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Magdolna Hetnyi Csand Sajg Istvn Vet Alice Brukner-Wein Zsuzsanna Sznt 《Organic Geochemistry》2004,35(11-12):1201
This paper presents isotopic, bulk geochemical and biomarker data measured on organic matter accumulated in a narrow extensional basin developed at the oceanward margin of the huge Triassic carbonate platform in the Alps–Appenines domain. The integration of isotope signatures, organic petrographical and biomarker evidence together with the composition of kerogen pyrolysates suggests immature organic matter predominantly of algal origin with a minor, but not negligible, higher plant derived and moderate bacterial contribution for the entire sequence. The mineral sources are dominated by platform-derived subtidal Dachstein limestone with a minor palaeosol input and a moderate contribution of autochtonous quartz. Nevertheless, parallel variations observed in the mineral content, as well as in the amount and the quality of the organic matter reflect variations in the palaeoenvironment. The increased humidity, existing in the period of the accumulation of the upper section of the sequence, led to the restriction of dolomitization. A slightly greater higher plant derived contribution, in this section, is evidenced by the composition of bitumen and the results on GC and GC/MS analyses on the non-aromatic hydrocarbon fraction of bitumen. Moreover, the climate-induced weathering enchanced the primary productivity and resulted in a pronounced increase in the TOC content. The average estimated value of the planktonic productivity is about three times higher for the calcite-rich sequence than the dolomite-rich one, being 44.2 and 15.3 tCorg/m2/Ma, respectively. The low to moderate planktonic productivity shows that anoxic conditions, observed for the entire succession, are a consequence of the stagnant water stratification rather than high planktonic productivity. Depth trends in the data measured on kerogens (HI, OI, δ13Corg values, composition of pyrolysate) together with the δ18O excursions and Δδ13C values appear to be controlled by sea-level fluctuations. Consistent with the high abundance of alkyltiophenes in kerogen pyrolysates, the high Sorg/C ratios (ranging between 0.05 and 0.10) suggest the importance of natural sulfurization in the formation of the sulfur-rich type-II-S kerogen occurring in all of the samples. 相似文献
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Molecular geometries for a variety of classes of compounds are discussed. Where available, the structures of free molecules are compared with those in the crystal. Information inferred about intermolecular interactions are augmented with observations on structural consequences of dimerization and complex formation. Examples include substituted benzenes, sulfones, siloxane derivatives, metal halides, group four dihalides, tetrahaloaluminates, and donor-acceptor complexes. 相似文献
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György Hetényi 《地学学报》2014,26(5):372-376
Mass conservation is a fundamental physical law. Yet, computer models aiming to simulate Earth evolution commonly fail to respect it. Indeed, most geodynamic models implement phase transitions of rocks – such as metamorphism (solid–solid phase change) or melting (solid–liquid phase change) – following a simplifying assumption dating back to 1897 which is conserving volume rather than mass. The underlying problem is present at different scales, illustrated here by three examples: metamorphism in the continental crust, phase changes in the mantle transition zone and melt crystallization during columnar jointing. These illustrate that phase changes may become a driving force of a system's deformation and point to important differences with respect to simplified models. Developing and applying mass‐conserving approaches in future modelling tools are therefore not an option, but a necessity. 相似文献
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Magdolna Hetnyi Alice Brukner-Wein Csand Sajg Jnos Haas Mria Hmor-Vid Zsuzsanna Sznt Mria Tth 《Organic Geochemistry》2002,33(12)
The variations in the organic matter quantity and quality were studied with respect to the mineral composition of the carbonate sequences accumulated on a gentle slope (Zl-1 well) and at the toe of the slope (Rzt-1 well) located between a Late Triassic carbonate platform and a backplatform basin. Parallel variations observed in mineral composition and organic geochemical features of the successions appeared to be controlled by the change in climate and by sea-level fluctuations. The repetitive sea-level changes resulted in a variation in the carbonate-rich basin facies and in the mineralogically heterogenous slope and toe-of-slope ones. According to Rock Eval pyrolysis, organic petrography and carbon isotope ratios, the immature organic matter is of predominantly marine origin and composed of mainly liptinites in both of the studied boreholes. The results of the GC and GC/MS analyses of the saturated hydrocarbon fractions of bitumens together with the composition of kerogen pyrolysates reveal a predominant algal input with a minor variable bacterial and subordinate terrestrial contribution for the Rzt-1 borehole. In the Zl-1 borehole a significantly higher proportion of the bacterial biomass contributed to the organic precursors. The δ13C values and the composition of the kerogen pyrolysates together with the results of the maceral analysis and GC data suggest a relatively higher, but moderate, higher plant derived contribution in the slope facies and at the top of the toe-of-slope facies. The elementary composition of kerogens and Rock Eval data display type II-S kerogen in the basin and the slope facies, and type I-II-S one in the toe-of-slope facies. Variations in the hydrogen content of the organic matter mainly reflect variations in the preservation conditions and in primary productivity. The presence of the 2,6,10,15,19-pentamethyleicosane and the extremely low pristane/phytane ratios indicate a relatively high methanogenic bacterial activity and strongly anoxic depositional conditions in the Rzt-1 well, especially in two most organic-rich toe-of-slope facies. 相似文献
