively, by use of LIBS. These values agree with ion microprobe analyses, bulk analyses, or both. For eucryptite crystals, the Li concentrations are scattered because grain size is smaller than the LIBS spatial resolution (6 to 8 μm). Lithium concentrations of melt inclusions from the Streltsovka U deposit (Siberia) are in the range of 2 to 6.2 wt% (Li₂O) for Li-rich daughter minerals. Lithium estimations on silicate glasses display values between 90 and 400 ppm.Lithium was also analyzed as a trace element in quartz. Transverse profiles were performed in hydrothermal barren quartz veins from the Spanish Central System (Sierra de Guadarrama). The highest Li concentrations (250 to 370 ppm) were found in specific growth bands in conjunction with the observed variation in optical cathodoluminescence intensity. Considering the fluid inclusion analysis, the source of fluid responsible to the Li enrichment in quartz is probably high-salinity fluids derived from sedimentary basins.  相似文献   

A comment on “The nitrogen record of crust-mantle interaction and mantle convection from Archean to Present” by B. Marty and N. Dauphas [Earth Planet. Sci. Lett. 206(2003) 397-410]     

Pierre Cartigny  Magali Ader 《Earth and Planetary Science Letters》2003,216(3):425-432

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Réponse aux commentaires d'Azambre et al. et de Rapaille et al.: [C. R. Geoscience 334 (2002) 197]     

Christian Desreumaux  Bernard Clément  Richard Fabre  Bruno Martins-Campina 《Comptes Rendus Geoscience》2004,336(2):173-174

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Shear wave velocity, seismic attenuation, and thermal structure of the continental upper mantle   总被引：3，自引：0，他引：3  

Irina M. Artemieva  Magali Billien  Jean-Jacques Lévêque  Walter D. Mooney 《Geophysical Journal International》2004,157(2):607-628

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Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event          下载免费PDF全文

Joseph G. T. Armstrong  John Parnell  Liam A. Bullock  Magali Perez  Adrian J. Boyce  Jorg Feldmann 《地学学报》2018,30(3):244-253

Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O₂ concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period.  相似文献   

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis     

Alicja Wudarska  Ewa S&#x;aby  Michael Wiedenbeck  Jaime D. Barnes  Magali Bonifacie  Neil C. Sturchio  Grard Bardoux  Frdric Couffignal  Johannes Glodny  Linnea Heraty  Timm John  Christof Kusebauch  Sathish Mayanna  Franziska D. H. Wilke  Ewa Deput 《Geostandards and Geoanalytical Research》2021,45(1):121-142

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.  相似文献   

Calderas,landslides and paleo-canyons on Piton de la Fournaise volcano (La Réunion Island,Indian Ocean)     

Olivier Merle  Philippe Mairine  Laurent Michon  Patrick Bachèlery  Magali Smietana 《Journal of Volcanology and Geothermal Research》2010,189(1-2):131-142

Based upon a re-interpretation of previous data and a new field campaign, a structural evolution is proposed for the early history of Piton de la Fournaise volcano from 500,000 to 50,000 years. Conceptually, it is shown that the formation of a caldera in which lava flows are contained inside the caldera depression, gives time for erosion to excavate deep canyons on the external slopes of the volcano, for example, the Rivière des Remparts, the Rivière Langevin and the Rivière de l'Est canyons on Piton de la Fournaise volcano. These canyons are infilled when lavas, filling the caldera and overflowing its rim, are able again to flow on the external slopes of the volcano. In the past, this excavating/infilling process has occurred twice following the formation of the Rivière des Remparts and Morne Langevin calderas. The formation of the third caldera, the Plaine des Sables caldera, was followed by the excavation of the current canyons. In addition to this process, two large landslides have been documented in the field. The first, which happened about 300,000 years ago, is apparently the first episode of the break up of Piton de la Fournaise volcano, predating the formation of the four large calderas. The second landslide, which occurred 150,000 years ago and is considered to be less extensive, has carried away the entire southern flank of the Rivière des Remparts caldera.  相似文献   

Sensitivity of a Greenland ice sheet model to ice flow and ablation parameters: consequences for the evolution through the last climatic cycle     

C. Ritz  A. Fabre  A. Letréguilly 《Climate Dynamics》1996,13(1):11-23

Sensitivity experiments are conducted to test the influence of poorly known model parameters on the simulation of the Greenland ice sheet by means of a three dimensional numerical model including the mechanical and thermal processes within the ice. Two types of experiments are performed: steady-state climatic conditions and simulations over the last climatic cycle with a climatic forcing derived from the GRIP record. The experiments show that the maximum altitude of the ice sheet depends on the ice flow parameters (deformation and sliding law coefficients, geothermal flux) and that it is low when the ice flow is fast. On the other hand, the maximum altitude is not sensitive to the ablation strength and consequently during the climatic cycle it is driven by changes in accumulation rate. The ice sheet extension shows the opposite sensitivity: it is barely affected by ice flow velocity and the ice covered area is smaller for large ablation coefficients. For colder climates, when there is no ablation, the ice sheet extension depends on the sea level. An interesting result is that the variations with time of the altitude at the ice divide (Summit) do not depend on the parameters we tested. The present modelled ice sheets resulting from the climatic cycle experiments are compared with the present measured ice sheet in order to find the set of parameters that gives the best fit between modelled and measured geometry. It seems that, compared to the parameter set most commonly used, higher ablation rate coefficents must be used. Received: 19 September 1995 / Accepted: 30 May 1996  相似文献   

