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M. A. Amani A. M. Latifi K. Tahvildari R. Karimian 《International Journal of Environmental Science and Technology》2018,15(6):1301-1312
In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L?1, temperature of 298 K and adsorbent dose of 0.1 g L?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups. 相似文献
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Mohammad Reza Maleki Javan Asadollah Noorzad Manouchehr Latifi Namin 《国际地质力学数值与分析法杂志》2008,32(6):681-699
The dynamic behaviour of pile groups subjected to an earthquake base shaking is analysed. An analysis is formulated in the time domain and the effects of material nonlinearity of soil, pile–soil–pile kinematic interaction and the superstructure–foundation inertial interaction on seismic response are investigated. Prediction of response of pile group–soil system during a large earthquake requires consideration of various aspects such as the nonlinear and elasto‐plastic behaviour of soil, pore water pressure generation in soil, radiation of energy away from the pile, etc. A fully explicit dynamic finite element scheme is developed for saturated porous media, based on the extension of the original formulation by Biot having solid displacement (u) and relative fluid displacement (w) as primary variables (u–w formulation). All linear relative fluid acceleration terms are included in this formulation. A new three‐dimensional transmitting boundary that was developed in cartesian co‐ordinate system for dynamic response analysis of fluid‐saturated porous media is implemented to avoid wave reflections towards the structure. In contrast to traditional methods, this boundary is able to absorb surface waves as well as body waves. The pile–soil interaction problem is analysed and it is shown that the results from the fully coupled procedure, using the advanced transmitting boundary, compare reasonably well with centrifuge data. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
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Strength behavior and microstructural characteristics of tropical laterite soil treated with sodium silicate-based liquid stabilizer 总被引：4，自引：1，他引：3
Although the effects of nontraditional stabilizers on the geotechnical properties of tropical soils has been the issue of investigation in recent years, the micro-structural characteristics of nontraditional soil additives and in particular selected additive (TX-85) have not been fully studied. Nontraditional soil stabilization additives are widely used for stabilizing marginal materials. These additives are low-cost alternatives to traditional construction materials and have different compositions. They also differ from one another while interacting with soil. In line with that, it was the objective of this research to investigate the strength properties and physicochemical mechanisms related to tropical laterite soil mixed with the liquid stabilizer TX-85. Macro-structure study, i.e., compaction, and unconfined compression strength test were used to assess the engineering and shear properties of the stabilized laterite soil. In addition, the possible mechanisms that contributed to the stabilization process were discussed using various spectroscopic and microscopic techniques such as X-ray diffractometry (XRD), energy-dispersive X-ray spectrometry, scanning electron microscopy, and Fourier transform infrared spectroscopy. From engineering point of view, the results indicated that the strength of TX-85 stabilized laterite soil improved significantly. The degree of improvement was approximately four times stronger than natural soil after a 7-day curing period. The XRD showed no crystalline products (gel form). Moreover, weathering effects were obvious in TX-85 treated samples in most of clay minerals’ peak intensities. These effects were reduced especially for kaolinite mineral inside the soil with curing time. 相似文献
4.
Namin Koo Kwon-Rae Kim Youn-Jung Choi Sang-Hwan Lee Gary Owens Jeong-Gyu Kim 《Environmental Earth Sciences》2012,65(3):689-697
To determine the appropriate allocation of resources for the future restoration of the abandoned mining district of Kangwon
in Korea, identification of the main pollutants and the main sources discharging these pollutants is crucial. Therefore, a
2-year study was undertaken to quantify the amount of pollutants in the Uchen stream (a potential sink for contamination),
which runs through the district, and to determine the potential sources of these pollutants, including mine drainage and soil.
Arsenic (As) was the main pollutant in mine drainage and soils showing concentrations above the Korean regulated standard
levels of 50 μg L−1 and 50 mg kg−1 for water and soil, respectively. In addition, the pollution index (PI) showed that mine drainages were polluted by As to
a moderate (2 ≤ PI < 3) or strong (4 ≤ PI < 5) degree. Consequently, As load in mine drainage and soil contributed to increased
amounts of As in the stream. The As loads in mine drainages (11 and 587 g month−1 for mine adit 1 and 2, respectively) accounted for only 9% of the total As load to the stream (6,378 g month−1); and the influence of mine drainages on As contents in the stream was more reliant on the total volume of mine drainage
generated rather than the As concentration in the mine drainage. Approximately 91% of the As in the stream was derived from
the soils within the study area. 相似文献
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Various methods to control scour around bridge piers have been proposed.In the present study the application of cable or collar and a combination of cable and collar were examined experimentally,as countermeasures against local scouring at a smooth circular bridge pier,close to threshold flow conditions of initiation of uniform sediment motion.The results show that the simultaneous use of cable and collar has high efficiency in reducing the scour depth.The best configuration was found for a cable-pier diameter ratio of 0.15 and thread angle of 15°,in which the scour depth in upstream of the pier reduced to about 53%.In the case of a pier protected with cable and collar the scouring postponed more than pier protected with collar and the rate of scouring is less than in pier protected with collar.These advantages can reduce the risk of pier failure when the duration of flood is short. The results indicate that the scour reduction increases as the cable diameter increased and the thread angle decreased. 相似文献
7.
In this paper reduction of scour around group of two and three piers using circular collar has been carried out for the case of clear-water flow over uniform sediment. The efficiency of collars, with different sizes and spaces between piers is studied through experiments in group of two and three piers. The result reveals that collar has more influence in reduction of scour depth in rear piers than the first pier. Also, when the spacing between the piers increases the area without protection between the piers is washed away resulting deeper scour holes at the rear piers. 相似文献
8.
Physicochemical behavior of tropical laterite soil stabilized with non-traditional additive 总被引：1，自引：0，他引：1
Non-traditional soil stabilizers are widely used for treating weak materials. These additives are cost- and time-effective alternatives to more traditional materials such as lime and cement. It has been well established that the treatment of natural soil with chemical additives will gradually affect the size, shape, and arrangement of soil particles. Furthermore, the degree of improvement is dependent on the quantity and the pattern of new products formed on and around the soil particles. In this paper, unconfined compressive strength (UCS) test was performed as an index of soil improvement on mix designs treated with calcium-based powder stabilizer (SH-85). The time-dependent changes in shear strength parameter and compressibility behavior of treated soil were also studied using standard direct shear and one-dimensional consolidation tests. In order to better understand the shape and surface area of treated particles, FESEM, N2-BET, and particle size distribution analysis were performed on soil-stabilizer matrix. From engineering standpoint, the UCS results showed that the degree of improvement for SH-85-stabilized laterite soil was roughly five times stronger than the untreated soil at the early stages of curing (7-day period). Also, a significant increase in the compressibility resistance of treated samples with curing time was observed. Based on the results, less porous and denser soil fabric was seen on the surface of clay particles. FESEM images of the treated mix designs showed the formation of white lumps in the soil fabric with the cementitious gel filling the pores in the soil structure. 相似文献
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