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Receiver functions of teleseismic waveforms recorded at four Hungarian permanent broadband stations have been analyzed using
semilinearized and stochastic inversion methods to estimate the crustal thickness and S wave velocity structure in the Pannonian
Basin. The results of both inversion methods agree well with the crustal thicknesses obtained by previous seismic refraction
and reflection studies in the regions which are densely covered with seismic lines (28 and 27 km in westernmost and southern
Hungary, respectively) and suggest a thicker crust compared to what was known before beneath the Transdanubian and Northern
Ranges (34 and 33 km, respectively). The comparison of the one-dimensional shear wave velocity models derived by the different
inversion methods shows that, in case of simple, smoothly varying structures, the results do not differ significantly and
can be regarded as absolute velocities. Otherwise, the recovered velocity gradients agree, but there are differences in the
absolute velocity values. The back-azimuthal variations of both radial and tangential receiver functions are interpreted as
dipping structure and as waves sampling different geological areas. The signature of the deep structure on low-frequency receiver
functions suggests a strong velocity contrast at the 670-km discontinuity. The vanishing 410-km boundary may be attributed
to the remnant of a subducted oceanic slab with increased Poisson’s ratio in the transition zone. 相似文献
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Bjarne S. G. Almqvist Sonja A. Bosshard Ann M. Hirt Hannes B. Mattsson Gy?rgy Hetényi 《Bulletin of Volcanology》2012,74(7):1667-1681
The anisotropy of magnetic susceptibility (AMS) and rock magnetic properties were measured on specimens from a basalt plate that was cut from a vertical section of a basalt column from Hrepphólar, Iceland. Macroscopic structures are clearly distinguishable in the plate, including banding inferred to represent viscous fingering parallel to the vertical axis of the column. Rock magnetic experiments indicate that the dominant ferromagnetic (sensu lato) mineral is titanomagnetite, Fe 3?x Ti x O4, with a Ti-composition of x?=?~0.6. Magnetic properties are related to the position within the plate and reveal a dominant volume fraction of single domain titanomagnetite in the center of the basalt column, with multidomain titanomagnetite away from the center. The AMS determined by low-field measurements shows an inconclusive relationship with the visual structures, which arises from variation of the grain size (i.e., single domain versus multidomain) across the column. In contrast, the AMS measured with a high-field torsion magnetometer avoids the complication of magnetic domain state, as is demonstrated in this contribution, and additionally allows for the separation of ferrimagnetic from paramagnetic sub-fabrics. Both sub-fabrics display a clear relationship with the macroscopic structures and support the hypothesis that vertical flow of melt took place during development of the Hrepphólar columnar basalt. Maximum susceptibility axes of the ferrimagnetic sub-fabric are grouped near the vertical axis of the column. The paramagnetic sub-fabric varies systematically across the column in coincidence with internal structure. The shape of the magnetic susceptibility ellipsoid varies across the basalt column, showing an increasingly prolate fabric toward its center. 相似文献
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György Hetényi Benoît Taisne Fanny Garel Étienne Médard Sonja Bosshard Hannes B. Mattsson 《Bulletin of Volcanology》2012,74(2):457-482
Columnar jointing is a common feature of solidified lavas, sills and dikes, but the factors controlling the characteristic
stoutness of columns remain debated, and quantitative field observations are few in number. In this paper, we provide quantitative
measurements on sizing of columnar joint sets and our assessment of the principal factors controlling it. We focus on (1)
chemistry, as it is the major determinant of the physical (mechanical and thermal) properties of the lava, and (2) geology,
as it influences the style of emplacement and lava geometry, setting boundary conditions for the cooling process and the rate
of heat loss. In our analysis, we cover lavas with a broad range of chemical compositions (from basanite to phonolite, for
six of which we provide new geochemical analyses) and of geological settings. Our field measurements cover 50 columnar jointing
sites in three countries. We provide reliable, manually digitized data on the size of individual columns and focus the mathematical
analysis on their geometry (23,889 data on side length, of which 17,312 are from full column sections and 3,033 data on cross-sectional
area and order of polygonality). The geometrical observations show that the variation in characteristic size of columns between
different sites exceeds one order of magnitude (side length ranging from 8 to 338 cm) and that the column-bounding polygons’
average order is less than 6. The network of fractures is found to be longer than required by a minimum-energy hexagonal configuration,
indicating a non-equilibrium, geologically quick process. In terms of the development and characteristic sizing of columnar
joint sets, our observations suggest that columns are the result of an interplay between the geological setting of emplacement
and magma chemistry. When the geological setting constrains the geometry of the emplaced body, it exerts a stronger control
on characteristic column stoutness. At unconstrained geometries (e.g. unconfined lava flows), chemistry plays the major role,
resulting in stouter columns in felsic lavas and slenderer columns in mafic lavas. 相似文献
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