Outline of the Pan-African geology of adrar des Iforas (Republic of Mali)     

R. Black  H. Ba  E. Ball  J. M. Bertrand  A. M. Boullier  R. Caby  I. Davison  J. Fabre  M. Leblanc  L. I. Wright 《International Journal of Earth Sciences》1979,68(2):543-564

The Iforas (60 000 km²) falls within the Pan-African mobile belt bordering the West-African craton in north-eastern Mali Republic. It is characterized by major N-S shear belts parallel to the edge of the craton which delimit longitudinal blocks some of which have undergone considerable horizontal displacements. The central core of the Iforas which consists largely of reactivated pre-Pan-African basement injected by Pan-African syn- and post-tectonic intermediate and acid plutonic rocks, has behaved as a relatively rigid blocks during the Pan-African dividing the orogenic belt into a western Iforas and an eastern Iforas.Western Iforas displays W to E zonation: an ophiolitic suture (Timetrine); trench volcano-sedimentary deposits cut by gabbros diorites and acid granitoids (Tilemsi); and a late orogenic composite »coastal range batholith intruding the pre-Pan-African basement of Central Iforas and its overlying volcano-sedimentary deposits which here display a littoral facies and a tillite.Central Iforas consists of two major units: a polycyclic pre-Pan-African basement metamorphosed under high amphibolite facies conditions of presumed Eburnean age and the Iforas granulite block bound to the W, N and E by shear zones.Eastern Iforas was totally separated during metamorphism and deformation from the Iforas granulite block. From West to East, three lithological assemblages have been recognised separed by shear belts: a Quartzite Group, a Gneissic Group and a Pelitic Group the latter representing the southern prolongation of the central Hoggar Pharusian province.Shear zones are an essential feature of Pan-African tectonism East of the West-African craton. The superimposed stress fields have been recognised producing: early N20° trending sinistral shear zones, a north-south dextral shear zone (Andjour-Tamaradant shear zone) and late conjugating sinistral NNW and dextral ENE wrench faults.Late Pan-African events reflect the uplift and unroofing of the Pan-African composite batholith, the intrusion of circular granite plutons often located close to shear zones and alternating episodes of distension and compression.Lastly the simple model proposed for the closing stages of the Pan-African in the Iforas is that of an active continental plate margin separated from the West African craton by an oceanic domain. Subsequent continental collision to the South with a promotory of the West African craton led to the formation of the Dahomeyan thrust front and modified the stress field. Closure of the oceanic domain of western Iforas is thought to have taken place by continued eastward subduction of the oceanic plate and sinistral movement along an inferred north westerly trending transform fault coinciding with the future Cretaceous Gao trough and an alignement of strong positive gravity anomalies. It was accompanied by the northerly migration of central and western Iforas along the conjugating dextral N-S Andjour-Tamaradant shear zone. Further shortening led to folding of the arcuate Timetrine-Ydouban-Gourma fold belt overlying the deformed margin of the West African craton.

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Zusammenfassung Das Iforas-Gebiet (60 000 km²) gehört zur pan-afrikanischen Bewegungszone, die in Mali an das westafrikanische Kraton grenzt. Diese Zone wird von N-S Scherbewegungen parallel zum Kraton durchzogen, wobei größere horizontale Versetzungsbeträge langgestreckte Blöcke herausgetrennt haben. Der zentrale Teil von Iforas besteht im wesentlichen aus reaktiviertem prae-panafrikanischem Basement, das in pan-afrikanischer Zeit von syn- und posttektonischen, intermediären und sauren Plutoniten intrudiert wurde. Dieses Gebiet wirkt als relativ starrer Block, der während der pan-afrikanischen Orogenese den Orogengürtel in einen westlichen und einen östlichen Ast teilt. Das westliche Iforas-Gebiet zeigt eine E-W Zonierung: eine Ophiolith-Sutur, einen vulkano-sedimentären Gürtel und einen Rand-Batholithen.Zentral-Iforas wird aus zwei Einheiten aufgebaut: ein mehrfach metamorphisiertes Basement und einen Granitblock.In den überregionalen Scherzonen lassen sich drei Stress-Felder erkennen: eine ältere 20° streichende sinistrale Scherzone, eine N-S dextrale Scherzone und jüngere NNW und dextrale ENE Bruchzonen.Spät-pan-afrikanische Ereignisse sind durch Heraushebung und Abtrag, Granitintrusionen und wechselnden Dehnungs- und Kompressionsbewegungen gekennzeichnet.

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Résumé L'Adrar des Iforas (60 000 km²) fait partie de la zone mobile pan-africaine en marge du craton ouest-africain au Nord-Est de la République du Mali. La région est caractérisée par d'importants accidents mylonitiques parallèles à la bordure du craton qui délimitent des compartiments longitudinaux dont certains ont subi des déplacements horizontaux considérables. La zone dorsale des Iforas qui consiste essentiellement en un socle pré-pan-africain réactivé et injecté au Pan-Africain par des roches plutoniques intermédiaires et acides, syn- et post-tectoniques, s'est comportée en compartiments relativement rigides au cours du Pan-Africain, divisant la chaîne en un rameau occidental et un rameau oriental.Le rameau occidental présente une zonation d'Ouest en Est: une suture ophiolitique (Timetrine); des dépôts volcano-sédimentaires de fosse recoupés par des gabbros et des diorites; et un vaste batholite composite tardi-orogénique qui recoupe le socle pré-pan-africain de la zone dorsale des Iforas et sa couverture de dépôts volcanosédimentaires ici à faciès littoral.La zone dorsale des Iforas comprend deux unités majeures: un socle prépan-africain polycyclique métamorphisé dans le faciès amphibolite, d'âge éburnéen présumé et le môle granulitique des Iforas, délimité à l'W, au N et à l'E par des accidents mylonitiques.Le rameau oriental était séparé du môle granulitique des Iforas lors du métamorphisme et de la déformation. D'W en E, on trouve trois unités séparées par des zones mylonitiques: un Groupe de Quartzites, un Groupe de Gneiss et un Groupe de Pélites. Ce dernier représente le prolongement vers le Sud de la province pharusienne du centre Hoggar.Les grands accidents de cisaillement sont un fait marquant du tectonisme pan-africain à l'Est du craton ouest-africain. Trois champs de contraintes superposées ont produit des accidents précoces sénestres de direction N20, un accident N-S dextre (Andjour-Tamaradant), et des failles cisaillantes tardives conjuguées d'orientation NNW sénestres et ENE dextres.Les événements pan-africains tardifs sont marqués par la surrection et l'érosion des batholites pan-africains, la mise en place de plutons granitiques souvent à proximité des grands accidents et par des alternances de distensions et de compressions.Enfin un modèle simple est proposé pour les stades ultimes du Pan-Africain dans l'Adrar des Iforas: une marge continentale active séparée du craton ouest-africain par un domaine océanique; suite à une collision au Sud avec un promontoire du craton ouestafricain qui aurait produit le front de chevauchement dahomeyen et modifié le champ de contraintes, la fermeture du domaine océanique de l'Ouest Iforas se serait produite par subduction à l'E de la plaque océanique et une translation sénestre le long d'une faille transformante orientée NW et coincidant avec le fossé crétacé de Gao et un alignement d'anomalies gravimétriques positives. Elle aurait été accompagnée par le déplacement vers le N de l'Iforas occidental et central le long de l'accident cisaillant dextre d'Andjour-Tamaradant. Cette fermeture aurait provoqué les plissements de la chaîne du Timetrine-Ydouban-Gourma qui repose sur la bordure déformée du craton ouestafricain.

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Impact of Hydropower Regulation on River Water Composition in Northern Sweden     

Dmytro Siergieiev  Anders Widerlund  Angela Lundberg  Lisbeth Almqvist  Magali Collomp  Johan Ingri  Björn Öhlander 《Aquatic Geochemistry》2014,20(1):59-80

Using hydrogeochemical analysis of two large boreal rivers (pristine Kalix and hydropower regulated Lule) discharging into the Gulf of Bothnia, the major impacts of regulation on water discharge, element transport and their seasonal redistribution have been assessed. The pre-regulation hydrogeochemical features were assumed to be similar for the two rivers. For the Lule River, the average maximum runoff was almost halved, while the average minimum was tripled as a result of the regulation. The fraction of winter transport of total organic carbon (TOC), Fe, Si, suspended Mn and P in the Lule River was, according to a conservative estimate, two to three times higher than in the pristine river. Longer residence time in the Lule River delayed arrival of the suspended Mn peak and dissolved Si decline to the river mouth. During summer, the suspended C/N ratio in the regulated river was 10–20 compared to <10 for the pristine, suggesting presence of predominantly old organic material. This was supported by a virtually constant suspended P/Fe ratio throughout the year in the Lule River, indicating low abundance of phytoplankton. TOC varied irregularly in the Lule River suggesting temporal disconnection between the river and the upper riparian zone. The disappearance of the spring flow maximum, a shift of element transport from spring to winter and supply of mainly old organic material during the vegetation growth season may have a pronounced impact on the ecosystem of the Gulf of Bothnia and the river itself.  相似文献